Abstract
Intermolecular charge-transfer (CT) complexes between dichloronaphthoquinone (DCN) as acceptor and amine derivatives as donors such as ethylamine, diethyl-amine, triethyl-amine were investigated using spectroscopic techniques. The colorimetric signaling of CT complex from the point of view of their energy levels was carried out by theory calculation. The CT complexes were highly colored with ethylamine, diethyl-amine, triethyl-amine sensing giving rise to a colorless to yellow, red, and blue, respectively. A simple “OR” logic operation was successfully realized by ethylamine, diethyl-amine as input signals. Due to the dependence of the CT complexes absorption intensity of added ethylamine and diethyl-amine, it is possible to mimic the function of the truth table of an “OR” gate.
This is a preview of subscription content, log in via an institution to check access.
References
A. P. de Silva, H. Q. N. Gunaratne, T. Gunnlaugsson, A. J. M. Huxley, C. P. McCoy, J. T. Rademacher, and T. Ee Rice, Chem. Rev., 77, 1515 (1997).
B. Valeur and I. Leray, Coordin.Chem. Rev., 205, 3 (2000).
H. N. Kim, H. M. Lee, H. J. Kim, J. S. Kim, and J. Yoon, Chem. Soc. Rev., 37, 1465 (2008).
S. Subrahmanyam, S. A. Piletsky, E. V. Piletska, B. Chen, R. Day, and A. P. F. Turner, Adv. Mater., 12, 722 (2000).
S. Reinert and G. J. Mohr, Chem. Commun., 19, 2272 (2008).
J. H. Jung, S. J. Lee, J. S. Kim, W. S. Lee, Y. Sakata, and T. Kaneda, Org. Lett., 8, 3009 (2006).
K. Takahiro, U. Shinichi, I. Yuka, S. K. Hsien, M. Soichi, K. Yasushi, K. Nobuko, and K. Nobutami, J. Am. Chem. Soc., 111, 1881 (1989).
F. Kaoru, T. Kazuniri, T. Kiyoshi, H. Noriyuki, O. Tadamune, and K. Takayoshi, J. Am. Chem. Soc., 121, 3807 (1999).
J. H. Perstein, Angew. Chem. Int. Edit., 89, 539 (1977).
J. B. Torrance, Accounts Chem. Res., 12, 79 (1979).
J. Ferrais, O. D. Crowan, V. Valatka, and J. H. Perstein, J. Am. Chem. Soc., 95, 948 (1973).
B. Delley, J. Chem. Phys., 92, 508 (1990).
B. Delley, J. Chem. Phys., 13, 7756 (2000).
A. D. Boese and N. C. Handy, J. Chem. Phys., 114, 5497 (2001).
K. Liu, L. He, X. He, Y. Guo, S. Shao, and S. Jiang, Tetrahedron Lett., 48, 4275 (2007).
A. P. de Silva, H. Q. N. Gunaratne, and C. P. McCoy, Nature, 364, 42 (1993).
A. P. de Silva, H. Q. N. Gunaratne, and C. P. McCOY, J. Am. Chem. Soc., 119, 7891 (1997).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Gwon, SY., Bae, JS., Son, YA. et al. Colorimetric signaling of mono-, di-, and triethylamine based on intermolecular n-π charge transfer interaction. Fibers Polym 10, 855–857 (2009). https://doi.org/10.1007/s12221-009-0855-5
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s12221-009-0855-5