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1,3,5-Triazine-2,4,6-triyltrisulfamic acid (TTSA): A new organic solid acid for the nitrosation of secondary amines and oxidation of urazoles in the presence of NaNO2 under mild and heterogeneous conditions

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Abstract

Melamine reacted with chlorosufonic acid (ClSO3H) to form a new sulfamic-type acid, 1,3,5-triazine-2,4,6-triyltrisulfamic acid (TTSA). Both nitrosation of secondary amines and oxidation of urazoles were accomplished by using TTSA/NaNO2 system under mild and heterogeneous conditions with good to excellent yields.

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Authors and Affiliations

  1. School of Pharmacy, Hamedan University of Medical Sciences, Zip Code 65178, Hamedan, Iran

    Gholamabbas Chehardoli

  2. Faculty of Chemistry, Bu-Ali Sina University, Hamedan, 6517838683, Iran

    Mohammad Ali Zolfigol & Toktam Faal-Rastegar

  3. Organic Polymer Chemistry Research Laboratory, Department of Chemistry, Isfahan University of Technology, Isfahan, 84156-83111, Iran

    Shadpour Mallakpour

  4. Department of Chemistry, Faculty of Sciences, Ilam University, Ilam, 69315516, Iran

    Arash Ghorbani-Choghamarani

Authors
  1. Gholamabbas Chehardoli
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  2. Mohammad Ali Zolfigol
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  3. Toktam Faal-Rastegar
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  4. Shadpour Mallakpour
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  5. Arash Ghorbani-Choghamarani
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Correspondence to Gholamabbas Chehardoli or Mohammad Ali Zolfigol.

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Chehardoli, G., Zolfigol, M.A., Faal-Rastegar, T. et al. 1,3,5-Triazine-2,4,6-triyltrisulfamic acid (TTSA): A new organic solid acid for the nitrosation of secondary amines and oxidation of urazoles in the presence of NaNO2 under mild and heterogeneous conditions. J Chem Sci 121, 441–447 (2009). https://doi.org/10.1007/s12039-009-0052-5

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  • DOI: https://doi.org/10.1007/s12039-009-0052-5

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