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Levels of Arsenic and Other Trace Elements in Southern Libyan Agricultural Irrigated Soil and Non-irrigated Soil Projects

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Abstract

The levels of As and various other trace elements found in the irrigated agricultural soil (T soil) of southern Libya were compared with non-irrigated soil (C soil) from the same sampling campaign collected between April and May 2008. The soil samples represented agronomic practice in the southern Libyan regions of Maknwessa (MAK), Aril (ARL) and Taswaa (TAS), and were analyzed by Inductively coupled plasma mass spectrometry (ICP-MS) for Co, Ni, Cu, Se, Mo, Zn, As, Pb, Cd and P. Concentrations of P and As in TAS and MAK were found to be higher in T soil compared to C soil, while the opposite was true for ARL. In general, As concentrations in these areas were 2–3 times lower than the global average. In ARL, the average P concentrations of the C soil samples were significantly higher than those of T soil samples: this site is composed mainly of pasture for animal production, where phosphate fertilizers are used regularly. Distance from the source of irrigation was found to be of an important influence on the heavy metal concentration of the soil, with greater concentrations found closer to the irrigation source. It can be concluded from the results that irrigation water contains elevated levels of As, which finds its way into the soil profile and can lead to accumulation of As in the soil over time.

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References

  • Abdelrhem IM, Rashid K, Ismail A (2009) Simulation of groundwater level at Murzuk Dasin due to great man-made river project, Libya. Eur J Sci Res 26:522–531

    Google Scholar 

  • Beke GJ, Entz T, Graham DP (1993) Long-term quality of shallow ground water at irrigated sites. J Irrig Drain 119:116–128. doi:10.1061/(ASCE)0733-9437(1993)119:1(116)

    Article  Google Scholar 

  • Crossley R, McDougall N (1998) Lower palaeozoic reservoirs of North Africa. Geological society special publication, no 132, pp 157–166

  • Csiki SJC, Martin CW (2008) Spatial variability of heavy-metal storage in the floodplain of the Alamosa River, Colorado. Phys Geog 29:306–19. doi:10.2747/0272-3646.29.4.306

    Article  Google Scholar 

  • De Vera MR (1984) Rainfall-runoff relationship of some catchments with karstic geomorphology under arid to semi-arid conditions (Libya). J Hydrol 68:85–93. doi:10.1016/0022-1694(84)90205-1

    Article  Google Scholar 

  • El-Ghawi U, Pátzay G, Vajda N, Bódizs D (1999) Analysis of selected fertilizers imported to Libya for major, minor, trace and toxic elements using ICP-OES and INAA. J Radioanal Nucl Chem 242:693–701. doi:10.1007/BF02347381

    Article  CAS  Google Scholar 

  • El-Tantawl A (1998) Water resources in Libya (applied study). MSc dissertation, Institute of African Researches and Studies, Cairo University (in Arabic)

  • He ZL, Yang XE, Stoffella PJ (2005) Trace elements in agroecosystems and impacts on the environment. J Trace Elem Med Biol 19:125–40. doi:10.1016/j.jtemb.2005.02.010

    Article  CAS  Google Scholar 

  • Hossain MB, Jahiruddin M, Panaullah GM, Loeppert RH, Islam MR, Duxbury JM (2008) Spatial variability of arsenic concentration in soils and plants, and its relationship with iron, manganese and phosphorus. Environ Pollut 156:739–44. doi:10.1016/j.envpol.2008.06.015

    Article  CAS  Google Scholar 

  • Huang SW, Jin JY (2008) Status of heavy metals in agricultural soils as affected by different patterns of land use. Environ Monit Assess 139:317–327. doi:10.1007/s10661-007-9838-4

    Article  CAS  Google Scholar 

  • Huda FS (2004) Development of rural areas and societies in Libya. PhD dissertation, Szent Istvan University

  • Lindberg SE, Zhang H, Gustin M et al. (1999) Increases in mercury emissions from desert soils in response to rainfall and irrigation. J Geophys Res D Atmos 104:21879–21888. doi:10.1016/j.atmosenv.2005.07.064

    Article  CAS  Google Scholar 

  • Lopez-Bellido L, Lopez-Bellido RJ, Castillo JE, Lopez-Bellido FJ (2000) Effects of tillage, crop rotation, and nitrogen fertilization on wheat under rainfed Mediterranean conditions. Agron J 92:1054–1063. doi:10.1016/j.eja.2007.05.008

    Article  Google Scholar 

  • Loska K, Wiechuła D (2003) Application of principal component analysis for the estimation of source of heavy metal contamination in surface sediments from the Rybnik reservoir. Chemosphere 51:723–733. doi:10.1016/S0045-6535(03)00187-5

    Article  CAS  Google Scholar 

  • McBride MB, Spiers G (2001) Trace element content of selected fertilizers and dairy manures as determined by ICP-MS. Commun Soil Sci Plant Anal 32:139–156. doi:10.1081/CSS-100102999

    Article  CAS  Google Scholar 

  • Meharg AA, Williams PN, Adomako E et al. (2009) Geographical variation in total and inorganic arsenic content of polished (white) rice. Environ Sci Technol 43:1612–1617. doi:10.1021/es802612a

    Article  CAS  Google Scholar 

  • Mortvedt JJ (1996) Heavy metal contaminats in inorganic and organic fertilizers. Fertil Res 43:55–61. doi:10.1007/BF00747683

    Article  Google Scholar 

  • Oweis T, Ziedan H, Taimeh A (1992) Modeling approach for optimizing supplemental irrigation management. In: Proceedings of the international conference on supplementary irrigation and drought water management. Istituto Agronomico Mediterraneo, Valenzano

    Google Scholar 

  • Phosyn (2005) Wadi aril production project. Phosyn, York

    Google Scholar 

  • Rafique E, Rashid A, Ryan J, Bhatti AU (2006) Zinc deficiency in rainfed wheat in Pakistan: magnitude, spatial variability, management, and plant analysis diagnostic norms. Commun Soil Sci Plant Anal 37:181–197. doi:10.1080/00103620500403176

    Article  CAS  Google Scholar 

  • Romic M, Romic D (2003) Heavy metals distribution in agricultural topsoils in urban area. Environ Geol 43:795–805. doi:10.1007/s00254-002-0694-9

    CAS  Google Scholar 

  • Scherer FT, Seelig B, Franzen D (1996) Soil, water and plant characteristics important to irrigation. NDSU. http://www.ag.ndsu.edu/pubs/ageng/irrigate/eb66w.htm#between. Accessed: December

  • Shaki AA, Adeloye AJ (2006) Evaluation of quantity and quality of irrigation water at Gadowa irrigation project in Murzuq Basin, Southwest Libya. Agric Water Manag 84:193–201. doi:10.1016/j.agwat.2006.01.012

    Article  Google Scholar 

  • Swezey CS (2009) Cenozoic stratigraphy of the Sahara, Northern Africa. J Afr Earth Sci 53:89–121. doi:10.1016/j.jafrearsci.2008.08.001

    Article  Google Scholar 

  • Thuy HTT, Tobschall HJ An, PV (2000) Distribution of heavy metals in urban soils—a case study of Danang-Hoian area (Vietnam). Environ Geol 39:603–10. doi:10.1016/j.scitotenv.2005.04.033

    Article  CAS  Google Scholar 

  • Wheida E, Verhoeven R (2007) An alternative solution of the water shortage problem in Libya. Water Res Manag 21:961–982. doi:10.1007/s11269-006-9067-6

    Article  Google Scholar 

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Correspondence to Yuossef F. Lawgali.

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Lawgali, Y.F., Meharg, A.A. Levels of Arsenic and Other Trace Elements in Southern Libyan Agricultural Irrigated Soil and Non-irrigated Soil Projects. Water Qual Expo Health 3, 79–90 (2011). https://doi.org/10.1007/s12403-011-0045-8

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  • DOI: https://doi.org/10.1007/s12403-011-0045-8

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