Skip to main content
SpringerLink
Log in

Surface reactivity and layer analysis of chemisorbed reaction films in the surface-chemical environment of alkyl octadecenoates

  • Published:
Journal of Chemical Sciences Aims and scope Submit manuscript

Abstract

Studies on surface reactivity of substrate iron (Fe-particles) were made in the tribo-chemical environment of alkyl octadecenoates. Two alkyl octadecenoates namely ethyl octadecenoate and methyl 12-hydroxy octadecenoate, slightly different in their chemical nature, were taken for preparing the chemisorbed reaction films (CRF) at the temperature 100 ± 5°C. The reaction products collected in the composite (amorphous) phase were isolated into three different solvent-soluble fractions (sub-layer films) using polar solvents of increasing polar strength. The FTIR analysis of these films showed that these were primarily organic in nature and were composed of alkyl and/or aryl hydroxy ethers, unsaturated hydroxy ketones, and aromatic structures chemically linked with iron surface. These reaction films also contained large amount of iron (Fe). Further, these film fractions also showed varying thermal behaviour during thermal decomposition in the temperature range of 50–800°C when thermally evaluated in the nitrogen environment.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Eustathopoulos N, Nicholas M G and Drevet B 1999 (NY: Pergamon) p. 93

  2. Bull S J 1999 Wear 233 412

    Article  Google Scholar 

  3. Nayak S, Meyer H M and Dahotre N B 2004 Surface Eng. 20 48

    Article  CAS  Google Scholar 

  4. Dwivedi D K 2004 Surface Eng. 20 87

    Article  CAS  Google Scholar 

  5. Parezanovic I and Spiegel M 2004 Surface Eng. 20 285

    Article  CAS  Google Scholar 

  6. Lin M L, Zhou H L, Chen Y R and Jia Y Q 2005 Mater Chem. Phys. 80 289

    Google Scholar 

  7. Tsay P C-C Hu and C-K Wang 2005 Mater. Chem. Phys. 89 275

    Article  CAS  Google Scholar 

  8. Ratajski J I 2004 J. Mater. Res. Adv. Tech.: Z. Metallkd 95 9

    Google Scholar 

  9. Peng K, Liu F, Fu D, Huang Z, Xu F and Du Y 2005 Mater. Chem. Phys. 89 138

    Article  CAS  Google Scholar 

  10. Li, Y-J, Wang J, Yin Y-S and Ma H-J 2004 Mater. Soc. Technol. 20 1484

    Article  CAS  Google Scholar 

  11. Francis J A 2002 Sci. Tech. Weld. 7 331

    Article  Google Scholar 

  12. Kotechki D J and Ogborn J S 1995 Weld. J. 7 269

    Google Scholar 

  13. Yang J H 1995 Weld. J. 2 103

    CAS  Google Scholar 

  14. Kotvis P V 1986 Lubrication Eng. 42 363

    CAS  Google Scholar 

  15. Forbes E S and Allum K G 1967 J. Inst. Petrol. 53 173

    Google Scholar 

  16. Buckley H (ed.); 1987 CRC Handbook of lubrication, p. 28

  17. Chudhary R B and Jha M K 2004 Lubri. Sci. 16 205

    Google Scholar 

  18. Edward E W and Davey W 1958 Wear 1 291

    Article  Google Scholar 

  19. Sakurai T, Ikeda S and Okabe H 1962 ASLE Trans. 5 67

    CAS  Google Scholar 

  20. Kajdas C 1984 Lubri. Sci.. 34 261

    Google Scholar 

  21. Rosenblum, B, Braulich P and Mimmel L 1977 J. Appl. Phys. 48 5262

    Article  CAS  Google Scholar 

  22. Von A M, Steinfelder K and Tummler R 1971 (Berlin: Springer Verlag) p. 121

  23. Rowe C N and Murphy W R 1977 Tribo Work (Washington DC: NSF) p. 327

    Google Scholar 

  24. Allum K G and Ford J F 1965 J. Inst. Petr. 51 497

    Google Scholar 

  25. Allum K G and Forbes E S 1967 J. Inst. Petrol 5 521

    Google Scholar 

  26. Willermate A, Pieprzak J M, Dailey D P, Carter R O, Lindsay N E, Haak L P and deVrieS J E 1991 ASME J. Tribo. 113 38

    Article  Google Scholar 

  27. Harrison G and Brown P 1991 Wear 148 123

    Article  CAS  Google Scholar 

  28. Willermate P A, Carter R O and Boulos E N 1992 Tribo. Int. 25 371

    Article  Google Scholar 

  29. Weinmin L, Ganzhu G, Pingyu Z and Qunji X 1997 Lubri. Sci. 10 67

    Article  Google Scholar 

  30. Palermo T, Giasson S, Buffeteau T, Desbat B and Turlet J M 1996 Lubri. Sci. 8 119

    Article  CAS  Google Scholar 

  31. Chen C, Dong J and Chen G 1996 Mocaxue Xuebao 16 247

    Google Scholar 

  32. Barkshire I R, Pruton M and Smith G C 1995 Appl. Sur. Sci. 84 331

    Article  CAS  Google Scholar 

  33. Smith G C and Bell J C 1999 Appl. Sur. Sci. 144 222

    Article  Google Scholar 

  34. Martin J M, Belin M and Mansot J L 1986 ASLE Trans. 29 523

    CAS  Google Scholar 

  35. Schuetzle D, Shyu R O J, Dickie R A, Halubka J and McLintyre N S 1986 Appl. Spectro. 40 641

    Article  CAS  Google Scholar 

  36. Pidduck A J and Smith G C 1997 Wear 212 254

    Article  CAS  Google Scholar 

  37. Smith G C 2000 J. Appl. Phys. D33 187

    Google Scholar 

  38. Wooten D L and Hughes D W 1987 Lubr. Eng. 43 736

    Google Scholar 

  39. United State Patent No. 6936906

  40. Weisner U, Floudas G and Ulrich R 1999 J. Chem. Phys. 110 652

    Article  Google Scholar 

  41. Feng J, Pham H, Macdonald P, Winnik, M A, Geurts J M, Zirkzee H, Vanes S and German A L 1998 J. Coatings Technol. 70 57

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Center for Advanced Technology (CAT), Haryana Engineering College Jagadhari, Yamunanagar, Haryana, 135 003, India

    R. B. Choudhary

  2. Specialties and Additives Group, Chemical and Bio-Science Division, Indian Institute of Petroleum, Mohkampur, Dehradun, 248 005, India

    O. N. Anand

  3. Spectroscopy (FTIR) Laboratory, Analytical Science Division (ASD), Indian Institute of Petroleum, Mohkampur, Dehradun, 248 005, India

    O. S. Tyagi

Authors
  1. R. B. Choudhary
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. O. N. Anand
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. O. S. Tyagi
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to R. B. Choudhary.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Choudhary, R.B., Anand, O.N. & Tyagi, O.S. Surface reactivity and layer analysis of chemisorbed reaction films in the surface-chemical environment of alkyl octadecenoates. J Chem Sci 121, 353–360 (2009). https://doi.org/10.1007/s12039-009-0041-8

Download citation

  • Received:

  • Revised:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s12039-009-0041-8

Keywords

Search

Navigation