Abstract
Three polymers, poly(vinyl alcohol) (PVA), poly(acrylic acid) (PAA) and poly(methyl methacrylate) (PMMA), are used as matrices to synthesize three nanocomposites each with reduced graphene oxide (RGO) fillers (5 wt%). The dielectric properties of these nanocomposites, RGO–PVA, RGO–PAA and RGO–PMMA, are studied in zero magnetic field and in magnetic field (H) up to 1.2 T. From these data magnetodielectric effects are obtained as the variation of \( \varepsilon^{\prime} \) and \( \varepsilon^{\prime\prime} \)—the real and imaginary parts of complex dielectric constant with H at some frequencies. Thus at 100 kHz for the increase of H from zero to 1 T \( \varepsilon^{\prime} \) decreases by 5% in RGO–PVA and by 4% in RGO–PAA, whereas \( \varepsilon^{\prime} \) increases by 4% in RGO–PMMA. The observed magnetodielectric effects, though small, are significant. They show both decrease and increase of \( \varepsilon^{\prime} \) depending on the polymer. This fact is the indicative of the interaction between RGO filler particles and polymer chains.
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Acknowledgements
We thank the University Grants Commission of India (UGC) for awarding a Minor Research Project grant Vide UGC letter No. F. PSW – 224/15-16(ERO) dt. 16 Nov. to Dr S S Pradhan, Assistant Professor, Midnapore College (Autonomous) Midnapore 721101, India for pursuing this research work. We thank Dr A Nayak, Professor, Presidency University, India and Dr P Deb of Tezpur Central University, India for their help and comments.
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Pradhan, S.S., Ghosh, T.N., Marik, A. et al. Magnetodielectric effects in three reduced graphene oxide–polymer nanocomposites. Bull Mater Sci 43, 208 (2020). https://doi.org/10.1007/s12034-020-02185-5
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DOI: https://doi.org/10.1007/s12034-020-02185-5