Skip to main content
Log in

Time-dependent physicochemical characteristics of Malaysian residual soil stabilized with magnesium chloride solution

  • Original Paper
  • Published:
Arabian Journal of Geosciences Aims and scope Submit manuscript

Abstract

The effects of non-traditional additives on the geotechnical properties of tropical soils have been the subject of investigation in recent years. This study investigates the strength development and micro-structural characteristics of tropical residual soil stabilized with magnesium chloride (MgCl2) solution. Unconfined compression strength (UCS) and standard direct shear tests were used to assess the strength and shear properties of the stabilized soil. In addition, the micro-structural characteristics of untreated and stabilized soil were discussed using various spectroscopic and microscopic techniques such as X-ray diffractometry (XRD), energy-dispersive X-ray spectrometry (EDAX), field emission scanning electron microscopy (FESEM), Fourier transform infrared spectroscopy (FTIR) and Brunauer, Emmett and Teller (BET) surface area analysis. From the engineering point of view, the results indicated that the strength of MgCl2-stabilized soil improved noticeably. The degree of improvement was approximately two times stronger than natural soil after a 7-day curing period. The results also concluded the use of 5 % of MgCl2 by dry weight of soil as the optimum amount for stabilization of the selected soil. In addition, the micro-structural study revealed that the stabilization process modified the porous network of the soil. The pores of the soils had been filled by the newly formed crystalline compounds known as magnesium aluminate hydrate (M-A-H).

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11

Similar content being viewed by others

References

  • Ahmad F, Atemimi YK, Ismail MAM (2013) Evaluation the effects of styrene butadiene rubber addition as a new soil stabilizer on geotechnical properties. Electronic Journal of Geotechnical Engineering 18:735–748

    Google Scholar 

  • Ahmad KB, Taha MR, Kassim KA (2010) Electrokinetic treatment on a tropical residual soil. Proceedings of the ICE-Ground Improvement 164(1):3–13

    Article  Google Scholar 

  • Acaz, A (2011) The effect of magnesium chloride solution on swell, dispersibility and strength characteristics of problematic clay soil (in Turkish with English Abstract). (M.Sc. Thesis) Eskisehir Osmangazi University, Graduate School of Natural and Applied Sciences, Eskisehir, Turkey

  • ASTM D3080 / D3080M - 11 Standard Test Method for Direct Shear Test of Soils Under Consolidated Drained Conditions. ASTM International, West Conshohocken, PA, DOI: 10.1520/D3080_D3080M-11

  • Blanck, G., Cuisinier, O., and Masrouri, F (2013) Soil treatment with organic non-traditional additives for the improvement of earthworks. Acta Geotechnica. 1–12

  • Bobet A, Hwang J, Johnston CT, Santagata M (2011) One-dimensional consolidation behavior of cement-treated organic soil. Canadian Geotechnical Journal 48(7):1100–1115

    Article  Google Scholar 

  • Chang I, Cho GC (2012) Strengthening of Korean residual soil with β- 1,3/1,6-glucan biopolymer. Construction and Building Materials 30:30–35

    Article  Google Scholar 

  • British Standards Institution (1990a) British Standard methods of test for soils for civil engineering purposes: Part 2, Classification tests. London, BS1377

  • British Standards Institution (1990b) British Standard methods of test for soils for civil engineering purposes: Part4, Compaction-related tests. London, BS1377

  • British Standards Institution (1990c) British Standard methods of test for civil engineering purposes: Part 7, shear strength tests (total stress). London, BS1377

  • Canada E (2001) Canadian Environmental Protection Act, 1999: priority substance list assessment report—road salts. Environmental Canada, Hull

    Google Scholar 

  • Eisazadeh A, Kassim KA, Nur H (2011) Characterization of phosphoric acid- and lime-stabilized tropical lateritic clay. Environmental Earth Sciences 63(5):1057–1066

    Article  Google Scholar 

  • Eisazadeh A, Kassim KA, Nur H (2012) Stabilization of tropical kaolin soil with phosphoric acid and lime. Natural hazards 61(3):931–942

    Article  Google Scholar 

  • Eisazadeh A, Kassim KA, Nur H (2013) Morphology and BET surface area of phosphoric acid stabilized tropical soils. Engineering Geology 154:36–41

    Article  Google Scholar 

  • Fon CL (2010) Stabilization of earth roadbed for road building using Probase soil stabilizer. Electronic Journal of Geotechnical Engineering 15:1793–1814

    Google Scholar 

  • Goodrich BA, Koski RD, Jacobi WR (2009) Condition of soils and vegetation along roads treated with magnesium chloride for dust suppression. Water, air, and soil pollution 198(1–4):165–188

    Article  Google Scholar 

  • Ganesh I, Bhattacharjee S, Saha BP, Johnson R, Mahajan YR (2001) A new sintering aid for magnesium aluminate spinel. Ceramics international 27(7):773–779

    Article  Google Scholar 

  • Gadsen JA (1975) Infrared spectra of minerals and related inorganic compounds. Butterworths, London

    Google Scholar 

  • García Lodeiro I, Macphee DE, Palomo A, Fernández-Jiménez A (2009) Effect of Alkalis on Fresh C–S–H Gels. FTIR Analysis. Cement and Concrete Research 39(3):147–153

    Article  Google Scholar 

  • Gidigasu MD (1972) Mode of formation and geotechnical characteristics of laterite materials of Ghana in relation to soil forming factors. Engineering Geology 6(2):79–150

    Article  Google Scholar 

  • Harrison AJW (2008) U.S. Patent No. 7,347,896. DC: U.S. Patent and Trademark Office, Washington

    Google Scholar 

  • Hafez, M. A., Sidek, N., and Md. Noor, M. J (2008) Effect of pozzolanic process on the strength of stabilized lime clay. Electronic Journal of Geotechnical Engineering. 13:1–19

  • Horpibulsuk S, Katkan W, Apichatvullop A (2008) An approach for assessment of compaction curves of fine-grained soils at various energies using a one point test. Soils and Foundations 48(1):115–125

    Article  Google Scholar 

  • Horpibulsuk S, Katkan W, Naramitkornburee A (2009) Modified Ohio’s curves: a rapid estimation of compaction curves for coarse- and fine-grained soils Geotechnical Testing Journal. ASTM 32(1):64–75

    Google Scholar 

  • Jianli M, Youcai Z, Jinmei W, Li W (2010) Effect of magnesium oxychloride cement on stabilization/solidification of sewage sludge. Construction and Building Materials 24(1):79–83

    Article  Google Scholar 

  • JCPDS (1995) Index to the powder diffraction file. International Center for Diffraction Data. International Center for Diffraction Data, Swarthmore

    Google Scholar 

  • Jayaseelan DD, Zhang S, Hashimoto S, Lee WE (2007) Template formation of magnesium aluminate (MgAl2O4) spinel microplatelets in molten salt. Journal of the European Ceramic Society 27(16):4745–4749

    Article  Google Scholar 

  • Ketcham, S.A., Minsk, D.L., Blackburn, R.R., Fleege, E.J (1996) Manual of practice for an effective anti-icing program: a guide for highway winter maintenance personnel (report no: FHWA-RD-95-202). A Report Presented to Federal Highway Administration by US Army Cold Regions Research and Engineering Laboratory, Hanover, New Hampshire

  • Katz LE, Rauch AF, Liljestrand HM, Harmon JS, Shaw KS, Albers H (2007) Mechanisms of soil stabilization with liquid ionic stabilizer. Transp Res Rec: J Transp Res Board 1757(1):50–57

    Google Scholar 

  • Kassim KA, Kok KC (2004) Lime stabilized Malaysian cohesive soils. Jurnal Kejuruteraan Awam 16(1):13–23

    Google Scholar 

  • Katz LE, Rauch AF, Liljestrand HM, Harmon JS, Shaw KS, Albers H (2001) Mechanisms of soil stabilization with liquid ionic stabilizer. Transp Res Rec: J Transp Res Board 1757(1):50–57

    Article  Google Scholar 

  • Latifi N, Marto A, Eisazadeh A (2013) Structural characteristics of laterite soil treated by SH-85 and TX-85 (non-traditional) stabilizers. EJGE 18:1707–1718

    Google Scholar 

  • Latifi N, Eisazadeh A, Marto A (2014) Strength behavior and micro-structural characteristics of tropical laterite soil treated with sodium silicate-based liquid stabilizer. Environmental Earth Sciences 72(1):91–98

    Article  Google Scholar 

  • Latifi N, Marto A, Eisazadeh A (2015a) Analysis of strength development in non-traditional liquid additive-stabilized laterite soil from macro-and micro-structural considerations. Environmental Earth Sciences 73(3):1133–1141

    Article  Google Scholar 

  • Latifi N, Marto A, Eisazadeh A (2015b) Physicochemical behavior of tropical laterite soil stabilized with non-traditional additive. Acta Geotechnica. doi:10.1007/s11440-015-0370-3

    Google Scholar 

  • Latifi N, Marto A, Rashid A, Yii J (2015c) Strength and physico-chemical characteristics of fly ash-bottom ash mixture. Arabian Journal for Science and Engineering 40(9):2447–2455

    Article  Google Scholar 

  • Liu J, Shi B, Jiang H, Huang H, Wang G, Kamai T (2011) Research on the stabilization treatment of clay slope topsoil by organic polymer soil stabilizer. Engineering Geology 117(1):114–120

    Article  Google Scholar 

  • Marto A, Latifi N, Eisazadeh A (2014) Effect of non-traditional additives on engineering and microstructural characteristics of laterite soil. Arabian Journal for Science and Engineering 39(10):6949–6958

    Article  Google Scholar 

  • Mitchell JK, Soga K (2005) Fundamentals of soil behavior, 3rd edn. John Wiley and Sons, New York

    Google Scholar 

  • Madejova J, Komadel P (2001) Baseline studies of the clay minerals society source clays: infrared methods. Clays and Clay Minerals 49(5):410–432

    Article  Google Scholar 

  • Nixon WA, Williams AD (2001) A guide for selecting anti-icing chemicals version 1.0 (report no: 420). A Technical Report Prepared by Hydroscience and Engineering Department of University of Iowa, Iowa City

    Google Scholar 

  • Obuzor GN, Kinuthia JM, Robinson RB (2012) Soil stabilization with lime-activated-GGBS—a mitigation to flooding effects on road structural layers/embankments constructed on floodplains. Engineering Geology 151:112–119

    Article  Google Scholar 

  • Piechota, T., van Ea, J., Batista, J., Stave, K., & James, D. (Eds.) (2004) Potential environmental impacts of dust suppressants: avoiding another times beach: an expert panel summary, Las Vegas, NV. May 30–31, 2002. USEPA. EPA 600/R-04/031

  • Pal S, Bandyopadhyay AK, Mukherjee S, Samaddar BN, Pal PG (2010a) Function of magnesium aluminate hydrate and magnesium nitrate as MgO addition in crystal structure and grain size control of α-Al2O3 during sintering. Bulletin of Materials Science 33(1):55–63

    Article  Google Scholar 

  • Pal S, Bandyopadhyay AK, Mukherjee S, Samaddar BN, Pal PG (2010b) Effect of agglomeration during coprecipitation: delayed spinellization of magnesium aluminate hydrate. Bulletin of Materials Science 33(4):451–456

    Article  Google Scholar 

  • Quantachrome Corporation (2007) Autosorb-1 series Manual. 1008 07101 REV. A

  • Rauch AF, Harmon JS, Katz LE, Liljestrand HM (2002) Measured effects of liquid soil stabilizers on engineering properties of clay. Transp Res Rec: J Transp Res Board 1787(1):33–41

    Article  Google Scholar 

  • Randolph RB (1997) Earth materials catalyst stabilization for road bases, road shoulders, unpaved roads, and transportation earthworks. Transportation Research Record 1589, TRB. National Research Council, Washington, pp 58–63

    Google Scholar 

  • Singh V, Piechota T, James D (2003) Hydrologic impacts of disturbed lands treated with dust suppressants. Journal of Hydraulic Engineering 8:278–286

    Google Scholar 

  • Salih, A. G (2012) Review on granitic residual soils’ geotechnical properties. Electronic Journal of Geotechnical Engineering. 2645–2658

  • Sukmak P, Horpibulsuk S, Shen SL, Chindaprasirt P, Suksiripattanapong C (2013) Factors influencing strength development in clay–fly ash geopolymer. Construction and Building Materials 47:1125–1136

    Article  Google Scholar 

  • Turkoz M, Vural P (2013) The effects of cement and natural zeolite additives on problematic clay soils. Sci Eng Compos Mater 20(4):395–405

    Article  Google Scholar 

  • Tingle JS, Newman JK, Larson SL, Weiss CA, Rushing JF (1989) Stabilization mechanisms of nontraditional additives. Transp Res Rec: J Transp Res Board 1:59–67

    Google Scholar 

  • Tingle JS, Santoni RL (2003) Stabilization of clay soils with nontraditional additives. Transp Res Rec: J Transp Res Board 1819(1):72–84

    Article  Google Scholar 

  • Turkoz M, Savas H, Acaz A, Tosun H (2014) The effect of magnesium chloride solution on the engineering properties of clay soil with expansive and dispersive characteristics. Applied Clay Science 101:1–9

    Article  Google Scholar 

  • Thenoux G, Vera S (2002) Evaluación de la efectividad del cloruro de magnesio hexahidratado (Bischofita) como estabilizador químico de capas de rodadura granulares. Materiales de Construcción 52(265):5–22

    Article  Google Scholar 

  • Transportation Research Board (1991) Special report 235: highway deicing, comparing salt and calcium magnesium acetate. Committee on the Comparative Cost of Rock Salt and Calcium Magnesium Acetate (CMA) for Highway Deicing National Research Council, Washington

    Google Scholar 

  • Turkoz M, Tosun H (2011) A GIS model for preliminary hazard assessment of swelling clays, a case study in Harran Plain (SE Turkey). J Environ Earth Sci 63:1343–1353

    Article  Google Scholar 

  • Townsend FC (1985) Geotechnical characteristics of residual soils. Journal of Geotechnical Engineering 111(1):77–94

    Article  Google Scholar 

  • Zelalem A (2005) Basic engineering properties of lateritic soils found in Nejo– Mendi Road Construction Area, Welega. M. Sc. Thesis. Department of Civil Engineering, Addis Ababa University, Ethiopia

    Google Scholar 

  • Zhu ZD, Liu SY (2008) Utilization of a new soil stabilizer for silt subgrade. Engineering Geology 97(3):192–198

    Article  Google Scholar 

  • Zhang T, Xu YY, Wang H (2012) Application and curing mechanism of soil stabilizer. Advanced Materials Research 557:809–812

    Article  Google Scholar 

Download references

Acknowledgments

The authors wished to acknowledge the financial supports given by the Ministry of Education Malaysia under the Fundamental Research Grant (FRGS), R.J130000.7822.4F658, and the supports from Universiti Teknologi Malaysia (UTM) and Construction Research Centre UTM.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Ahmad Safuan A. Rashid.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Latifi, N., Rashid, A.S.A., Ecemis, N. et al. Time-dependent physicochemical characteristics of Malaysian residual soil stabilized with magnesium chloride solution. Arab J Geosci 9, 58 (2016). https://doi.org/10.1007/s12517-015-2100-4

Download citation

  • Received:

  • Accepted:

  • Published:

  • DOI: https://doi.org/10.1007/s12517-015-2100-4

Keywords

Navigation