Skip to main content
SpringerLink
Log in

Novel renewable alkyd resins based on imide structures

  • Published:
Journal of Coatings Technology and Research Aims and scope Submit manuscript

Abstract

New bio-based building blocks were synthesized from amino acids like lysine, glycine, and phenylalanine and from di- or tricarboxylic acids like succinic acid and citric acid, respectively. These building blocks were incorporated into alkyd resins by standard polycondensation chemistry and technology. The resulting alkyd resins were evaluated as coating resins, either by casting films from xylene or by making coatings from water-based alkyds after emulsification of the synthesized alkyd resins. The renewability content of the resins could easily be varied between 80 and ca. 95 wt%. The properties of the highly bio-based coatings look promising, some even outperforming standard commercial alkyd resins.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4

Similar content being viewed by others

References

  1. Deligny, P, Tuck, N, “Alkyds and Polyesters.” In: Oldring, PKT (ed.) Resins for Surface Coatings, Vol. II. New York, Wiley (2000) and references cited therein

  2. Güner, FS, Yağci, Y, Erciyes, AT, “Polymers from Triglyceride Oils.” Progr. Polym. Sci., 31 633–670 (2006)

    Article  Google Scholar 

  3. Hofland, A, “Alkyd Resins: From Down and Out to Alive and Kicking.” Prog. Org. Coat., 73 (4) 274–282 (2012)

    Article  Google Scholar 

  4. https://www.perstorp.com/products/voxtar_m100

  5. https://www.basf.com/en/company/news-and-media/news-releases/2016/03/p-16-153.html

  6. Collias, DI, Harris, AM, Nagpal, V, Cottrell, IW, Schultheis, MW, “Biobased Terephthalic Acid Technologies: A Literature Review.” Ind. Biotechnol., 10 (2) 91–105 (2014)

    Article  Google Scholar 

  7. Mahmoud, E, Watson, DA, Lobo, RF, “Renewable Production of Phthalic Anhydride from Biomass-Derived Furan and Maleic Anhydride.” Green Chem., 16 167–175 (2014)

    Article  Google Scholar 

  8. Wright, HJ, De Puis, RN, “Imide-Modified Alkyd Resins.” Ind. Eng. Chem., 38 (12) 1303–1308 (1946)

    Article  Google Scholar 

  9. Fukami, A, Nakajima, H, Kubota, S, “Preparation of Heat Resistant Alkyd Resins.” JPS 5318695 (A), 1978

  10. Kishanprasad, VS, Gedam, PH, “N-(carboxymethyl) Trimellitimide—Based Polyesterimides as Film Formers for Air-Drying Protective Coatings.” J. Appl. Polym. Chem., 43 (9) 1709–1716 (1991)

    Article  Google Scholar 

  11. Reidlinger, G, Billiani, J, Zrin, E, Scherz, J, “Hydroxy-Functional Binder Components.” US Patent 194,922 A1, 2006

  12. Hloba, AI, Grachek, VI, Krut’ko, ET, “Imide-Containing Oligomers as Alkyd Resin Modifiers.” Russ. J. Appl. Chem., 85 (11) 1780–1785 (2012)

    Article  Google Scholar 

  13. http://www.reverdia.com/products/biosuccinium

  14. Lansbergen, AJH, Koning, CE, Buijsen, PFA, Hendriks, JWM, Papegaaij, A, “Polymer and Composition,” WO2015/052342A1, 2015

Download references

Acknowledgments

The authors would like to thank DSM Coating Resins for permission to publish this paper.

Author information

Authors and Affiliations

  1. DSM Coating Resins, Ceintuurbaan 5, 8022 AW, Zwolle, The Netherlands

    Cor Koning, Aad Lansbergen, Fokelien Koldijk, Hans Hendriks, Alwin Papegaaij, Reinier Smabers, Paul Buijsen, Coen Gehrels, Bart Reuvers & Jan Herrema

Authors
  1. Cor Koning
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Aad Lansbergen
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Fokelien Koldijk
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Hans Hendriks
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Alwin Papegaaij
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Reinier Smabers
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. Paul Buijsen
    View author publications

    You can also search for this author in PubMed Google Scholar

  8. Coen Gehrels
    View author publications

    You can also search for this author in PubMed Google Scholar

  9. Bart Reuvers
    View author publications

    You can also search for this author in PubMed Google Scholar

  10. Jan Herrema
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Cor Koning.

Electronic supplementary material

Below is the link to the electronic supplementary material.

Supplementary material 1 (DOCX 1055 kb)

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Koning, C., Lansbergen, A., Koldijk, F. et al. Novel renewable alkyd resins based on imide structures. J Coat Technol Res 14, 783–789 (2017). https://doi.org/10.1007/s11998-017-9915-8

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11998-017-9915-8

Keywords

Search

Navigation