Abstract
Printed functional materials are a rapidly growing area of interest for low-cost high-speed device manufacture with flexographic printing seen as a route to achieving this. The relationship between surface tension of the ink and surface free energy (SFE) of the photopolymer plate is a key for optimum performance. However, traditional methods of surface tension modification of the ink/coating often cannot be employed for functional inks. In this research, rapid, permanent modification of flexographic printing plate’s SFE is achieved through controlled UV-ozone treatment, and the effects of the treatment on the polar and dispersive component of SFE are analyzed by Fourier transform infrared attenuated total reflectance spectroscopy, swelling experiments, and roughness measurements. Printing trials using the modified printing plates reveal improved print uniformity and control of deposited ink layer thickness, as well as improved print features—particularly track and pad junctions which can be problematic for printed electronic applications. The ability to rapidly tailor printing plate SFE is of benefit to all volume printing applications. Furthermore, it is of critical importance for functional printing and printed electronics where surface tension of the ink is determined by the functional material and chemical modification is not possible or desirable.
Similar content being viewed by others
References
Bois, C, Dumont, JJP, Blayo, A, Vincent, R, Nayoze, C, Chaussy, D, “Evaluating the Effectiveness of Using Flexography Printing for Manufacturing Catalyst-Coated Membranes for Fuel Cells.” Fuel Cells, 14 (4) 614–625 (2014)
Krebs, FC, Fyenbob, J, Jørgensena, M, “Product Integration of Compact Roll-to-Roll Processed Polymer Solar Cell Modules: Methods and Manufacture Using Flexographic Printing, Slot-Die Coating and Rotary Screen Printing.” J. Mater. Chem., 20 8994–9001 (2010)
Maksud, MI, Yusof, MS, Embong, Z, Nodin, MN, Rejab, NA, “An Investigation on Printability of Carbon Nanotube (CNTs) Inks by Flexographic onto Various Substrates.” Int. J. Mater. Sci. Eng., 2 (1) 49–55 (2014)
Galton, D, Bould, D, Claypole, T, “The Effect of Surface Properties on the Printability of Flexographic Printing Plates.” Proceedings of 37th International Research Conference of Iarigai, Montreal, 2010
Youssef, KT, “Using of Flexographic Printing Plates for Producing an Organic Field Effect Transistor.” Int. Des. J., 5 (2) 375–383 (2011)
Rimdusit, S, Ishida, H, “Development of New Class of Electronic Packaging Materials Based on Ternary Systems of Benzoxazine, Epoxy, and Phenolic Resins.” Polymer, 41 (22) 7941–7949 (2000)
Tomašegović, T, Mahović Poljaček, S, Milčić, D, “Qualitative Analysis of Coverage Value Transfer in Modern Packaging Printing Workflow.” In: Sek, MA, Rouillard, V, Bigger, SW (Eds.) Proceedings of 19th IAPRI World Conference on Packaging, Melbourne, 2014
Chung, D, Papadakis, SE, Yam, KL, “Evaluation of a Polymer Coating Containing Triclosan as the Antimicrobial Layer for Packaging Materials.” Int. J. Food Sci. Technol., 38 (2) 165–169 (2003)
Joshi, AV, Bandyopadhyay, S, “Effect of Gravure Process Variables on Void Area in Shrink Film.” J. Coat. Technol. Res., 11 (5) 757–764 (2014)
Joshi, AV, Dettke, C, Steingraeber, J, “Investigation on Electrostatic Assist and Gravure Process Parameters on Solid Mottle Reduction for Shrink Films.” J. Coat. Technol. Res., (2015). doi:10.1007/s11998-015-9753-5
Israelachvili, JN, Intermolecular and Surface Forces. Elsevier, University of California, New York, 2011
Strobel, M, Lyons, CS, Mittal, KL (eds.), Plasma Surface Modification of Polymers: Relevance to Adhesion. VSP, Zeist, 1994
Owens, DK, Wendt, RC, “Estimation of the Surface Free Energy of Polymers.” J. Appl. Polym. Sci., 13 (8) 1741–1747 (1969)
Knöll, R, “Photopolymerizable Flexographic Printing Elements Comprising SIS/SBS Mixtures as Binder for the Production of Flexographic Printing Plates.” US Patent 6531263 B2, 2003
Mayenez, C, Muyldermans, X, “Flexographic Printing Plates from Photocurable Elastomer Compositions.” EP Patent 0696761 B1, 1998
Decker, C, Jenkins, AD, “Kinetic Approach of Oxygen Inhibition in Ultraviolet- and Laser-Induced Polymerizations.” Macromolecules, 18 (6) 1241–1244 (1985)
Tomašegović, T, Mahović Poljaček, S, Cigula, T, “Surface Properties of Flexographic Printing Plates Related to UVC Post-treatment.” J. Print Media Technol. Res., 4 227–234 (2013)
Lee, TY, Guymon, CA, Sonny Jönsson, E, Hoyle, CE, “The Effect of Monomer Structure on Oxygen Inhibition of (Meth)acrylates Photopolymerization.” Polymer, 45 (18) 6097–6426 (2004)
Fan, CW, Lee, SC, “Surface Free Energy Effects in Sputter-Deposited WNx Films.” Mater. Trans., 48 (9) 2449–2453 (2007)
Hallab, NJ, Bundy, KJ, O’Connor, K, Moses, RL, Jacobs, JJ, “Evaluation of Metallic and Polymeric Biomaterial Surface Energy and Surface Roughness Characteristics for Directed Cell Adhesion.” Tissue Eng., 7 (1) 55–71 (2001)
Abate, PF, Zahra, VN, Macchi, RL, “Effect of Photopolymerization Variables on Composite Hardness.” J. Prosthet. Dent., 86 (6) 632–635 (2001)
Mahović Poljaček, S, Tomašegović, T, Gojo, M, “Influence of UV Exposure on the Surface and Mechanical Properties of Flexographic Printing Plate.” In: Novaković, D (ed.) Proceedings of GRID 2012, Novi Sad, 2012
Crivello, JV, “Advanced Curing Technologies Using Photo-and Electron Beam Induced Cationic Polymerization.” Radiat. Phys. Chem., 63 21–27 (2002)
Mittal, KL, Polymer Surface Modification: Relevance to Adhesion. CRC Press, New York, 2004
Mesic, B, Lestelius, M, Engström, G, Edholm, B, “Printability of PE-Coated Paperboard With Water-Borne Flexography: Effects of Corona Treatment and Surfactants Addition.” Pulp Paper Canada, 106 (11) 229–234 (2005)
Johnson, J, “Aspects of Flexographic Print Quality and Relationship to Some Printing Parameters.” Dissertation, Karlstad University (2008)
Mahović Poljaček, S, Tomšegović, T, Cigula, T, Milčić, D, “Application of FTIR in Structural Analysis of Flexographic Printing Plate.” In: Politis, AE, Gatsou C (Eds.), Proceedings of IC 2014 Conference, Athens, 2014
Phillips, CO, Govindarajan, S, Hamblyn, SM, Conlan, RS, Gethin, DT, Claypole, TC, “Patterning of Antibodies Using Flexographic Printing.” Langmuir, 28 (25) 9878–9884 (2012)
Deganello, D, Cherry, JA, Gethin, DT, Claypole, TC, “Patterning of Micro-Scale Conductive Networks Using Reel-to-Reel Flexographic Printing.” Thin Solid Films, 518 6113–6116 (2010)
Macia, LG, Morrin, A, Smyth, MR, Killard, AJ, “Advanced Printing and Deposition Methodologies for the Fabrication of Biosensors and Biodevices.” Analyst, 135 845–867 (2010)
Novascan UV-ozone cleaner user guide. http://microfluidics.cnsi.ucsb.edu/tools/Novascan%20UV-Ozone%20cleaner%20user%20guide.pdf. Accessed 25 Jan 2016
MacDermid LUX ITP 60 printing plate manufacturing process. http://printing.macdermid.com/files/5614/2625/6737/LUXITP60_Brochure-1.pdf. Accessed 25 Jan 2016
Schroder, HL, “Process For the Ozone Protection by Photopolymer-Flexoprinting Plates by Alcohol-Soluble Polyamides.” US Patent 4640877 A, 1987
Dataphysics, Determination of the surface energy of a solid. http://www.dataphysics.de/2/start/knowledge/understanding-interfaces/determination-of-the-surface-energy-of-a-solid/. Accessed 24 Jan 2015
Hejda, F, Solar, P, Kousal, J, “Surface Free Energy Determination by Contact Angle Measurements—A Comparison of Various Approaches.” In: Šafránková J, Pavlů, J (Eds.) Proceedings of WDS’10, Part III, Prague, 2010
Wyko NT 2000 user guide. http://erc.ncat.edu/Facilities/Manuals/Wyko.pdf. Accessed 25 Jan 2016
Hinda, AR, Bhargava, SK, McKinnonb, A, “At The Solid/Liquid Interface: FTIR/ATR—The Tool of Choice.” Adv. Colloid Interface, 93 (1–3) 91–114 (2001)
Liu, J, Zheng, XJ, Tang, KY, “Study on The Gravimetric Measurement of the Swelling Behaviours of Polymer Films.” Rev. Adv. Mater. Sci., 33 452–458 (2013)
Kaoru, F, Hiroshi, HI, Fumio, I, Yoshinobu, M, Sakae, S, Minoru, Y, “Flexo Ink Composition.” US Patent 3912675 A, 1975
Cheremisinoff, NP, Handbook of Applied Polymer Processing Technology. CRC Press, New York, 1996
Drummond, CJ, Chan, DYC, “van der Waals Interaction, Surface Free Energies, and Contact Angles: Dispersive Polymers and Liquids.” Langmiur, 13 3890–3895 (1997)
Oberg, E, Machinery’s Handbook, 29th ed. Industrial Press, New York, 2012
Coates, J, “Interpretation of Infrared Spectra, A Practical Approach.” In: Meyers, RA (ed.) Encyclopedia of Analytical Chemistry. Wiley, Chichester, 2000
Deflorian, F, Fedrizzi, L, Rossi, S, “Electrochemical Impedance Spectroscopy and Fourier Transform Infrared Spectroscopy of Natural and Accelerated Weathering of Organic Coatings.” Corrosion, 54 (8) 598–605 (1998)
Fridman, A, Plasma Chemistry. Cambridge University Press, Cambridge, 2008
Ramakrishnan, ES, “Detecting Surface Energy Indicative of the Degree of Completion of Cross-Linking Polymerization.” WO Patent 2014021949 A1, 2014
Andersson, C, Johnson, J, Järnström, L, “Ultraviolet-Induced Aging of Flexographic Printing Plates Studied by Thermal and Structural Analysis Methods.” J. Appl. Polym. Sci., 112 (3) 1636–1646 (2009)
Hansen, CM, Hansen Solubility Parameters: A User’s Handbook, 2nd ed. CRC Press, Boca Raton, 2007
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Tomašegović, T., Beynon, D., Claypole, T. et al. Tailoring the properties of deposited thin coating and print features in flexography by application of UV-ozone treatment. J Coat Technol Res 13, 815–828 (2016). https://doi.org/10.1007/s11998-016-9794-4
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11998-016-9794-4