Designed synthesis of tunable amorphous carbon nanotubes (a-CNTs) by a novel route and their oxidation resistance properties

Abstract

Tunable amorphous carbon nanotubes (a-CNTs) were successfully synthesized using V₃O₇·H₂O and glucose solution as the starting materials by a novel route for the first time. The as-obtained samples were separately characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray powder diffraction (XRD), energy-dispersive spectrometer (EDS), elemental analysis (EA), Fourier transform infrared spectroscopy (FT-IR) and Raman spectrum. The results showed that the as-obtained a-CNTs had uniform diameters with outer diameter ranging from 140 to 250 nm and inner diameter about 28 nm on an average, and their length was up to several micrometres. No VO _x residues remaining in a-CNTs showed the as-obtained a-CNTs with high purity. The as-prepared a-CNTs were a kind of hydrogenated a-CNTs containing both the sp ³- and sp ²-type carbons. Furthermore, the thermal stability of the as-obtained a-CNTs in the air atmosphere were investigated by thermo-gravimetric/differential thermal analyser (TG-DTA), revealing that the as-obtained a-CNTs had good thermal stability and oxidation resistance below 300 °C in air.