Abstract
The oxidized sodium carboxymethylcellulose (O-CMC) fibers have been successfully synthesized via the oxidation-etherification method. Subsequently, the O-CMC fibers are characterized by Fourier transform infrared (FT-IR), 13C nuclear magnetic resonance (13C-NMR) and X-ray diffraction (XRD). In addition, the viscosity behaviors of the O-CMC aqueous solution have been investigated at five temperatures (25, 30, 40, 50 and 60 °C), six concentrations (30, 35, 40, 45, 50 and 60 kg/m3) and four shear rates (6, 12, 30 and 60 rpm). The results show that the viscosity of the O-CMC aqueous solution increases with increasing concentrations and decreases with increasing temperature. The viscosity of the O-CMC aqueous solution is found to exhibit a dilatant behavior. The dissolution rate in water of the O-CMC fibers is faster than that of the carboxymethylcellulose (CMC) fibers. It could be used as novel absorbable hemostatic fibers in surgery.
Similar content being viewed by others
References
T. Hasan and N. Arslan, Carbohyd. Polym., 54, 73 (2003).
T. Heinze and K. Pfeiffer, Die Angewandte Makromolekulare Chemie, 266, 37 (1999).
B. de Douglas and B. G. Odilio, Thermochim. Acta, 494, 115 (2009).
R. J. Hunter, C. Neagoe, H. A. Jarvelainen, C. R. Martin, K. O. Lindros, W. A. Linke, and V. R. Preedy, J. Nutr., 133, 1154 (2003).
B. E. Randy, M. Eric, K. P. Anna, and S. G. Erin, Am. J. Vet. Res., 65, 637 (2004).
E. R. Kathleen, E. S. Herbert, R. Norma, T. Melvin, K. William, and S. Gere, Fertil Steril, 73, 831 (2000).
E. C. Borrazzo, M. F. Belmont, D. Boffa, and D. L. Fowler, Hernia, 8, 108 (2004).
E. Suphan, Y. Serdar, T. Muhyittin, E. Baki, S. Nevin, B. Huriye, D. Ahmet, C. Ali, and S. Haluk, Dis. Colon. Rectum., 46, 529 (2003).
A. Gokhan, V. Mehmet, T. Asuman, E. Bulent, and K. Eksal, J. Reconstr. Microsurg, 19, 29 (2003).
K. R. Charlotte and C. S. Harry, Am. J. Surg., 169, 154 (1995).
M. Hayashi, H. Sekiya, K. Takatoku, Y. Kariya, and Y. Hoshino, Knee Surg Sport Tr A, 12, 545 (2004).
H. Gu, J. He, Y. Huang, and Z. Guo, Fiber. Polym., 13, 748 (2012).
V. Marianna, K. Taina, R. Monika, J. Jaroslaw, C. Danuta, G. Stina, S. Matti, E. C. Kristina, and N. Pertti, Cellulose, 15, 671 (2008).
O. Aytekin, M. R. Erick, M. Charles, A. T. Jean, and S. G. Inderbir, Am. J. Roentgenol., 172, 1481 (1999).
S. G. Hardeep, H. Monica, and M. R. Cristina, Cereal Chem., 80, 750 (2003).
Y. Fevzi, T. Hasan, and N. Arslan, J. Food Eng., 81, 187 (2007).
F. Kar and N. Arslan, Carbohyd. Polym., 40, 277 (1999).
E. V. Andriana, K. P. Tunc, K. P. Sandeep, and R. D. Christopher, J. Food Process Eng., 25, 41 (2002).
C. Barba, D. Montane, X. Farriol, D. Jacques, and R. Marguerite, Cellulose, 9, 327 (2002).
X. H. Yang and W. L. Zhu, Cellulose, 14, 409 (2007).
M. Zhang, J. Zhang, and S. Xia, US 7, 262, 181 (2007).
V. Pushpamalar, S. J. Langford, M. Ahmad, and Y. Y. Lim, Carbohyd. Polym., 64, 312 (2006).
K. Vijay and Y. Tianrun, Carbohyd. Polym., 48, 403 (2002).
D. A. Silva, C. M. Regina, J. P. A. Feitosa, C. F. Ana, J. S. Maciel, and H. C. B. Paula, Carbohyd. Polym., 58, 163 (2004).
C. M. Regina, H. Frank, and M. B. Peter, Polym. Int., 45, 27 (1998).
H. N. Cheng, M. Takai, and E. A. Ekong, Macromol. Symp., 140, 145 (1999).
K. A. Coia and K. R. Stauffer, J. Food Eng., 52, 166 (1987).
S. D. Holdsworth, J. Texture Stud., 2, 393 (1971).
S. L. Young and J. W. Norman, Rheol. Acta, 42, 199 (2003).
S. Dapia, C. A. Tovar, V. Santos, and J. C. Parajo, Food Hydrocolloid., 19, 313 (2005).
D. C. Valenza, L. Merle, G. Mocanu, L. Picton, and G. Muller, Carbohyd. Polym., 60, 87 (2005).
G. Francois and P. Lennart, J. Phys. Chem., 99, 9201 (1995).
M. Zhang, J. Zhang, and X. Song, US 7, 262, 181 B2 (2007).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Gu, H., He, J., Huang, Y. et al. Fabrication of oxidized sodium carboxymethylcellulose from viscose fibers and their viscosity behaviors. Fibers Polym 14, 1266–1270 (2013). https://doi.org/10.1007/s12221-013-1266-1
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s12221-013-1266-1