Skip to main content
Log in

Mechanical and thermal behaviour of biodegradable composites based on polycaprolactone with pine cone particle

  • Published:
Sādhanā Aims and scope Submit manuscript

Abstract

Polycaprolactone (PCL) was reinforced with natural fibres as they not only permit a substantial reduction of the material costs, but also play a role as reinforcement in mechanical properties. This work was focused on the estimation of mechanical and thermal behaviour based on PCL and Pine Cone particles (PCP) filler at different weight percentages (0, 5, 10, 15, 30 and 45 wt%). Tests results indicated considerable improvement in mechanical properties, corresponding to a gain in impact strength and % elongation of 6 and 9.2% at 15 wt% particle loading, respectively. Some decrease in thermal stability was observed for composites with increasing filler content where as composite at 15% PCP was not significantly affected. Lower melting and crystallization enthalpies and higher crystallinity values were obtained for bio-composites compared with neat PCL. Some decrease in thermal stability and increase in oxygen and water vapour barrier properties were also observed for composites with increasing filler content.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Figure 1
Figure 2
Figure 3
Figure 4
Figure 5

Similar content being viewed by others

References

  1. Bogoeva-Gaceva G 2013 Biocomposites based on poly (lactic acid) and kenaf fibers: effect of microfibrillated cellulose. Maced. J. Chem. Chem. Eng. 32(2): 331–335

    Google Scholar 

  2. Hung S J and Edelman P G 1995 An overview of biodegradable polymers and biodegradation of polymers. In: Degradable Polymers: Principles and Application, eds. G Scott and D Gilead, 8–24. London: Chapman & Hall

    Google Scholar 

  3. Chiellini E, Cinelli P, Chiellini F and Imam S H 2004 Environmentally degradable bio-based polymeric blends and composites. Macromol. Biosci. 4:218–231

    Article  Google Scholar 

  4. Wu C S 2003 Physical properties and biodegradability of maleated polycaprolactone / starch composite. Polym. Degrad. Stab. 80: 127–34

    Article  Google Scholar 

  5. Naira L S and Laurencin C T 2007 Biodegradable polymers as biomaterials. Prog. Polym. Sci. 32:762–798

    Article  Google Scholar 

  6. Vilaplana F, Stromberg E and Karlsson S 2010 Environmental and resource aspects of sustainable bio-composites. Polym. Degrad. Stab. 95: 2147–2161

    Article  Google Scholar 

  7. Tokiwa Y, Calabia B, Ugwu C and Aib S 2009 Biodegradability of plastics. Int. J. Mol. Sci. 10: 3722–3742

    Article  Google Scholar 

  8. Bisanda E T N and Ansell M P 1999 The effect of silane treatment on the mechanical and physical properties of sisal-epoxy composites. Compos. Sci. Technol. 141: 165–178

    Google Scholar 

  9. Pavithran C, Mukherjee P S, Bramakumar M and Damodaran A D 1987 Impact properties of natural fiber composites. J. Mater. Sci. Lett. 7: 882–889

    Article  Google Scholar 

  10. Chin-San Wu and Hsin-Tzu Liao 2012 Polycaprolactone–based green renewable eco-composite made from rice straw fiber: characterization and assessment of mechanical and thermal properties. Ind. Eng. Chem Res. 51:3329–3337

    Article  Google Scholar 

  11. Bledzki A K and Gassan J 1999 Composites reinforced with cellulose based fibres. Prog. Polym. Sci. 24(2): 221–274

    Article  Google Scholar 

  12. Kabir M M, Wang H, Aravinthan T, Cardona F and Lau K T 2011 Effects of natural fiber surface on composite properties: a review. In: eddBE Proceedings, pp. 94–99

  13. Ashori A and Nourbakhsh A 2009 Mechanical behavior of agro-residue-reinforced polypropylene composites. J. Appl. Polym. Sci. 111(5): 2616–2620

    Article  Google Scholar 

  14. Shakoor A, Muhammad R, Thomas N L and Silber Schmidt V V 2013 Mechanical and thermal characterisation of poly (l-lactide) composites reinforced with hemp fibers. J. Phys. Conf. Ser. 451: 012010

    Google Scholar 

  15. R Khandanlou, MB Ahmad, K Shameli, MZ Hussein, N Zainuddin and K Kalantari 2014 Mechanical and thermal stability properties of modified rice straw fiber blend with polycaprolactone composite. J. Nanomater. 675258: 9

    Google Scholar 

  16. Kamol Dey, Sumon Ganguly, Ruhul A Khan and Mubarak A Khan 2013 Surface treatment of areca-nut fiber using silane and gamma irradiation: fabrication of polycaprolactone based composite. J. Compos. Biodegrad. Polym. 1: 1–7

    Article  Google Scholar 

  17. Bakare I O, Okieimen F E, Pavithran C, Abdul Khalil H P S and Brahmakumar M 2010 Mechanical and thermal properties of sisal fiber-reinforced rubber seed oil-based polyurethane composites. Mater. Des. 31(9): 4274–4280

    Article  Google Scholar 

  18. Turker Dundar, Nadir Aryrilmis and Umit Buyuksari 2010 Utilization of waste pine cone in manufacture of wood/plastic composite. In: 2nd International Conference on Sustainable Contruction Material and Technologies 28th–30th June. Universita politecnica Delle Marche, Ancona, Italy

  19. Corradini E, Mattoso L H C, Guedes C G F and Rosa D S 2004 Mechanical, thermal and morphological properties of poly(e-caprolactone)/zein blends. Polym. Adv. Technol. 15: 340–345

    Article  Google Scholar 

  20. Odusanya O S, Ishiaku U S and Azemi B M 2000 On Mechanical Properties of Sago Starch/Poly(&-caprolactone). Compos. Polym. Sci. Eng. 40: 1298

    Article  Google Scholar 

  21. Ishiaku U S, Pang K W, Lee W S and Ishak Z A M 2002 Mechanical Properties and Enzymic Degradation of Thermoplastic and Granular Sago Starch Filled Poly(Epsilon-Caprolactone). Eur. Polym. J. 38 (2): 393–401

    Article  Google Scholar 

  22. Nitz H, Semke H, Landers R and Mulhaupt R 2001 Reactive extrusion of polycaprolactone compounds containing wood flour and lignin. J. Appl. Polym. Sci. 81: 1972–1984

    Article  Google Scholar 

  23. Essabir H, Nekhlaoui S, Malta M, Bensalah M O, Arrakhiz F Z, Qaiss A and Bouhfid R 2013 Bio-composites based on polypropylene reinforced with almond shells particles: mechanical and thermal properties. Mater. Des. 53: 225–230

    Article  Google Scholar 

  24. Noel Ibrahim Akos, Mat Uzir Wahit, Rahmah Mohamed and Abdirahman Ali Ususf 2013 Comparative studies of mechanical properties of polycaprolactone and poly(lactic acid) blends reinforced with natural fibers. Compos. Interfaces 20(7): 459–467

    Article  Google Scholar 

  25. Wahit M U, Akos N I and Laftah W A 2013 Influence of natural fibers on the mechanical properties and biodegradation of poly(lactic acid) and poly(e-caprolactone) composites: a review. Polym. Compos. 33(7): 1045–1053

    Article  Google Scholar 

  26. Valdés A, Beltrán, A and Garrigós MC 2013 Characterization and classification of almond cultivars by using spectroscopic and thermal techniques. J. Food Sci. 78(2): C138–C144

    Article  Google Scholar 

  27. Reixach R, Espinach F, Franco-Marqués E, Ramirez de Cartagena F, Pellicer N, Tresserras J and Mutjé P 2013 Modeling of the tensile moduli of mechanical, thermomechanical, and chemi-thermomechanical pulps from orange tree pruning. Polym. Compos. 34(11): 1840–1846

    Article  Google Scholar 

  28. Sergio N M, Veronica Calado, Ruben Jesus S Rodriguez and Frederico M Margem 2012 Thermogravimetric behavior of natural fibers reinforced polymer composites—an overview. Mater. Sci. Eng. A557: 17–28

    Google Scholar 

  29. Dayma N and Satapathy B K 2010 Morphological interpretation and micromechanical properties of polyamide-6/polypropylene-grafted-maleic anhydride/nanoclay ternary nanocomposites. Mater. Des. 31(10): 4693–4703

    Article  Google Scholar 

Download references

Acknowledgements

The Authors are grateful to the Director of Institute Instrumentation Centre, India Institute of Technlogy, Roorkee, Uttarakhand and CIPET, Govt. of India, Amritsar, Punjab for their support in the characterization of the green composites. Also, for DIT University for partial funding of the research.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Kanishka Jha.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Jha, K., Tyagi, Y.K. & Singh Yadav, A. Mechanical and thermal behaviour of biodegradable composites based on polycaprolactone with pine cone particle. Sādhanā 43, 135 (2018). https://doi.org/10.1007/s12046-018-0822-1

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • DOI: https://doi.org/10.1007/s12046-018-0822-1

Keywords

Navigation