Skip to main content
Log in

Mount Etna volcano (Italy) as a major “dust” point source in the Mediterranean area

  • Original Paper
  • Published:
Arabian Journal of Geosciences Aims and scope Submit manuscript

Abstract

Volcanic emissions represent one of the most relevant natural sources of trace elements to the troposphere. Due to their potential toxicity, they may have important environmental impacts from local to global scale. They can also severely affect the atmospheric and terrestrial environment at timescales ranging from a few to millions of years. Mt. Etna volcano is known as one of the largest global contributors of magmatic gases (CO2, SO2 and halogens) and particulate matter, including some toxic trace elements. The aim of this study is to characterize the chemical composition and the mineralogical features of the volcanogenic aerosol passively emitted from Mt. Etna. Twenty-five samples were collected by filtration technique from different sites between 2008 and 2014. Chemical and mineralogical analyses allowed to discriminate two main constituents: the first is mainly referable to the silicate component in the volcanic plume, like lithic, juvenile fragments or glass shards and crystals (e.g. plagioclases, pyroxenes, oxides); the second constituent consists of soluble compounds like sulphosalts or halide minerals (sulphates, chlorides and fluorides). Fluxes of major and trace metals emitted in the atmosphere have been estimated. By comparing the Etnean trace elements with those from European anthropic emissions, we conclude that Mt. Etna is the main persistent point source of major and trace metals in the Mediterranean region. Results gathered from this investigation is of fundamental importance due to the exposure and potential impact of harmful chemical compounds for hundred thousand tourist visits each year to the summit of Mt. Etna.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8

Similar content being viewed by others

References

  • Aiuppa A, Federico C, Paonita A, Pecoraino G, Valenza M (2002) S, Cl and F degassing as an indicator of volcanic dynamics: the 2001 eruption of Mount Etna. Geophys Res Lett 29(11):15529. doi:10.1029/2002GL015032

    Article  Google Scholar 

  • Aiuppa A, Dongarrà G, Federico C, Pecoraino G, Valenza M (2003) Degassing of trace volatile metals during the 2001 eruption of Etna. In: Robock A, Oppenheimer C (eds) Volcanism and the Earth’s Atmosphere. Geophysical Monograph, p 139

  • Bonaccorso A, Caltabiano T, Currenti G, Del Negro C, Gambino S, Ganci T, Giammanco S, Greco F, Pistorio A, Salerno G, Spampinato S, Boschi E (2011) Dynamics of a lava fountain revealed by geophysical, geochemical and thermal satellite measurements: the case of 10 April 2011 Mt. Etna eruption. Geophys Res Lett 38:L24307. doi:10.1029/2011GL049637

    Article  Google Scholar 

  • Buat-Menard P, Arnord M (1978) The heavy metal chemistry of atmospheric particulate matter emitted by Mount Etna Volcano. Geophys Res Lett 5(4):245–248

  • Cadle RD (1980) Some effects of the emissions of explosive volcanoes on the stratosphere. J Geophys Res 85(C8):4495–4498

  • Calabrese S, D’Alessandro W (2015) Characterization of the Etna volcanic emissions through an active biomonitoring technique (moss-bags): part 2—Morphological and mineralogical features. Chemosphere 119:1456–1464

    Article  Google Scholar 

  • Calabrese S, Aiuppa A, Allard P, Bagnato E, Bellomo S, Brusca L, D’Alessandro W, Parello F (2011) Atmospheric sources and sinks of volcanogenic elements in a basaltic volcano (Etna, Italy). Geochim Cosmochim Acta 75:7401–7425

    Article  Google Scholar 

  • Calabrese S, D’Alessandro W, Bellomo S, Brusca L, Martin RS, Saiano F, Parello F (2015) Characterization of the Etna volcanic emissions through an active biomonitoring technique (moss-bags): part 1—major and trace element composition. Chemosphere 119:1447–1455

    Article  Google Scholar 

  • Caltabiano T, Burton M, Giammanco S, Allard P, Bruno N, Murè F, Romano R (2004) Volcanic gas emission from the summit craters and flanks of Mt. Etna, 1987–2000, in Mt. Etna: Volcano Laboratory, Geophys. Monogr. Ser., vol 143, (eds Calvari et al) pp. 111–128, AGU, Washington, D.C

  • Campion R, Salerno GG et al (2010) Measuring of volcano degassing of SO2 in the lower troposphere with ASTER band measurements. J Volcanol Geotherm Res 194:42–54

    Article  Google Scholar 

  • Erfurt-Cooper P, Cooper M (2010) Volcano and geothermal tourism. Earthscan, London, p 378

    Google Scholar 

  • Floor GH, Calabrese S, Román-Ross G, Aiuppa A (2011) Selenium mobilization in soils due to volcanic derived acid rain: an example from Mt Etna volcano, Sicily. Chem Geol 289(3):235–244

    Article  Google Scholar 

  • Gauthier P-J, Le Cloarec M-F (1998) Variability of alkali and heavy metal fluxes released by Mt. Etna volcano, Sicily, between 1991 and 1995. J Volcanol Geotherm Res 81:311–326

    Article  Google Scholar 

  • Hinkley TK, Lamothe PJ, Wilson SA, Finnegan DL, Gerlach TM (1999) Metal emissions from Kilauea, and a suggested revision of the estimated worldwide metal output by quiescent degassing of volcanoes. Earth Planet Sci Lett 170:315–325

    Article  Google Scholar 

  • La Spina A, Burton M, Salerno GG (2010) Unravelling the processes controlling gas emissions from the central and northeast craters of Mt. Etna. J Volcanol Geotherm Res. doi:10.1016/j.jvolgeores.2010.09.018

    Google Scholar 

  • Martin RS, Mather TA, Pyle DM, Watt SFL, Day J, Collins SJ, Wright TE, Aiuppa A, Calabrese S (2009) Sweet chestnut (Castanea sativa) leaves as a bio- indicator of volcanic gas, aerosol and ash deposition onto the flanks of Mt. Etna in 2005–2007. J Volcanol Geotherm Res 179:107–119. doi:10.1016/j.jvolgeores.2008.10.012

    Article  Google Scholar 

  • Merucci L, Burton M, Corradini S, Salerno GG (2011) Reconstruction of SO2 flux emission chronology from space-based measurements. J Volcanol Geotherm Res. doi:10.1016/j.jvolgeores.2011.07.002

    Google Scholar 

  • Montana G, Randazzo L, Mazzoleni P (2012) Natural and anthropogenic sources of total suspended particulate and their contribution to the formation of black crusts on building stone materials of Catania (Sicily). Environ Earth Sci 67:1097–1110

    Article  Google Scholar 

  • Moune S, Gauthier P-J, Delmelle P (2010) Trace elements in the particulate phase of the plume of Masaya Volcano, Nicaragua. J Volcanol Geotherm Res 193(2010):232–244. doi:10.1016/j.jvolgeores.2010.04.004

    Article  Google Scholar 

  • Nriagu JO (1989) A global assessment of natural sources of atmospheric trace metals. Nature 338:47–49

  • Oppenheimer C (2003) Volcanic degassing. In: The crust (ed RL Rudnick) vol 3, Treatise on geochemistry (eds HD Holland & KK Turekian), Elsevier-Pergamon, Oxford, pp 123–166

  • Patanè D, Aiuppa A, Aloisi M, Behncke B, Cannata A, Coltelli M, Di Grazia G, Gambino S, Gurrieri S, Mattia M, Salerno G (2013) Insights into magma and fluid transfer at Mount Etna by a multi-parametric approach: a model of the events leading to the 2011 eruptive cycle. J Geophys Res Solid Earth 118:1–21. doi:10.1002/jgrb.50248

    Article  Google Scholar 

  • Salerno GG, Burton MR, Oppenheimer C, Caltabiano T, Tsanev V, Bruno N (2009a) Novel retrieval of volcanic SO2 abundance from ultraviolet spectra. J Volcanol Geotherm Res 181:141–153. doi:10.1016/j.jvolgeores.2009.01.009

    Article  Google Scholar 

  • Salerno GG, Burton M, Oppenheimer C, Caltabiano T, Randazzo D, Bruno N (2009b) Three-years of SO2 flux measurements of Mt. Etna using an automated UV scanner array: comparison with conventional traverses and uncertainties in flux retrieval. J Volcanol Geotherm Res 183:76–83. doi:10.1016/j.jvolgeores.2009.02.013

    Article  Google Scholar 

  • Spampinato L, Sciotto M, Cannata A, Cannavo F, La Spina A, Palano M, Salerno GG, Privitera E, Caltabiano T (2015) Multiparametric study of the February–April 2013 paroxysmal phase of Mt. Etna New South-East crater. Geochem Geophys Geosyst 16:1932–1949. doi:10.1002/2015GC005795

    Article  Google Scholar 

  • Tassi F, Capecchiacci F, Cabassi J, Calabrese S, Vaselli O, Rouwet D, Pecoraino G, Chiodini G (2012) Geogenic and atmospheric sources for VOCs (Volatile Organic Compounds) in fumarolic emissions from Mt. Etna and Vulcano Island (Sicily, Italy). J Geophys Res 117:D17305

    Google Scholar 

  • Wang X, Boselli A, D’Avino L, Pisani G, Spinelli N, Amodeo A, Chaikovsky A et al (2008) Volcanic dust characterization by EARLINET during Etna’s eruptions in 2001–2002. Atmos Environ 42(5):893–905

    Article  Google Scholar 

  • Wittmer J, Bobrowski N, Liotta M, Giuffrida G, Calabrese S, Platt U (2014) Active alkaline traps to determine acidic-gas ratios in volcanic plumes: Sampling techniques and analytical methods. Geochem Geophys Geosyst 15. doi:10.1002/2013GC005133

Download references

Acknowledgments

Part of the data presented in this work was obtained during the “Mt. Etna-Pizzi Deneri field trips” of the years 2010–2014 organized and supported by the Università degli Studi di Palermo (DiSTeM) and the Istituto Nazionale di Geofisica e Vulcanologia (INGV) of Catania and Palermo.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to S. Calabrese.

Additional information

This article is part of the Topical Collection on DUST

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Calabrese, S., Randazzo, L., Daskalopoulou, K. et al. Mount Etna volcano (Italy) as a major “dust” point source in the Mediterranean area. Arab J Geosci 9, 219 (2016). https://doi.org/10.1007/s12517-015-2165-0

Download citation

  • Received:

  • Accepted:

  • Published:

  • DOI: https://doi.org/10.1007/s12517-015-2165-0

Keywords

Navigation