Abstract
A method of hollow fiber–stir bar sorptive extraction (HF–SBSE) coupled with gas chromatography–mass spectrometry was proposed to explore the migration of eight organochlorine pesticide residues in environmental and biological matrices. HF–SBSE was a configuration for solid–phase microextraction purposes, combining the features of SBSE and hollow fiber membrane extraction technology. Variables affecting the extraction (salt addition, extraction temperature, and time) and desorption (microwave time, eluted solvent) have been evaluated. Under the optimal conditions, good linearity (r > 0.999) of all calibration curves was obtained in validation experiments. The recoveries in different sample matrices were in the range from 69.0 to 114.1% with RSD% less than 10.2%. The bio-accumulation of OCPs was tested in samples of soil, underground water, forage grass, and raw milk. It was indicated that HF-SBSE could be applied in simultaneous extraction of hazardous substances in different matrices without sample clean-up.
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Financial supports from the National Nature Science Foundation of China (No. 21467027 No. 31260500, and No. 51563022) are gratefully acknowledged.
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This study was funded by the National Nature Science Foundation of China (grant number 21467027).
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Hong Li declares that he has no conflict of interest. Wen-Juan Zhang declares that she has no conflict of interest. Yan-Bin Wang declares that he has no conflict of interest. Qiong Su declares that she has no conflict of interest. Lan Wu declares that she has no conflict of interest.
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Chinese National Standard, General Administration of Quality Supervision Inspection and Quarantine of the People’s Republic of China, GB/T 23200.86–2016: National food safety standards–Determination of multiple residue of organochlorine pesticides in milk and dairy products–gas chromatography-mass spectrometry; GB/T5009.146–2008: Determination of organochlorine and pyrethroid pesticide multi-residues in vegetable foods; DB22/T 2084–2014: Determination of organochlorine pesticides residues in soil–gas chromatography-mass spectrometry; HJ 699–2014:Water quality– Determination of organochlorine pesticides and chlorobenzenes–Gas chromatography mass spectrometry
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Li, J., Li, H., Zhang, WJ. et al. Hollow Fiber–Stir Bar Sorptive Extraction and Gas Chromatography–Mass Spectrometry for Determination of Organochlorine Pesticide Residues in Environmental and Food Matrices. Food Anal. Methods 11, 883–891 (2018). https://doi.org/10.1007/s12161-017-1053-5
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DOI: https://doi.org/10.1007/s12161-017-1053-5