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Hydro-geochemical assessment of an open dumpsite in a basement complex of Abeokuta, Ogun State, Southwestern Nigeria

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Abstract

The study assesses heavy metal concentrations in soil and groundwater samples collected around Saje dumpsite, Abeokuta, Nigeria. Health risks caused by the presence of the heavy metals to the inhabitant of the dumpsite were also evaluated. Sixteen soil samples were collected at depths 0–20, 20–40, 40–60, and 60–80 cm, and 12 groundwater samples were obtained from nearby hand-dug wells for Pb, Fe, Cu, Ni, Zn, and Cd analyses using a flame atomic absorption spectrophotometer. Measured heavy metal concentrations were used to evaluate the health risks. The mean concentrations varied significantly in the soil analysis with Fe having the highest concentration. Control samples had lower concentrations compared with the study samples. The Hazard Index values indicated insignificant non-carcinogenic health risk for children and adults. The carcinogenic health risks associated with Pb and Cd for children were within the acceptable range, while for adults, Cd possesses serious risk, and Pb was within the limit. High concentrations of Pb, Ni, Cd, and Fe were observed to a distance of about 150 m in the groundwater analysis with higher concentrations of Fe. Groundwater contamination index ranged between 1 and 5, indicating slight contaminations. Pb had the highest pollution index, while Ni, Zn, and Cu had the least pollution indices. Samples S3, S4, S6, S9, and S10 indicated unacceptable non-carcinogenic health risks while S1, S2, S5, S7, S8, S11, and S12 indicated acceptable level. The carcinogenic health risks of being exposed to Cd and Pb possess serious health risks. The subsurface had been highly polluted with toxic metals making the soil and groundwater unsuitable for both domestic and agricultural purposes.

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References

  • Abd El-Salam MM, Abu-Zuid GI (2015) Impact of landfill leachate on the groundwater quality: a case study in Egypt. J Adv Res 6(4):579–586

    Google Scholar 

  • Abdullahi NK, Osazuwa IB, Sule PO (2011) Application of integrated geophysical techniques in the investigation of groundwater contamination: a case study of municipal solid waste leachate. Ozean J Appl Sci 4(1):7–25

    Google Scholar 

  • Adamu CI, Nganje TN, Aniekan E (2015) Heavy metal contamination and health assessment associated with abandoned barite mines in Cross River State, southeastern Nigeria. Environ Nanotechnol Monit Manag 3:10–21

    Google Scholar 

  • Adejumo RO, Adagunodo TA, Bility H, Lukman AF, Isibor PO (2018) Physicochemical constituents of groundwater and its quality in crystalline bedrock, Nigeria. Int J Civ Eng Technol 9(8):887–903 ISSN 0976-6308; 0976-6316

    Google Scholar 

  • American Public Health Association (1998) Standard methods for the examination of water and wastewater, 20th edn. APHA, AWWWA, WEF, Washington

    Google Scholar 

  • Amos-Tautua B, Martin W, Onigbinde AO, Ere D (2014) Assessment of some heavy metals and physicochemical properties in surface soils of municipal open waste dumpsite in Yenagoa, Nigeria. Afr J Environ Sci Technol 8(1):4–47

    Google Scholar 

  • Ashutosh M, Kesharwani L, Mishra MK (2018) Analysis of Heavy metal in soil through atomic absorption spectroscopy for forensic consideration. International Journal for Research in Applied Science & Engineering Technology (IJRASET) 6(6):1188–1192 ISSN: 2321-9653

    Google Scholar 

  • Atomic Absorption Spectrometry (2019) The report of The Royal Society of Chemistry Fine Chemicals and Medicinal Group, Education Department, The Royal Society of Chemistry, Burlington House, Piccadilly, London W1J 0BA. http://www.liskeard.cornwall.sch.uk/images/Liskeard-Sixth-Form/Atomic-Absorption-Spectrometry.pdf. Accessed 25 September 2019

  • Awofolu OR (2005) A survey of trace metals in vegetation, soil and lower animals along some selected major roads in metropolitan city of Lagos. Environ Monit Assess 105:431–447

    Google Scholar 

  • Azim MD, Mahabubur Rahman M, Khan RH, Kamal ATMM (2011) Characteristics of leachate generated at landfill sites and probable risks of surface and groundwater pollution in the surrounding areas. A case study of Matuail landfill site, Dhaka. J Bangladesh Acad Sci 35(2):153–160

    Google Scholar 

  • Badejo AA, Taiwo AO, Bada BS, Adekunle AA (2013) Groundwater quality assessment around municipal solid waste dumpsite in Abeokuta, South-West Nigeria. Pac J Sci Technol 14(1):593–603

    Google Scholar 

  • Badmus BS, Ozebo VC, Idowu OA, Ganiyu SA, Olurin OT (2014) Physico-chemical properties of soil samples and dumpsite environmental impact on groundwater quality in South Western Nigeria. Afr Rev Phys 9:103–114

    Google Scholar 

  • Caspah K, Mathuthu M, Madhuku M (2016) Health risk assessment of heavy metals in soils from Witwatersrand gold mining basin, South Africa. Int J Environ Res Public Health 13:663. https://doi.org/10.3390/ijerph13070663

    Article  Google Scholar 

  • Chinwe UO, Obinna NC, Akeem A, Alo BI (2010) Assessment of heavy metals in urban highway runoff from Ikorodu expressway, Lagos, Nigeria. J Environ Chem Ecotoxic 2(3):34–39

    Google Scholar 

  • Daping S, Dafang Z, Dong J, Jingying F, Qiao W (2015) Integrated health risk assessment of heavy metals in Suxian County, South China. Int J Environ Res Public Health 12:7100–7117

    Google Scholar 

  • David OM, Oluyege AO (2014) Effect of open refuse dumpsite on the quality of underground water used for domestic purposes in Ado-Ekiti, Nigeria - a public health awareness study. J Environ Ecol 5(2) ISSN 2157-6092. https://doi.org/10.5296/jee.v5i2.6241

  • Dubey V, Dhanajai S, Aparna P (2014) Chemical studies on dumpsite soils (with specific focus on Cu level) within municipal area of Sidhi Town, District Sidhi (M.P.) India. Orient J Chem 30(4):2077–2079

    Google Scholar 

  • Ejiogu BC, Opara AI, Nwofor OK, Nwosu EI (2017) Geochemical and bacteriological analyses of water resources prone to contamination from solid waste dumpsites in Imo State, Nigeria. J Environ Sci Technol 10(6):325–343

    Google Scholar 

  • El-Hamid HTA, Hegazy TA (2017) Evaluation of water quality pollution indices for groundwater resources of New Damietta, Egypt. MOJ Eco Environ Sci 2(6):00045. https://doi.org/10.15406/mojes.2017.02.00045

    Article  Google Scholar 

  • Environmental Protection Agency, EPA (2012) Channel processes: bed load transport in water: Science & Technology. http://water.epa.gov/scitech/datait/tools/warsss/bedload.cfm. Accessed 10 March 2018

  • Fatoki OS, Lujiza N, Ogunfowokun OA (2005) Trace metal pollution in Umtata river. Water S.A. 28(2):183–189

    Google Scholar 

  • Freeze RA, Cherry JA (1979) Groundwater. Prentice-Hall Inc, Englewood Cliffs 604 pp

    Google Scholar 

  • Ganiyu SA, Badmus BS, Olurin OT, Ojekunle ZO (2018) Evaluation of seasonal variation of water quality using multivariate statistical analysis and irrigation parameter indices in Ajakanga area, Ibadan, Nigeria. Appl Water Sci 8:35. https://doi.org/10.1007/s13201-018-0677-y

    Article  Google Scholar 

  • García R, Báez AP (2012) Atomic absorption spectrometry (AAS), atomic absorption spectroscopy, Dr. Muhammad Akhyar Farrukh (Ed.), ISBN: 978-953-307-817-5, In Tech, http://www.intechopen.com/books/ atomic-absorption-spectroscopy/atomic-absorption-spectrometry-aas. Accessed 30 July 2018

  • Ibeto C, Okoye C, Ofoefule A, Uzodinma E (2012) Analysis of environmental pollutants by atomic absorption spectrophotometry, macro to nano spectroscopy, Dr. Jamal Uddin (Ed.), ISBN: 978-953-51-0664-7, InTech, Available from: http://www.intechopen.com/books/macro-to nanospectroscopy/analysis-of-environmental-pollutants-by-atomic-absorption-spectrophotometry. Accessed 15 October 2019

  • Kayode OT, Okagbue HI, Achuka JA (2018) Water quality assessment for groundwater around a municipal waste dumpsite. Data in Brief 17:579–587. https://doi.org/10.1016/j.dib.2018.01.072

    Article  Google Scholar 

  • Kowalska JB, Mazurek R, Gąsiorek M, Zaleski T (2018) Pollution indices as useful tools for the comprehensive evaluation of the degree of soil contamination - a review. Environ Geochem Health 40:2395–2420

    Google Scholar 

  • Lee JS, Chon HT, Kim KW (2005) Human risk assessment of As, Cd, Cu and Zn in the abandoned metal mine site. Environ Geochem Health 27:185–191

    Google Scholar 

  • Li PH, Kong SF, Geng CM, Han B, Lu B, Sun RF, Bai ZP (2013) Assessing the hazardous risks of vehicle inspection workers’ exposure to particulate heavy metals in their work places. Aerosol Air Qual Res 13:255–265. https://doi.org/10.4209/aaqr.2012.04.0087

    Article  Google Scholar 

  • Lim HS, Lee JS, Chon HT, Sager M (2008) Heavy metal contamination and health risk assessment in the vicinity of the abandoned Soongcheon Au-Ag mine in Korea. J Geochem Explor 96:223–230

    Google Scholar 

  • Mshelia EW, Chindo IY, Ekanem EO, Sanda DB (2014) Assessment of contamination pattern of municipal solid waste dumpsites on arid soil: a comparative study of Maiduguri Metropolis. World J Anal Chem 2(1):1–5

    Google Scholar 

  • Ojo AO (2018) An assessment of selected solid waste dumpsites using integrated geophysical, hydro-geochemical and gamma spectrometric techniques within Abeokuta and Sagamu Metropolises, South-Western Nigeria. Unpublished PhD Thesis, Federal University of Agriculture, Abeokuta, Nigeria

  • Oladunjoye MA, Olayinka AI, Amidu SA (2011) Geoelectrical imaging at an abandoned waste dumpsite in Ibadan, Southwest Nigeria. J Appl Sci 11(22):3755–3766

    Google Scholar 

  • Olafisoye ER, Sunmonu LA, Ojoawo A, Adagunodo TA, Oladejo OP (2012) Application of very low frequency electromagnetic and hydro-physicochemical methods in the investigation of groundwater contamination at Aarada waste disposal site, Ogbomoso, Southwestern Nigeria. Aust J Basic Appl Sci 6(8):401–409

    Google Scholar 

  • Olafisoye ER, Sunmonu LA, Adagunodo TA, Oladejo OP (2013) Groundwater contaminant’s investigation at Aarada waste disposal site using geophysical and hydro-physicochemical approach. IOSR J Environ Sci Toxicol Food Technol 2(4):01–10

    Google Scholar 

  • Olagunju E, Badmus O, Ogunlana F, Babalola M (2018) Environmental impact assessment of waste dumpsite using integrated geochemical and physico-chemical approach: a case study of Ilokun waste dumpsite, Ado-Ekiti, Southern Nigeria. Civ Eng Res J 4(2):001–013. https://doi.org/10.19080/CERJ.2018.04.555631

    Article  Google Scholar 

  • Olivero-Verbel J, Padilla-Bottet C, De la Rosa O (2008) Relationships between physicochemical parameters and the toxicity of leachates from a municipal solid waste landfill. Ecotoxicol Environ Saf 70:294–299

    Google Scholar 

  • Olufisoye OB, Tejumade A, Otolorin AO (2013) Heavy metals contamination of water, soil, and plants around an electronic waste dumpsite. Pol J Environ Stud 22(5):1431–1439

    Google Scholar 

  • Olurin OT, Ganiyu SA, Hammed OS, Aluko TJ (2016) Interpretation of aeromagnetic data over Abeokuta and its environs, Southwest Nigeria, using spectral analysis (Fourier transform technique). RMZ-M&G 63:199–0212. https://doi.org/10.1515/rmzmag-2016-0018

    Article  Google Scholar 

  • Oyedele DJ, Gasu MB, Awotoye OO (2008) Changes in soil properties and plant uptake of heavy metals on selected municipal waste dump sites in Ile Ife, Nigeria. Afr J Environ Sci Technol 3(5):107–117

    Google Scholar 

  • Patil SB, Chore HS (2014) Contaminant transport through porous media: an overview of experimental and numerical studies. Adv Environ Res 3(1):45–69

    Google Scholar 

  • Porteus A (1985) Hazardous waste management handbook. Butterworths and Co. Publishers, London, pp 146–166

    Google Scholar 

  • Rajappa B, Manjappa S, Puttaiah ET (2010) Monitoring of heavy metal concentration in groundwater of Hakinaka Taluk, India. Contemp Eng Sci 3(4):183–190

    Google Scholar 

  • Ruqia N, Muslim K, Muhammad M, Hameed Ur R, Naveed Ur R, Surrya S, Nosheen A, Muhammad S, Mohib U, Muhammad R, Zeenat S (2015) Accumulation of heavy metals (Ni, Cu, Cd, Cr, Pb, Zn, Fe) in the soil, water and plants and analysis of physico-chemical parameters of soil & water collected from Tanda Dam Kohat. J Pharm Sci Res 7(3):89–97

  • Shemang YC (2016) Determination of Some heavy metals in dumpsite soil and Abelmochus esculentus fruit grown near dumpsites in Kafanchan Metropolis, Kaduna State, Nigeria. Published M.Sc. Dissertation, Ahmadu Bello University, Zaria, Nigeria

  • Standard Organization of Nigeria, SON (2007) Nigeria industrial standard for natural mineral water. NIS 345

  • Sudhakar G, Swarna latha G, Vijayakumar G, Brahmaji Rao P, Venkatarathnamma V (2015) Application of Nemerow’s pollution index (NPI) for groundwater quality assessment of Bapatla Mandal west region, coastal Andhra Pradesh, India. Int J Appl Sci Eng Res 4(4):500–506

    Google Scholar 

  • Sundaray SK, Nayak BB, Lin S, Bhatta D (2011) Geochemical speciation and risk assessment of heavy metals in the river estuarine sediments-a case study: Mahanadi Basin, India. J Hazard Matter 186:1837–1846

    Google Scholar 

  • Sunmonu LA, Olafisoye ER, Adagunodo TA, Alagbe OA (2013) Geophysical and hydro-physicochemical evaluation of hand-dug wells near a dumpsite in Oyo State, Nigeria. Arch Appl Sci Res 5(6):29–40

    Google Scholar 

  • Tesfaye Z (2007) Groundwater pollution and public health risk analysis in the vicinity of Reppi solid waste dumpsite, Addis Ababa City, Ethiopia. Unpublished M.Sc. Thesis, Addis Ababa University, Ethiopia

  • The Centre for International Law (2008) International transport for lead and cadmium via trade: an international concern? Inter gov. forum on Chemical Safety. Six Sessions, Agenda Item 8:10

  • Tijani MN, Onodera S (2009) Hydrogeochemical assessment of metals contamination in an urban drainage system: a case study of Osogbo Township, SW-Nigeria. J Water Resource Protect 3:164–173

    Google Scholar 

  • U.S. Environmental Protection Agency (USEPA 2004) Risk assessment guidance for superfund volume I: human health evaluation manual (Part E, Supplemental guidance for dermal risk assessment); Washington, DC, USA

  • U.S. Environmental Protection Agency USEPA (2007) Framework for metals risk assessment. Office of the Science Advisor, Risk Assessment Forum, Washington, DC 20460. EPA 120/R-07/00. www.epa.gov/osa 172 pp. Accessed 20 June 2017

  • U.S. Environmental Protection Agency’s Integrated Risk Information System, USEPA IRIS (2011). Environmental Protection Agency Region I, Washington DC 20460 Available from http://wwwepagov/iris/ Accesses 20 June 2017

  • Ujile AA, Omo-irabor OO, Ogbonna J (2012) Groundwater contamination at waste disposal sites at Ibadan, Nigeria. J Solid Waste Technol Manag 38(3):149–156

    Google Scholar 

  • Water Stewardship Information Series (2007) Iron and manganese in groundwater. British Columbia: The British Columbia Ground Water Association. Available from http://www.env.gov.bc.ca/wsd/plan_protect_sustain/groundwater/library/ground_fact_sheets/pdfs/fe_mg(280717)_fin2.pdf. Accessed 28 February 2017

  • Wongsasuluk P, Chotpantarat S, Siriwong W, Robson M (2014) Heavy metal contamination and human health risk assessment in drinking water from shallow groundwater wells in an agricultural area in Uban Ratchathani province, Thailand. Environ Geochem Health 36(1):169–182. https://doi.org/10.1007/s10653-013-9537-8

  • World Health Organization, WHO (2011) Guidelines for drinking water quality, 4th edn. WHO Library Cataloguing-in-Publication Data

  • Yang G, Chaofeng S, Meiting J (2014) Heavy metal contamination assessment and partition for industrial and mining gathering areas. Int J Environ Res Public Health 11:7286–7303

    Google Scholar 

  • Ying H, Li YX, Yang J (2015) Harmful chemicals in soil and risk assessment of an abandoned open dumpsite in Eastern China. J Chem:297686 10 pp. https://doi.org/10.1155/2015/297686

  • Young E, Tarawou T (2014) Determination of metals in pepper by flame atomic absorption spectroscopy. Int J Biol Chem Sci 8(6):2891–2895

    Google Scholar 

  • Yu F, Tingping Z, Mengtong L, Jieyi H, Ruixue H (2017) Heavy metal contamination in soil and brown rice and human health risk assessment near three mining areas in Central China. J Healthc Eng:4124302 9 pp. https://doi.org/10.1155/2017/4124302

  • Yusuf AJ, Galadima A, Garba ZN, Nasir I (2015) Determination of some heavy metals in soil sample from Illela Garage in Sokoto State, Nigeria. Res J Chem Sci 5(2):8–10

    Google Scholar 

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Ojo, A.O., Olurin, O.T., Ganiyu, S.A. et al. Hydro-geochemical assessment of an open dumpsite in a basement complex of Abeokuta, Ogun State, Southwestern Nigeria. Arab J Geosci 13, 620 (2020). https://doi.org/10.1007/s12517-020-05651-w

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