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Ionic drift velocity measurement on hot-pressed Ag+ ion conducting glass-polymer electrolytes

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Abstract

Ionic drift velocity (v d) measurements of a new Ag+ ion conducting glass-polymer electrolytes (GPEs): (1−x) PEO : x [0.8(0.75AgI : 0.25AgCl) : 0.2(Ag 2O : V2O5)], where 0 < x < 50 wt%, were reported. GPEs were casted using the hot-press techniques developed in recent times. The composition: 70PEO : 30[0.8(0.75AgI : 0.25AgCl) : 0.2(Ag2O : V2O5)] with conductivity (σ) ∼ 7.7 × 10−7 S cm−1 was identified as highest conducting composition from the compositional-dependent conductivity studies. The ionic mobility (μ), mobile ion concentration (n), ionic transference number (t ion) and ionic drift velocity (v d) of GPEs were determined at different temperatures with the help of the d.c. polarization technique and other well-known important relations.

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Acknowledgement

I gratefully acknowledge SERB DST, New Delhi, for providing financial assistance through the ‘Fast Track Young Scientist Research Project’ (No. SR/FTP/PS-23/2009).

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Authors and Affiliations

  1. Solid State Physics Research Laboratory, Department of Applied Physics, Shri Shankaracharya Institute of Professional Management & Technology, Raipur, 492 015, India

    ANGESH CHANDRA

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  1. ANGESH CHANDRA
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CHANDRA, A. Ionic drift velocity measurement on hot-pressed Ag+ ion conducting glass-polymer electrolytes. Bull Mater Sci 38, 1743–1747 (2015). https://doi.org/10.1007/s12034-015-1107-5

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