Abstract
The present study reports on the kinetics of borided Nickel 201 alloy. The thermochemical treatment of boronizing was carried out in a solid medium consisting of B4C and KBF4 powders mixture at 1123, 1173 and 1223 K for 2, 4 and 6 h, respectively. The boride layer was characterized by optical microscopy, X-ray diffraction technique and micro-Vickers hardness tester. X-ray diffraction analysis revealed the existence of NiB, Ni2B, Ni3B and Ni4B3 compounds at the surface of borided Nickel 201 alloy. The thickness of the boride layer increased with an increase in the boriding time and the temperature. The hardness of the nickel borides formed on the surface of the nickel substrate ranged from 1642 to 1854 HV0.05, whereas the Vickers hardness value of the untreated nickel was 185 HV 0.05. The growth kinetics of boride layers forming on the borided Nickel 201 alloy was also analysed. The boron activation energy (Q) was estimated as equal to 203.87 kJ mol-1 for the borided Nickel 201 alloy.
Similar content being viewed by others
References
Genel K 2006 Vacuum 80 451
Uslu I, Comert H, Ipek M, Ozdemir O and Bindal C 2007 Mater. Des. 28 55
Gunes I 2014 Mater. Technol. 48 765
Ribeiro R, Ingole S, Usta M, Bindal C, Ucisik A H and Liang H 2006 Vacuum 80 1341
Keddam M 2009 Int. J. Mater. Res. 100 901
Mu D, Shen B, Yang C and Zhao X 2009 Vacuum 83 1481
Lou D C, Solberg J K, Akselsen O M and Dahl N 2009 Mater. Chem. Phys. 115 239
Anthymidis K G, Zinoviadis P, Roussos D and Tsipas D N 2002 Mater. Res. Bull. 37 515
Mu D, Yang C, Shen B and Jiang H 2009 J. Alloys Compd. 479 629
Usta M, Ozbek I, Bindal C, Ucisik A H, Ingole S and Liang H 2006 Vacuum 80 1321
Campos-Silva I, Bravo-Bárcenas D, Meneses-Amador A, Ortiz-Dominguez M, Cimenoglu H, Figueroa-López U and Andraca-Adame J 2013 Surf. Coat. Technol. 237 402
Usta M 2005 Surf. Coat. Technol. 194 251
Usta M, Ozbek I, Ipek M, Bindal C and Ucisik A H 2005 Surf. Coat. Technol. 194 330
Von Matuschka A G 1980 Boronizing (Philadelphia: Heyden and Son Inc.)
Bindal C and Ucisik A H 1999 Surf. Coat. Technol. 122 208
Keddam M 2004 Appl. Surf. Sci. 236 451
Sen S, Sen U and Bindal C 2005 Surf. Coat. Technol. 191 274
Ozbek I and Bindal C 2011 Vacuum 86 391
Bektes M, Calik A, Ucar N and Keddam M 2010 Mater. Charact. 61 233
Ulker S, Gunes I and Taktak S 2011 Indian J. Eng. Mater. Sci. 18 370
Gunes I, Ulker S and Taktak S 2011 Mater. Des. 32 2380
Ueda N, Mizukoshi T, Demizu K, Sone T, Ikenaga A and Kawamoto M 2000 Surf. Coat. Technol. 126 25
Sinha A K 1991 J. Heat Treat. 4 437
Campos I, Ramirez G, Figueroa U, Martinez J and Morales O 2007 Appl. Surf. Sci. 253 3469
Gunes I 2013 Sadhana 38 527
Taktak S and Tasgetiren S 2006 J. Mater. Eng. Perform. 15 570
Brakman C M, Gommers A W J and Mittemeijer E J 1989 J. Mater. Res. 4 1354
Ozbek I, Akbulut H, Zeytin S, Bindal C and Ucisik A H 2000 Surf. Coat. Technol. 126 166
Aytekin H and Akcin Y 2013 Mater. Des. 50 515
Yu L G, Khor K A and Sundararajan G 2006 Surf. Coat. Technol. 201 2849
Campos I, Oseguera J, Figueroa U, Garci J A, Bautista O and Kelemenis G 2003 Mater. Sci. Eng. A 352 261
Torun O 2008 Surf. Coat. Technol. 202 3549
Kahvecioglu O, Sista V, Eryilmaz O L, Erdemir A and Timur S 2011 Thin Solid Films 520 1575
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
GUNES, I., KEDDAM, M., CHEGROUNE, R. et al. Growth kinetics of boride layers formed on 99.0% purity nickel. Bull Mater Sci 38, 1113–1118 (2015). https://doi.org/10.1007/s12034-015-0931-y
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s12034-015-0931-y