Abstract
The graphene has several unique characteristics and many applications in all fields. Some of these characteristics are the quantum Hall effect at room temperature, the ambipolar field effect, the optical properties, the high electron mobility and the best electronic properties. The ability of fabricating large-area monolayer graphene is hindering its application. In this paper the effects of growth time on the quality of graphene synthesized by low-pressure chemical vapour deposition (LPCVD) has been investigated. Large-area monolayer graphene is synthesized on polycrystalline Cu foil (~1 cm2) by controlled experiment LPCVD at different growth times (30, 60, 120 and 150 s). The synthesized graphene was characterized using Raman spectroscopy and scanning electron microscopy (SEM). The Raman spectrum showed a I G /I 2D ~0.2 ratio which indicates that all samples are single-layer graphene and the SEM images demonstrate that the domain size increases when the growth time increases. The growth mechanism of LPCVD of graphene on Cu and the mechanisms governing the Raman scattering process in the films are also discussed. The control over the grain size of synthesized graphene by adjusting the growth time (achieved in this work), provides useful insights for understanding the growth mechanism of LPCVD of graphene and for optimization of the growth process to further improve the quality of graphene. Finally, with analyses of all investigations we found that the quality and the large-area of monolayer graphene improved by increasing the growth time and it is very important consequence for all those who do research on graphene.
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Novoselov K S, Geim A K, Morozov S V, Jiang D, Dubobos S V, Grigorieva I V and Firsov A A 2004, Science 306 666
Schwierz F 2010 Nat. Nanotechnol. 5 487
Bonaccorso F, Sun Z, Hasan T and Ferrari A C 2010, Nat. Photon. 4 611
Kim K S, Zhao Y, Jang H, Lee S Y, Kim J M, Kim Kw S, Ahn J H, Kim P, Choi J Y and Hong B H 2009, Nature 457 706
Nagashio K, Nishimura T, Kita K and Toriumi A 2009, Appl. Phys. Exp. 2 025003
Berger C, Song Z, Li X, Wu X, Brown N, Naud C, Mayou D, Li T, Hass J, Marchenkoy A N, Conrad E H, First P N and de Heer W A 2006, Science 312 1191
Li X, Li X., Magnuson C W, Venugopal A, An J, Suk J W, Han B, Borysiak M, Cai W, Velamakanni A, Zhu Y, Fu L, Vogel E M, Voelkl E, Colombo L and Ruoff R S 2010, Nano Lett. 10 4328
Usachov D, Dobrotvorskii A M, Varykhalov A, Rader O, Gudat W, Shikin A M and Adamchuk V K 2008, Phys. Rev. B 78 85403–1-8
Loginova E, Bartelt N C, Feibelman P J and MacCarty K F 2008, N J. Phys. 10 093026
N’Diaye A, Bleikamp S, Feibelman P J and Michely T 2006, Phys. Rev. Lett. 97
Li X, Cai W, An J, Kim S, Nah J, Yahng D, Piner R, Velamakanni A, Jung I, Tutuc E, Banerjee S K, Colombo L and Ruoff R S 2009, Science 324 1312
Ong T P, Xiong F, Chang R P H and White C W 1992 J. Mater. Res. 7 24
Constant L, Speisser C and Normand F L 1997, Surf. Sci. 387 28
Zhou W, Han Z, Wang J, Yan Z., Jin Z, Sun X, Yawen Z., Yan C and Li Y 2006, Nano Lett. 6 2987
Zhang W, Wu P, Li Z and Yang J 2011, J. Phys. Chem. C 115 17782
Gelb A and Cardillo M 1996, Surf. Sci. 59 140
Gelb A and Cardillo M 1977, Surf. Sci. 64 208
Fan L, Zou J, Li Z, Li X, Wang K, Wei J, Zhong M, Wu D, Xu Z and Zhu H 2012, Nanotechnology 23 115605
Bhaviripudi S, Jia X, Dresselhaus M S and Kong J 2010, J. Nano Lett. 10 4128
Li X S, Cai W, Colombo L and Ruoff R S 2009, Nano Lett. 9 4268
Dresselhaus M S, Jorio A, Hofmann M, Dresselhaus G and Saito R 2010, Nano Lett. 10 751
Ferrari A C, Meyer J C, Scardaci V, Casiraghi C, Lazzeri M, Mauri F, Piscanec S, Jiang D, Novoselov K S, Roth S and Geim A K 2006, Phys. Rev. Lett. 97 187401
Ni Z H, Chen W, Fan X F, Kuo J L, Yu T, Wee A T S and Shen Z X 2008, Phys. Rev. B 77 115416
Malard L M, Pimenta M A, Dresselhaus G and Dresselhaus M S 2009, Phys. Rep. 473 51
Oliveira M H J., Schumann T, Gargallo-Caballero R, Seyller T, Ramsteiner M, Trampert A, Geelhaar L, Lopes J M J and Riechert 2013, Carbon 56 339
Wang G, Zhang M, Zhu Y, Ding G, Jiang D, Guo Q, Liu S, Xie X, Chu P K, Di Z and Wang X 2013, Sci. Rep. 3 2465
Bao W, Miao F, Chen Z, Zhang H, Jang W, Dames C and Lau C N 2009, Nat. Nanotechnol. 4 562
Wu Y, Robertson A W, Schaffel F, Speller S C and Warner J H 2011, Chem. Mater. 23 4543
Chen S, Cai W, Piner R D, Suk J W, Wu Y, Ren Y, Kang Y and Ruoff R S 2011, Nano Lett. 11 3519
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JAFARI, A., ALIPOUR, R. & GHORANNEVISS, M. The effects of growth time on the quality of graphene synthesized by LPCVD. Bull Mater Sci 38, 707–710 (2015). https://doi.org/10.1007/s12034-015-0918-8
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DOI: https://doi.org/10.1007/s12034-015-0918-8