Abstract
Effect of different (2, 2.5, 3)mol. % yttria inside zirconia matrix alongside the effect of 3 mol. % Ytria stabilized zirconia (YSZ) inside the alumina matrix is studied. High hardness and fracture toughness has been observed for 3 mol. % Yttria reinforced inside zirconia matrix. Neural role of mol. % on grain growth and density, but significantly affect the phases. More amount of metastable tetragonal phases augments more toughening phenomenon that provides a beneficial effect on mechanical properties. Investigation on tribological properties reported an improvement in COF by 18 % for ZTA, compared to Alumina. This improvement is allied with the toughening phenomenon accompanied by softer YSZ particles acting as the second phase. The astral analysis of the wear track revealed high abrasions, fracture (formation of micro-cracks), grain pullout, and laminar removal of grains are the possible cause of wear.
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References
Wang J and Stevens R 1989 Zirconia-toughened Alumina (ZTA) Ceramics. Journal of Materials Science. 24(10): 3421–3440.
Pratap A, Kumar P, Singh G P, Mandal N and Singh B K 2020 Effect of indentation load on mechanical properties and evaluation of tribological properties for zirconia toughened Alumina. Materials Today Proceedings. 26: 2442–2446.
Singh B K, Goswami S, Ghosh K, Roy H and Mandal N 2021 Performance evaluation of self lubricatingCuO added ZTA ceramic inserts in dry turning application. International Journal of Refractory Metals and Hard Materials. 98: 105551.
Singh BK, Yaduvanshi AA and Mishra AK 2022 Comparative Study of CuO/ZTA and ZTA Composites in Terms of Functional Properties. In: Mukherjee, K, Layek, R., De, D (eds) Tailored Functional Materials. Springer Proceedings in Materials, vol 15: Springer, Singapore. https://doi.org/10.1007/978-981-19-2572-6_28
Mondal B, Mandal N and Doloi B 2014 Development of Ce-PSZ-/Y-PSZ-Toughened Alumina Inserts for High-Speed Machining Steel. International Journal of Applied Ceramic Technology. 11: 228–239
Singh B K, Roy H, Mondal B, Roy S S and Mandal N 2019 Measurement of chip morphology and multi criteria optimization of turning parameters for machining of AISI 4340 steel using Y-ZTA cutting insert. Measurement. 142: 181–194
Garvie R C 1965 The occurrence of metastable tetragonal zirconia as a crystallite size effect. The Journal of Physical Chemistry. 69(4): 1238–1243
Elsen S R and Ramesh T 2015 Optimization to develop multiple response hardness and compressive strength of zirconia reinforced Alumina by using RSM and GRA. International Journal of Refractory Metals and Hard Materials. 52: 159–164.
Dychtoń K, Drajewicz M, Pytel M, Rokicki P and Nowotnik A 2016 Yttria-stabilized zirconia–alumina composite sintering temperature effect on thermal diffusivity. Journal of Thermal Analysis and Calorimetry. 126(1): 1–7.
Zadorozhnaya O Y, Khabas T A, Tiunova O V and Malykhin S E 2020 Effect of grain size and amount of zirconia on the physical and mechanical properties and the wear resistance of zirconia-toughened Alumina. Ceramics International. 46(7): 9263–9270
Kerkwijk B, Winnubst A J, Verweij H, Mulder E J, Metselaar H S C and Schipper DJ, 1999 Tribological properties of nanoscale alumina–zirconia composites. Wear. 225: 1293–1302.
Kerkwijk B, Winnubst A J, Mulder E J and Verweij H 1999 Processing of homogeneous zirconia-toughened alumina ceramics with high dry-sliding wear resistance. Journal of the American Ceramic Society. 82(8): 2087–2093.
Geuzens E, Mullens S, Cooymans J, Luyten J, Lemoisson F, Sastry K Y, Froyen L, D’Haen J, Van Bael M K, Van den Rul H and Mullens J 2008 Synthesis and mechanical and tribological characterization of Alumina-Yttria stabilized zirconia (YSZ) nanocomposites with YSZ synthesized by means of an aqueous solution–gel method or a hydrothermal route. Ceramics international. 34(5): 1315–1325.
Paulo Davim J, Santos E, Pereira C and Ferreira J M F 2008 Comparative study of friction behaviour of alumina and zirconia ceramics against steel under water lubricated conditions. Industrial Lubrication and Tribology. 60(4): 178–182.
Ghaemi M H, Reichert S, Krupa A, Sawczak M, Zykova A, Lobach K, Sayenko S and Svitlychnyi Y 2017 Zirconia ceramics with additions of alumina for advanced tribological and biomedical applications. Ceramics International. 43(13): 9746–9752.
Singh B K, Ghosh K, Roy S S, Mondal B and Mandal N 2018 Correlation between microstructure and mechanical properties of YSZ/Al2O3 ceramics and its effect on high speed machining of steel. Transactions of the Indian Ceramic Society. 77(4): 219–225.
Singh B K, Mondal B and Mandal N 2016 Machinability evaluation and desirability function optimization of turning parameters for Cr2O3 doped zirconia toughened Alumina (Cr-ZTA) cutting insert in high speed machining of steel. Ceramics International. 42: 3338–3350.
Singh B K, Samanta S, Roy S S, Sahoo R R, Roy H and Mandal N 2020 Evaluation of Mechanical and Frictional properties of CuO added MgO/ZTA ceramics. Materials Research Express. 6(12): 125208–20.
Gafur M A, Sarker M S R, Alam M Z and Qadir M R 2017 Effect of 3 mol% yttria stabilized zirconia addition on structural and mechanical properties of alumina-zirconia composites. Materials Sciences and Applications. 8(07): 584.
French J D, Harmer M P, Chan H M and Miller G A 1990 Coarsening-resistant dual-phase interprenetrating microstructures. Journal of the American Ceramic Society. 73(8): 2508–2510.
Singh B K, Roy H, Mondal B, Roy S S and Mandal N 2018 Development andmachinability evaluation of MgO doped Y-ZTA ceramic inserts for high speedmachining of steel. Machining Science and Technology. 22(6): 899–913.
Nevarez-Rascon A, Aguilar-Elguezabal A, Orrantia E and Bocanegra-Bernal M H 2009 On the wide range of mechanical properties of ZTA and ATZ based dental ceramic composites by varying the Al2O3 and ZrO2 content. InternationalJournal of Refractory Metals and Hard Materials. 27(6): 962–970.
Meena K L, Vidyasagar C S and Karunakar D B 2020 Mechanical and tribological properties of alumina toughened zirconia composites through conventional sintering and microwave sintering. Transactions of the Indian Institute of Metals. 73: 1909–1923.
Pratap A, Singh B K and Sardana N 2022 Fracture in self-lubricating inserts: a case study. Materials Today: Proceedings. 66: 3738–3742.
Ramakrishnan T, Ganeshkumar S, Thirunavukkarasu V, Kumar R S and Venkatesh S 2020 Investigation of wear behaviour of silicon carbide toolinserts and titanium nitride coated tool inserts in machining of EN8 steel. International Journal of Mechanical Engineering and Technology 10(01): 1862–1873.
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The author thanks the Principal and Director of Sri Eshwar College of Engineering for their continual support in writing this article. The authors also like to thank all the members of the MPML group for their incessant support and motivation to carry out this work.
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RAJA, K., GANESHAN, P., SINGH, B.K. et al. Effect of mol.% of Yttria in Zirconia matrix alongside a comparative study among YSZ, alumina & ZTA ceramics in terms of mechanical and functional properties. Sādhanā 48, 72 (2023). https://doi.org/10.1007/s12046-023-02136-w
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DOI: https://doi.org/10.1007/s12046-023-02136-w