Abstract
A simple and efficient synthesis of E-9-aryl-5-arylidene-1-oxo-1,2,3,4,5,6,7,8-octahydroxanthenes and their lower analogues has been developed by amberlyst–15 catalysed cyclocondensation of E,E-α,α′-diarylidenecyclohexanones and E,E-α,α′-diarylidenecyclopentanones, respectively, with cyclohexan-1,3-diones. The products were obtained in moderate to good yield and their structures were confirmed from analytical and spectral data.
A simple and efficient synthesis of E-9-aryl-5-arylidene-1-oxo-1,2,3,4,5,6,7,8-octahydroxanthenes and their lower analogues has been developed by amberlyst-15 catalysed cyclocondensation of E,E-α,α′-diarylidenecyclohexanones and E,E-α,α′-diarylidenecyclopentanones, respectively, with cyclohexan-1,3-diones in anhydrous acetonitrile.
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Acknowledgements
Financial assistance from the UGC-CAS and DST-PURSE programs, Department of Chemistry is gratefully acknowledged. The authors also acknowledge the DST-FIST program to the Department of Chemistry, Jadavpur University and Prof. D Mal, Department of Chemistry, Indian Institute of Technology (IIT), Kharagpur for providing the NMR spectral data. SS and AD are thankful to the Council of Scientific and Industrial Research (CSIR), New Delhi and RM to the University Grants Commission (UGC), New Delhi for their Research Fellowships.
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SAMANTA, S., GUPTA, A.D., MONDAL, R. et al. A simple synthesis of E-9-aryl-5-arylidene-1-oxo-1,2,3,4,5,6,7, 8-octahydroxanthenes and their lower analogues from E,E-α,α′-diarylidenecycloalkanones. J Chem Sci 125, 737–743 (2013). https://doi.org/10.1007/s12039-013-0442-6
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DOI: https://doi.org/10.1007/s12039-013-0442-6