Abstract
This study focuses on the characterization of lateritic clays collected in the Mbalmayo area for their potential use in the production of fired bricks. They were subjected to physicochemical and mechanical tests. The mineralogy of sample powders was determined by X-ray diffraction and Fourier transforms infrared, while chemical composition was carried out by X-ray fluorescence for major elements and by mass spectrometry for trace elements. The spread-out grain size leads to good compaction of the final products. The mineralogical composition is dominated by quartz and kaolinite, with minor amounts of goethite, anatase, and gibbsite. Geochemical results show a predominance of SiO2 (62.34–80.73 wt%), followed by Al2O3 (9.09–19.13 wt%) and Fe2O3 (1.82–6.26 wt%). During firing, there is insufficient sintering due to the low fluxing oxide proportion, while the transformation of kaolinite into mullite increases the mechanical strength. The linear shrinkage values increase with firing temperature and are low and below 5% at temperatures less than 1000 °C. The water absorption rate varies between 11 and 23%. The values of flexural strength are moderate and lower than 15 MPa. These overall features make the Mbalmayo lateritic clay suitable for fired brick production as raw materials at the temperatures are 900 and 1000 °C.
Similar content being viewed by others
References
Abajo MF (2000) Manual sobre fabricacio´n de baldosas. Tejas y Ladrillos Edition Beralmar S. A, Barcelona
Abdelmalek B, Bouazi R, Bouftouha Y, Bouabsa L, Fagel N (2017) Mineralogical characterization of Neogene clay areas from the Jijel basin for ceramic purposes (NE Algeria-Africa). Appl Clay Sci 136:176–183. https://doi.org/10.1016/j.clay.2016.11.025
Abdullahi Y, Ali EA, Oyeyemi S (2012) A study of the physico-chemistry and mineralogy of Agbaja clay for its industrial application. Chemsearch J 3(2):53–60
Alcântara A, Beltrâo M, Oliveira H, Gimenez I, Barreto L (2008) Characterization of ceramic tiles prepared from two clays from Sergipe-Brazil. Appl Clay Sci 39:160–165. https://doi.org/10.1016/j.clay.2007.05.004
Andrade FA, Al-Qureshi HA, Hotza D (2011) Measuring the plasticity of clays: a review. Appl Clay Sci 51(1-2):1–7. https://doi.org/10.1016/j.clay.2010.10.028
Arslan C, Gencel O, Borazan I, Sutcu M, Erdogmus E (2021) Effect of waste-based micro cellulose fiber as pore maker on characteristics of fired clay bricks. Constr Build Mater 300:124298. https://doi.org/10.1016/j.conbuildmat.2021.124298
Bennour A, Mahmoudi S, Srasra E, Hatira N, Boussen S, Ouaja M, Zargouni F (2015) Identification and traditional ceramic application of clays from the Chouamekh region in south-eastern Tunisia. Appl Clay Sci 118:212–220. https://doi.org/10.1016/j.clay.2015.09.018
Bomeni IY, Njoya A, Ngapgue F, Wouatong ASL, Yongue Fouateu R, Kamgang Kabeyene V, Fagel N (2018) Ceramic with potential application of Ngwenfon alluvial clays (noun, west Cameroon) in building construction: mineralogy, physicochemical composition and thermal behavior. Constr Build Mater 182:493–503. https://doi.org/10.1016/j.conbuildmat.2018.06.135
Celik H (2010) Technological characterization and industrial application of two Turkish clays for the ceramic industry. Appl Clay Sci 50:245–254. https://doi.org/10.1016/j.clay.2010.08.005
Christidis GE (2011) Industrial clays. Eur Mineralog Union, Notes in Mineral 9(9):341–414
Cox R, Lowe DR, Cullers RL (1995) The influence of sediment recycling and basement composition on evolution of mudrock chemistry in the southwestern United States. Geochem Cosmochim Acta 59(14):2919–2940. https://doi.org/10.1016/0016-7037(95)00185-9
Dondi M, Fabbri B, Guarini G (1998) Grain-size distribution of Italian raw materials for building clay products: a reappraisal of the Winkler diagram. Clay Miner 33:435–442. https://doi.org/10.1180/000985598545732
Dondi M, Raimondo M, Zanelli C (2014) Clays and bodies for ceramic tiles: reappraisal and technological classification. Appl Clay Sci 96:91–109. https://doi.org/10.1016/j.clay.2014.01.013
Doum MJ, Fuh CG, Fadil-Djenabou S, Onana VL, Ndjigui P-D, Armstrong-Altrin JS (2020) Characterization and potential application of gleysols and ferralsols for ceramic industry: a case study from Dimako (Eastern Cameroon). Arab J Geosci 13:1074
El Ouahabi M, Daoudi L, Fagel N (2016) Technological behavior of cretaceous and pliocene clays of northern Morocco used in fired brick manufacturing. J Mater Environ Sci 9(4):1140–1151. https://doi.org/10.1016/j.clay.2019.02.019
Elimbi A, Tchakoute HK, Njopwouo D (2011) Effects of calcination temperature of kaolinite clays on the properties of geopolymer cements. Constr Build Mater 25:2805–2812. https://doi.org/10.1016/j.conbuildmat.2010.12.055
Fadil-Djenabou S, Ndjigui P-D, Mbey JA (2015) Mineralogical and physicochemical characterization of Ngaye alluvial clays (Northern Cameroon) and assessment of its suitability in ceramic production. J Asian Ceram Soc 3:50–58. https://doi.org/10.1016/j.jascer.2014.10.008
Fedo CM, Young GM, Nesbitt HW, Hanchar JM (1997) Potassic and sodic metasomatism in the Southern Province of the Canadian Shield: evidence from the Paleoproterozoic Serpent Formation Huronian Supergroup, Canada. Precambrian Res 84:17–36. https://doi.org/10.1016/S0301-9268(96)00058-7
Fiori C, Fabbri B, Donati G, Venturi I (1989) Mineralogical composition of the clay bodies used in the Italian tile industry. Appl Clay Sci 4:461–473. https://doi.org/10.1016/0169-1317(89)90023-9
Guzlena S, Sakale G, Certoks S, Grase L (2019) Sand size particle amount influence on the full brick quality and technical properties. Constr Build Mater 220:102–109. https://doi.org/10.1016/j.conbuildmat.2019.05.170
Kamgang Kabeyene Beyala V, Onana VL, Ndome Effoudou Priso E, Parisot JC, Ekodeck GE (2009) Behavior of REE and mass balance calculations in a lateritic profile over chlorite schists in South Cameroon. Chem Erde 69:61–73. https://doi.org/10.1016/j.chemer.2008.08.003
Kankao OO, Ngon Ngon GF, Tehna N, Bayiga EC, Mbog MB, Mbaï J.S, Etame J (2022) Physicochemical and mineralogical characterization of clay materials in the Douala Coastal Sedimentary Sub-basin (Cameroon, Central Africa). J Geosci Geomat 10(3):126-138. https://doi.org/10.12691/jgg-10-3-2
Kessoum Adamou J-M, Ntouala RFD, Ndome-Priso E, Nanga Bineli MT, Hamadjida G, Ngo’o Ze A, Onana VL (2023) Mineralogical, geochemical, and geotechnical features of lateritic soils from termite mounds in two contrasting savannah areas (central Cameroon) as raw materials for brick making. Heliyon 9:e17257. https://doi.org/10.1016/j.heliyon.2023.e17257
Kornmann M (2005) Ingénieurs du Centre Technique des Tuiles et Briques, Matériaux de construction en terre cuite, fabrication et propriétés. Editions Septima, Paris, pp 33–34
Kreimeyer R (1987) Some notes on the firing color of clay bricks. Appl Clay Sci 2:175–183. https://doi.org/10.1016/0169-1317(87)90007-X
Lahcen D, Elboudour EIH, Saadi L, Albizane A, Bennazha J, Waqif M, Elouahabi M, Fagel N (2014) Characteristics and ceramic properties of clayey materials from Amezmiz region (Western High Atlas, Morocco). Appl Clay Sci 102:139–147. https://doi.org/10.1016/j.clay.2014.09.029
Lee VG, Yeh TH (2008) Sintering effects on the development of mechanical properties of fired clay ceramics. Mater Sci Eng 485:5–13. https://doi.org/10.1016/j.msea.2007.07.068
Mahmoudi S, Srasra E, Zargouni F (2008) The use of Tunisian Barremian clay in the traditional ceramic industry: optimization of ceramic properties. Appl Clay Sci 42:125–129. https://doi.org/10.1016/j.clay.2007.12.008
Mango Itulamya LAM, Collin F, Pilate P, Courtejoie F, Fagel N (2019) Evaluation of Belgian clays for manufacturing compressed earth blocks. Geol Belg 22:139–148. https://doi.org/10.20341/gb.2019.002
Marsigli M, Dondi M (1997) Plasticita delle Argille Italiane per Laterizi e Previsione Del. Loro Comportamento in Foggiatura. L’'industria Laterizi 46:214–222
Mbey JA, Ngally Sabouang CJ, Makon TB, Coulibaly SL, Kong S (2021) The thermal dihydroxylation of kaolinite using thermogravimetric analysis and controlled rate thermal analysis. J Cameroon Acad Sci 16(3):225–245. https://doi.org/10.4314/Jcas.V16i3.4
Mbumbia L, Mertens De Wilmars A, Tirlocq J (2000) Performance characteristics of lateritic soil bricks fired at low temperatures: a case study of Cameroon. Constr Build Mater 14:121–131. https://doi.org/10.1016/S0950-0618(00)00024-6
McNally GH (1998) Soil and rock construction materials. CRC Press, London, pp 291–310
Meimaroglou N, Mouzakis C (2019) Cation exchange capacity (CEC), texture, consistency and organic matter in soil assessment for earth construction: the case of earth mortars. Constr Build Mater 221:27–39. https://doi.org/10.1016/j.conbuildmat.2019.06.036
Melo C, Kamseu E, Djangang C (2001) In Proceedings of the 1st Conference on the Valorization of Clay Materials in Cameroon and Launching of the Cameroonian Clay Group, Ed. by Nkoumbou, C and Njopwouo, D., April 11-12, Yaoundé, Cameroon. 57-69
Millogo Y, Hajjaji M, Morel JC (2011) Physical properties, microstructure and mineralogy of termite mound material considerer as construction materials. Appl Clay Sci 52:160–164. https://doi.org/10.1016/j.clay.2011.02.016
Moore D, Reynolds RC Jr (1997) X-ray diffraction and the identification and analysis of clay minerals, 2nd edn. Oxford University Press, Oxford
Monterio SN, Vieira CMF (2004) Influence of firing temperature on the ceramic properties of clays from Campos dos Goytacazes, Brazil. Appl Clay Sci 27:229–234. https://doi.org/10.1016/j.clay.2004.03.002
Murray HH (2007) Applied clay mineralogy: occurrence, processing and application of kaolins, bentonite, palygorskite-sepiolite and common clays, 1st edn. Elsevier, Amsterdam
Mvondo H, Owona S, Mvondo Ondoa J, Essono J (2007) Tectonic evolution of the Yaounde segment of the Neoproterozoic Central African Orogenic Belt in Southern Cameroon. Can J Earth Sci 44:433–444. https://doi.org/10.1139/e06-107
Nedelec A, Macaudiere J, Nzenti JP, Barbey P (1986) Evolution crustale et métamorphique des chloritoschistes de Mbalmayo (Cameroun). Implications sur la structure de la zone mobile panafricaine d’Afrique Centrale au contact du Craton du Congo. C R Acad Sci 303(II-1):75–80
Nesbitt HW, Young GM (1984) Prediction of some weathering trends of plutonic and volcanic rocks based on thermodynamic and kinetic considerations. Geochem Cosmochim Acta 48:1523–1534. https://doi.org/10.1016/0016-7037(84)90408-3
Ngun BK, Mohamad H, Sulaiman SK, Okada K, Ahmad ZA (2011) Some ceramic properties of clays from central Cambodia. Appl Clay Sci 53:33–41. https://doi.org/10.1016/j.clay.2011.04.017
Ntouala RFD, Onana VL, Kamgang V, Ekodeck GE (2016) Mineralogical, geochemical and mechanical characterization of Ayos (East-Cameroun) lateritic and alluvial clayey mixtures: suitability for building application. J Build Eng 5:50–56. https://doi.org/10.1016/j.jobe.2015.11.007
Ntouala RFD, Ndome-Priso E, Nanga Bineli MT, Mutlen JA, Ngo’o Ze A, Onana VL, Ekodeck GE (2023) Mineralogy, geochemistry, and geotechnical characterization of lateritic and alluvial clay deposits from Batouri. East Cameroon. Arab J Geosci 16:355. https://doi.org/10.1007/s12517-023-11451-9
Nzenti JP, Barbey P, Macaudiere J, Soba D (1988) Origin and evolution of the late-Precambrian out grade Yaounde gneisses (Cameroon). Precambrian Res 38:91–109. https://doi.org/10.1016/0301-9268(88)90086-1
Nzeukou Nzeugang A, El Ouahabi M, Aziwol B, Mache JR, MHS M, Fagel N (2018) Characterization of kaolin from Mankon. NW Cameroon. Clay Miner 53:1–29. https://doi.org/10.1180/clm.2018.45
Nzeukou Nzeugang A, Tsozué D, Kagonbé Pagna B,·Balo Madi A, Fankam Deumeni A, Ngos III S, Nkoumbou C, Fagel N (2021) Clayey soils from Boulgou (North Cameroon): geotechnical, mineralogical, chemical characteristics and properties of their fired products SN Appl Sci 3:551. https://doi.org/10.1007/s42452-021-04541-4
Onana VL, Ntouala RFD, Noa Tang S, Ndome Effoudou E, Kabeyene VK, Ekodeck GE (2016) Major, trace and REE geochemistry in contrasted chlorite schist weathering profiles from Southern Cameroon: influence of the Nyong and Dja Rivers water table fluctuations in geochemical evolution processes. J Afr Earth Sci 124:371–382. https://doi.org/10.1016/j.jafrearsci.2016.09.026
Onana VL, Ntouala RFD, Mbey JA, Ngo’o Ze A, Kabeyene VK, Ekodeck GE (2019) Mineralogy and preliminary assessment of the potential uses of alluvial clays from Batouri (Eastern-Cameroon). Cerâmica 65:407–415. https://doi.org/10.1590/0366-69132019653752626
Picard MD (1971) Classification of fine-grained sedimentary rocks. J Sediment Res 41(1):179–195. https://doi.org/10.1306/74D7221B-2B21-11D7-8648000102C1865D
Pourmand A, Dauphas N, Ireland TJ (2012) A novel extraction chromatography and MC-ICP-MS technique for rapid analysis of REE, Sc and Y: revising CI-chondrite and Post-Archean Australian Shale (PAAS) abundances. Chem Geol 291:38–54. https://doi.org/10.1016/j.chemgeo.2011.08.011
Reeves GM, Sims I, Cripps C (2006) Clay materials used in construction. Eng Geol Special Publication, Geol Soc , London. https://doi.org/10.1144/1470-9236/07-108
Roudouane TH, Mbey JA, Bayiga EC, Ndjigui P-D (2020) Characterization and application test of kaolinite clays from Aboudeia (Southeastern Chad) in fired bricks making. Sci Afr 7:e00294. https://doi.org/10.1016/j.sciaf.2020.e00294
Savazzini-Reis A, Possamai DSV, Oliveira DNJ, Teixeira PG (2017) Characterization and evaluation of ceramic properties with spherical and prismatic samples of clay used in red ceramics. Mat Res 20:543–548. https://doi.org/10.1590/1980-5373-MR-2016-0915
Semiz B (2017) Characteristics of clay-rich raw materials for ceramic applications in Denizli region (Western Anatolia). Appl Clay Sci 137:83–93. https://doi.org/10.1016/j.clay.2016.12.014
Singh P (2009) Major, trace and REE geochemistry of the Ganga River: influence on provenance and sedimentary processes. Chem Geol 266:242–255. https://doi.org/10.1016/j.chemgeo.2009.06013
Souza GP, Sanchez R, de Holanda JNF (2002) Characteristics and physical-mechanical properties of fired kaolinitic materials. Cerâmica 48:102–107. https://doi.org/10.1590/S0366-69132002000200009
Tardy Y (1993) Pétrologie des Latérites et des Sols, Tropicaux edn. Masson, Paris
Tsozué D, Nzeukou Nzeugang A, Mache JR, Loweh S, Fagel N (2017) Mineralogical, physico-chemical and technological characterization of clays from Maroua (Far-North, Cameroon) for use in ceramic bricks production. J Build Eng 11:17–24. https://doi.org/10.1016/j.jobe.2017.03.008
Ukwatta A, Mohajerani A (2017) Characterisation of fired-clay bricks incorporating biosolids and the effect of heating rate on properties of bricks. Constr Build Mater 142:11–22. https://doi.org/10.1016/j.conbuildmat.2017.03.047
Vieira CMF, Sanchez R, Monteiro SN (2008) Characteristics of clays and properties of building ceramics in the Rio de Janeiro, Brazil. Constr Build Mater 22:781–787. https://doi.org/10.1016/j.conbuildmat.2007.01.006
Winkler HGF (1954) Bedeutung der korngrössenverteilung und des mineral bestandes von tonen für die herstellung grobkeramischer erzeugnisse. Berichte der Deutschen Keramischen Gesellschaft 31:337–343
Yvon J, Lietard O, Cases JM, Delon J-F (1982) Minéralogie des argiles kaoliniques des Charentes. Bull Minéral 105:431–437
Acknowledgements
This paper is a partial part of the first author’s Ph.D. Thesis at the University of Yaoundé I (Cameroon). The authors express their gratitude to Thierry Adatte (Lausanne, Switzerland) for XRD and XRF analyses; to the Local Materials Promotion Authority (Cameroon) for mechanical tests; and to Pr. Onana Vincent Laurent for its assistance during the field works. The authors thank the Editor-in-Chief (Abdullah M. Al-Amri) and three anonymous reviews for their constructive comments that substantially improved the final version.
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
Conflict of interest
The authors declare no competing interests.
Additional information
Responsible Editor: Domenico M. Doronzo
Rights and permissions
Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.
About this article
Cite this article
Mapuna, E.C.N., Aye, B.A., Ntouala, R.F.D. et al. Mineralogical, geochemical, and physicomechanical features of the Mbalmayo lateritic clays (Southern Cameroon) for potential use as raw materials in the making of fired bricks. Arab J Geosci 16, 671 (2023). https://doi.org/10.1007/s12517-023-11791-6
Received:
Accepted:
Published:
DOI: https://doi.org/10.1007/s12517-023-11791-6