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Enhancement in compressive strength and UV ageing-resistance of poly(p-phenylene benzobisoxazole) nanocomposite fiber containing modified polyhedral oligomeric silsesquioxane

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Abstract

Modified polyhedral oligomeric silsesquioxane (m-POSS) from trisilanol isobutyl POSS and 4-formylbenzoic acid was synthesized and used for polymerization of poly(p-phenylene benzobisoxazole) (PBO) nanocomposite. PBO and its nanocomposite fibers could be obtained by dry-jet wet spinning the as-polymerized solutions at a liquid crystalline state. No decrease in tensile strength of PBO/m-POSS nanocomposite fibers was observed with the m-POSS content. The tensile modulus of PBO nanocomposite fibers showed the increase 38 % at 2 % loading of POSS and 16 % at 2 % loading of m-POSS compared to PBO fiber. Incorporation of m-POSS into PBO brought to the increase of 19-54 % in compressive strength compared to PBO fiber. The retention of tensile strength was improved from 48 % for PBO to 59 % for PBO/POSS-2.0 mol% fiber and to 62 % for PBO/m-POSS-2.0 mol% fiber after 16 h UV irradiation.

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Authors and Affiliations

  1. Department of Materials Design Engineering, Kumoh National Institute of Technology, Gumi, 39177, Korea

    Byung Gil Min

  2. Department of Energy and Chemical Engineering, Kumoh National Institute of Technology, Gumi, 39177, Korea

    Yong Won Jang & Kwan Han Yoon

Authors
  1. Yong Won Jang
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  2. Byung Gil Min
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  3. Kwan Han Yoon
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Correspondence to Kwan Han Yoon.

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Jang, Y.W., Min, B.G. & Yoon, K.H. Enhancement in compressive strength and UV ageing-resistance of poly(p-phenylene benzobisoxazole) nanocomposite fiber containing modified polyhedral oligomeric silsesquioxane. Fibers Polym 18, 575–581 (2017). https://doi.org/10.1007/s12221-017-1080-2

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  • DOI: https://doi.org/10.1007/s12221-017-1080-2

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