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Metallic glass formation at the interface of explosively welded Nb and stainless steel

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Abstract

The interface between explosively welded niobium and stainless steel SUS 304 was studied using scanning electron microscopy, transmission electron microscopy and energy dispersive X-Ray spectroscopy. The wavy interface along which vortex zones were located was observed. The vortex zones formed due to the mixing of materials typically had amorphous structure. Inoue’s criteria of glass formation were used to explain this result. The effect of the composition, cooling rate and pressure on the glass formation are discussed. The conditions of deformation, heating, and cooling as well as shockwaves propagation were numerically simulated. We show that the conditions of vortex zone formation resemble the conditions of rapid solidification processes. In contrast to the “classical” methods of rapid solidification of melt, the conditions of metastable phase formation during explosive welding are significantly complicated by the fluctuations of composition and pressure. Possible metastable structures formation at the interface of some common explosively joined materials is predicted.

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Bataev, I.A., Hokamoto, K., Keno, H. et al. Metallic glass formation at the interface of explosively welded Nb and stainless steel. Met. Mater. Int. 21, 713–718 (2015). https://doi.org/10.1007/s12540-015-5020-7

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