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Polymer supported sulphanilic acid: A highly efficient and recyclable green heterogeneous catalyst for the construction of 4,5-dihydropyrano[3,2-c]chromenes under solvent-free conditions

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Abstract

Polystyrene divinylbenzene supported sulphanilic acid was prepared, characterized and tested as an acidic catalyst in multicomponent organic synthesis. This is the first report focusing on the development of one-pot solvent-free synthesis of 4,5- dihydropyrano [3,2-c]chromenes under acidic conditions. It proved to be a versatile catalyst for microwave-assisted synthesis of 4,5-dihydropyrano[3,2-c]chromenes. This methodology is mild, high yielding, green and the catalyst could be easily recycled for several times.

Polystyrene divinylbenzene supported sulphanilic acid was prepared, characterized and applied as a novel heterogeneous catalyst in heterocyclic synthesis. A comparative study of the synthesis of chromenes under microwave irradiation and conventional techniques using the prepared catalyst has been made.

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Acknowledgements

Authors thank the Head, Department of Chemistry, Sardar Patel University for providing necessary research facilities. DKR is thankful to the authorities of Sardar Patel University, Vallabh Vidyanagar for allocation of research funding in the form of seed grant-2011.

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Authors and Affiliations

  1. Department of Chemistry, Sardar Patel University, Vallabh Vidyanagar, 388 120, India

    JASHMIN P PATEL, JEMIN R AVALANI & DIPAK K RAVAL

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  1. JASHMIN P PATEL
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  2. JEMIN R AVALANI
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Correspondence to DIPAK K RAVAL.

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PATEL, J.P., AVALANI, J.R. & RAVAL, D.K. Polymer supported sulphanilic acid: A highly efficient and recyclable green heterogeneous catalyst for the construction of 4,5-dihydropyrano[3,2-c]chromenes under solvent-free conditions. J Chem Sci 125, 531–536 (2013). https://doi.org/10.1007/s12039-013-0408-8

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  • DOI: https://doi.org/10.1007/s12039-013-0408-8

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