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Bisphenol A Analysis in Food Samples Using Modified Nanostructure Carbon Paste Electrode as a Sensor

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Abstract

The electrochemical oxidation of bisphenol A has been studied by CdO nanoparticle ionic liquid carbon paste electrode. Cyclic voltammetry, square wave voltammetry, and chronoamperometry were used to investigate the suitability of new sensor for the electrooxidation of bisphenol A in aqueous solution. The electrooxidation of bisphenol A occurs at a potential about 50 mV less positive than with the unmodified carbon paste electrode at pH 7.0. The square wave voltammetry (SWV) peak currents of the electrode increased linearly with the corresponding bisphenol A concentration in the range of 0.3–650 μM with a detection limit of 0.1 μM. The influence of pH value and potential interfering substances on the determination of bisphenol A were studied. Finally, the proposed novel sensor was also examined as a sensitive, high selective, simple, and precise electrochemical sensor for the determination of bisphenol A in food samples.

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Acknowledgments

The authors would like to thank Mashhad and Sari Branch, Islamic Azad University for support.

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Authors and Affiliations

  1. Department of Chemistry, Mashhad Branch, Islamic Azad University, Mashhad, Iran

    Vahid Arabali & Mahmoud Ebrahimi

  2. Department of Food Science & Technology, Faculty of Agricultural Sciences, University of Guilan, Rasht, Iran

    Siamak Gheibi

  3. The Health of Plant and Livestock Products Research Center, Mazandaran University of Medical Sciences, Sari, Iran

    Fatemeh Khaleghi

  4. Department of Chemistry, Sari Branch, Islamic Azad University, Sari, Iran

    Majede Bijad & Ali Rudbaraki

  5. Gas Division, Research Institute of Petroleum Industry, P.O. Box 14665-137, Tehran, Iran

    Maryam Abbasghorbani

  6. Center of Excellence in Electrochemistry, Faculty of Chemistry University of Tehran, Tehran, Iran

    M. R. Ganjali

Authors
  1. Vahid Arabali
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  2. Mahmoud Ebrahimi
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  3. Siamak Gheibi
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  4. Fatemeh Khaleghi
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  5. Majede Bijad
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  6. Ali Rudbaraki
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  7. Maryam Abbasghorbani
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  8. M. R. Ganjali
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Corresponding authors

Correspondence to Mahmoud Ebrahimi or Fatemeh Khaleghi.

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Funding

This work did not receive support from the university, and research has been conducted in the Laboratory of Nano Sciences in Sari Branch, Islamic Azad University, Sari, Iran.

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All of the authors declare that they have no conflict(s) of interest.

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This article does not contain any studies with human participants or animals performed by any of the authors.

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Informed consent was obtained from all individual participants included in the study.

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Arabali, V., Ebrahimi, M., Gheibi, S. et al. Bisphenol A Analysis in Food Samples Using Modified Nanostructure Carbon Paste Electrode as a Sensor. Food Anal. Methods 9, 1763–1769 (2016). https://doi.org/10.1007/s12161-015-0349-6

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  • DOI: https://doi.org/10.1007/s12161-015-0349-6

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