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Synthesis of naphthoxazinone derivatives using silica-bonded S-sulfonic acid as catalyst under solvent-free conditions

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Abstract

Silica-bonded S-sulfonic acid is employed as a recyclable catalyst for the synthesis of naphthoxazinone derivatives from the reaction of ß-naphthol, aromatic aldehydes and urea at 150°C under solvent-free conditions. The heterogeneous catalyst was recycled for five runs after the reaction of ß-naphthol, benzaldehyde and urea without losing its catalytic activity.

Silica-bonded S-sulfonic acid was employed as solid acid catalyst for the synthesis of naphthoxazinones under solvent-free conditions.

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Acknowledgements

We are thankful to Persian Gulf University Research Council for partial support of this work. Also, we are thankful to the School of Chemistry, Manchester University for NMR spectra.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Sciences, Persian Gulf University, Bushehr, 75169, Iran

    KHODABAKHSH NIKNAm & PARISA ABOLPOUR

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  1. KHODABAKHSH NIKNAm
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  2. PARISA ABOLPOUR
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Correspondence to KHODABAKHSH NIKNAm.

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Supplementary Information is available at www.ias.ac.in/chemsci.

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NIKNAm, K., ABOLPOUR, P. Synthesis of naphthoxazinone derivatives using silica-bonded S-sulfonic acid as catalyst under solvent-free conditions. J Chem Sci 127, 1315–1320 (2015). https://doi.org/10.1007/s12039-015-0895-x

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  • DOI: https://doi.org/10.1007/s12039-015-0895-x

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