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Investigations on the reactivity of arylantimony halides with N,O-donor ligands

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Abstract

The reactions of organoantimony(V) halides with N,O-donor ligands in presence of a base were investigated. The synthesis and crystal structure of three novel organoantimony(V) compounds \((\hbox {Ph}_{2}\hbox {Sb})_{2}(\hbox {Q})_{2}(\hbox {O})_{2}\) 1, (\(\hbox {Ph}_{3}\hbox {Sb}\))(PM)Cl 2 and (\(\hbox {Ph}_{2}\hbox {Sb}\))(TEA) 3 [where \(\hbox {Q} = \hbox {8-hydroxyquinoline}\), \(\hbox {PM} = \hbox {2-pyridinemethanol}\) and \(\hbox {TEA} = \hbox {triethanolamine}\)] are reported herein. 1 crystallizes as a dimer resulting in the formation of a four-membered \(\hbox {Sb}_{2}\hbox {O}_{2}\) ring while 2 and 3 are monomeric in the solid state. Interestingly, compound 3 crystallizes in orthorhombic chiral space group \(P2_{1}2_{1}2_{1}\) and is a rare example of spontaneous chirality exhibited in organoantimony(V) compounds.

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SYNOPSIS Herein we report the synthesis and structural characterization of three organoantimony(V) complexes supported by O,N donor ligands.

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Acknowledgements

V.B. thanks DST for funding under the SERC-Fast track Scheme. P.V.V.N.K. thanks CSIR for a Fellowship.

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Authors and Affiliations

  1. School of Chemistry, University of Hyderabad, Hyderabad, Telangana, 500 046, India

    Junaid Ali, Gujju Narasimhulu & Viswanathan Baskar

  2. Chemistry division, Department of Sciences and Humanities, VFSTR (Deemed to be University), Guntur, Andhra Pradesh, 522 213, India

    Pilli V V N Kishore

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  1. Pilli V V N Kishore
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  2. Junaid Ali
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  4. Viswanathan Baskar
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Correspondence to Viswanathan Baskar.

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Special Issue on Modern Trends in Inorganic Chemistry

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Kishore, P.V.V.N., Ali, J., Narasimhulu, G. et al. Investigations on the reactivity of arylantimony halides with N,O-donor ligands. J Chem Sci 130, 100 (2018). https://doi.org/10.1007/s12039-018-1495-3

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