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Passivity degradation of nuclear materials in reduced sulfur environments: A review

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Abstract

This paper reviews sulfur-induced passivity degradation of nuclear materials with emphasis on steam generator(SG)alloys. The state of arts on this topic concerning thermodynamic calculation and experimental data has been reviewed. Thermodynamic calculation results indicate that the distribution of sulfur species strongly depends on pH and temperature. Experimental data show that solution pH, temperature and solution chemistries can significantly affect the electrochemical behaviors of SG materials and the underlying degradation mechanisms. Some issues when conducting corrosion tests at high temperature should be paid attention to, such as the dissolution of the autoclave, which may affect the facticity of the experimental results.

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Authors and Affiliations

  1. Tianjin Key Laboratory of Composite and Functional Materials, Tianjin University, Tianjin, 300072, China

    Zhiming Gao  (高志明), Zeqing Wang  (王泽清), Yinghao Sun  (孙颖昊), Sibo Wu  (吴思博), Chao Ma  (马 超), Yu Zhu  (祝 钰) & Dahai Xia  (夏大海)

  2. School of Materials Science and Engineering, Tianjin University, Tianjin, 300072, China

    Zhiming Gao  (高志明), Zeqing Wang  (王泽清), Yinghao Sun  (孙颖昊), Sibo Wu  (吴思博), Chao Ma  (马 超), Yu Zhu  (祝 钰) & Dahai Xia  (夏大海)

  3. Department of Chemical and Materials Engineering, University of Alberta, Edmonton, T6K 2P6, Canada

    Dahai Xia  (夏大海)

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  1. Zhiming Gao  (高志明)
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  2. Zeqing Wang  (王泽清)
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  6. Yu Zhu  (祝 钰)
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  7. Dahai Xia  (夏大海)
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Corresponding author

Correspondence to Dahai Xia  (夏大海).

Additional information

Supported by the National Basic Research Program of China(“973” Program, No. 2014CB046805), National Natural Science Foundation of China(No. 51131007, No. 51371124), Natural Science Foundation of Tianjin(No. 14JCYBJC17700) and the Open-Ended Fund of the Key Laboratory of Nuclear Materials and Safety Assessment(Institute of Metal Research, Chinese Academy of Sciences, China)(No. 2016NMSAKF02).

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Gao, Z., Wang, Z., Sun, Y. et al. Passivity degradation of nuclear materials in reduced sulfur environments: A review. Trans. Tianjin Univ. 22, 189–201 (2016). https://doi.org/10.1007/s12209-016-2811-y

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