Abstract
A new efficient phosphor, Eu2+/Eu3+ and Ce3+ activated Na2Zn5(PO4)4 has been synthesized by solid-state reaction technique at high temperature. X-ray powder diffraction analysis confirmed the formation of Na2Zn5(PO4)4 host lattice. Scanning electron microscopy indicated that the microstructure of the phosphor consisted of irregular fine grains with a size of about 0·5–2 μm. Photoluminescence excitation spectrum measurements of Ce3+ activated Na2Zn5(PO4)4 show that the phosphor can be efficiently excited by UV-Vis light from 280 to 310 nm to realize emission in the visible (blue) range due to the 5d-4f transition of Ce3+ ions which is applicable for scintillation purpose, whereas Eu2+/Eu3+ activated Na2Zn5(PO4)4 phosphor emits blue, green and red emission spectrum shows at 487 nm, 546 nm with a dominant peak at 611 nm respectively, due to Eu2+/Eu3+ ions which is promising candidate for solid state lighting. Therefore, newly synthesised, by low cost and easy technique prepared, novel phosphors may be useful as RGB phosphor for solid state lighting application.
Similar content being viewed by others
References
Baldassare Di Bartolo (ed.) 1991a Advances in nonradiative processes in solids (New York: Plenum) p. 262
Baldassare Di Bartolo (ed.) 1991b Advances in nonradiative processes in solids (New York: Plenum) p. 282
Belsare P D, Joshi C P, Moharil S V, Kondawar V K, Muthal P L and Dhopte S M 2009a Radiat. Effects Defects Solids 164 197
Belsare P D, Joshi C P, Moharil S V, Omanwar S K, Muthal P L and Dhopte S M 2009b Opt. Mater. 31 668
Dorenbos P 2000 J. Lumin. 91 155
Haque M M, Lee H L and Kim D K 2009 J. Alloy Compd. 481 792
Hu Y S, Zhuang W D, Ye H Q, Zhang S S, Fang Y and Huang X W 2005 J. Lumin. 111 139
Ji L N, Ma H W, Li J B, Lianga J K, Sun B J, Liu Y H, Zhang J Y and Rao G H 2007 J. Solid State Chem. 180 2256
Omkaram I, Vengala Rao B and Buddhudu S 2009 J. Alloy Compd. 474 565
Park J K, Kim C H, Park S H and Park H D 2004 Appl. Phys. Lett. 84 1647
Riwotzki K and Haase M 1998 J. Phys. Chem. B102 10129
Ropp R C 1968 J. Electrochem. Soc. 115 841
Ternane R, Panzer G, Cohen-Adad M T H, Goutaudier C, Boulon G and Kbir-Ariguib N 2001 Opt. Mater 16 291
Wang J G, Jing X P, Yan C H, Lin J H and Liao F H 2006 J. Lumin. 121 57
Wang L S, Lin J and Quan Z W 2004a J. Rare Earths, 22 91
Wang Y H, Tadashi E, He L and Wu C F 2004b J. Cryst. Growth 268 568
Weber M J, Bliss M, Craig R A and Sunberg D S 1995 Radiat. Effects Defects Solids 134 23
Xia G D, Zhou S M, Zhang J J and Xu J 2005 J. Cryst. Growth 279 357
Yadav R S, Dutta R K, Kumar M and Pandey A C 2009 J. Lumin. 129 1078
Yang, Z P, Li X, Yang Y and Li X M 2007 J. Lumin. 122–123 707
Yao G Q, Duan J F, Ren M, Yu H D and Lin J H 2001 Chin. J. Lumin. 22 21
Ye J, Weiping Q, Jisen Z, Xianmin Z, Yan W and Chunyan C 2008 J. Solid State Chem. 181 724
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Shinde, K.N., Dhoble, S.J. & Kumar, A. Ce and Eu activated Na2Zn5(PO4)4, a new promising novel phosphor. Bull Mater Sci 34, 937–942 (2011). https://doi.org/10.1007/s12034-011-0218-x
Received:
Revised:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s12034-011-0218-x