Abstract
A simple method is reported for the preparation of superhydrophobic fiber reinforced plastic (FRP) surfaces with controlled adhesion. By simply adjusting the content of CaCO3 and SiO2 of surface coating, after surface treatment, we can obtain the different FRP surfaces with diverse morphologies. The results confirm that the FRP samples not only could achieve superhydrophobicity but also present huge differences in adhesive abilities. The microlens surface presents a strong sticky performance which can hold a 10-μL water droplet even tilted vertically or turned upside down. Such a property is very similar to the rose petal effect. In comparison, the microbowls surface presents a slippery property which can be regarded as a lotus effect. The water roll-off angle is as low as of approximately 9°. At the same time, the adhesion work of the surfaces is decreased from extreme high (34.7 mN/m) to very low (7.9 mN/m). Noticeably, the heat resistance and antifriction of the microbowls surface are better than that of the microlens.
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Meuler, AJ, McKinley, GH, Cohen, RE, “Exploiting Topographical Texture to Impart Icephobicity.” ACS Nano, 4 7048–7052 (2010)
Kako, T, Nakajima, A, Irie, H, Kato, Z, Uematsu, K, Watanabe, T, Hashimoto, K, “Adhesion and Sliding of Wet Snow on a Super-Hydrophobic Surface with Hydrophilic Channels.” J. Mater. Sci., 39 547–555 (2004)
Pazokifard, S, Esfandeh, M, Mirabedini, SM, Mohseni, M, Ranjbar, Z, “Investigating the Role of Surface Treated Titanium Dioxide Nanoparticles on Self-Cleaning Behavior of an Acrylic Facade Coating.” J. Coat. Technol. Res., 10 175–187 (2013)
Shang, Q, Zhou, Y, Xiao, G, “A Simple Method for the Fabrication of Silica-Based Superhydrophobic Surfaces.” J. Coat. Technol. Res., 11 509–515 (2014)
Xue, Z, Wang, S, Lin, L, Chen, L, Liu, M, Feng, L, Jiang, L, “A Novel Superhydrophilic and Underwater Superoleophobic Hydrogel-Coated Mesh for Oil/Water Separation.” Adv. Mater., 23 4270–4273 (2011)
Jin, M, Wang, J, Yao, X, Liao, M, Zhao, Y, Jiang, L, “Underwater Oil Capture by a Three-Dimensional Network Architectured Organosilane Surface.” Adv. Mater., 23 2861–2864 (2011)
Zhang, J, Seeger, S, “Polyester Materials with Superwetting Silicone Nanofilaments for Oil/Water Separation and Selective Oil Absorption.” Adv. Funct. Mater., 21 4699–4704 (2011)
Scardino, AJ, Zhang, H, Cookson, DJ, Lamb, RN, Nys, RD, “The Role of Nano-roughness in Antifouling.” Biofouling, 25 757–767 (2009)
Su, B, Li, M, Lu, Q, “Toward Understanding Whether Superhydrophobic Surfaces can Really Decrease Fluidic Friction Drag.” Langmuir, 26 6048–6052 (2009)
Jin, M, Feng, X, Feng, L, Sun, T, Zhai, J, Li, T, Jiang, L, “Superhydrophobic Aligned Polystyrene Nanotube Films with High Adhesive Force.” Adv. Mater., 17 1977–1981 (2005)
Hong, X, Gao, X, Jiang, L, “Application of Superhydrophobic Surface with High Adhesive Force in No Lost Transport of Superparamagnetic Microdroplet.” J. Am. Chem. Soc., 129 1478–1479 (2007)
Liu, M, Zheng, Y, Zhai, J, Jiang, L, “Bioinspired Super-Antiwetting Interfaces with SPECIAL Liquid-Solid Adhesion.” Acc. Chem. Res., 43 368–377 (2009)
Feng, L, Zhang, Y, Xi, J, Zhu, Y, Wang, N, Xia, F, Jiang, L, “Petal Effect: A Superhydrophobic State with High Adhesive Force.” Langmuir, 24 4114–4119 (2008)
Barthlott, W, Neinhuis, C, “Purity of the Sacred Lotus, or Escape from Contamination in Biological Surfaces.” Planta, 202 1–8 (1997)
Chen, P, Chen, L, Han, D, Zhai, J, Zheng, Y, Jiang, L, “Wetting Behavior at Micro-/Nanoscales: Direct Imaging of a Microscopic Water/Air/Solid Three-Phase Interface.” Small, 5 908–912 (2009)
Balu, B, Kim, JS, Breedveld, V, Hess, DW, “Tunability of the Adhesion of Water Drops on a Superhydrophobic Paper Surface via Selective Plasma Etching.” J. Adhes. Sci. Technol., 23 361–380 (2009)
Bhushan, B, Her, EK, “Fabrication of Superhydrophobic Surfaces with High and Low Adhesion Inspired from Rose Petal.” Langmuir, 26 8207–8217 (2010)
Li, J, Yang, Y, Zha, F, Lei, Z, “Facile Fabrication of Superhydrophobic ZnO Surfaces from High to Low Water Adhesion.” Mater. Lett., 75 71–73 (2012)
Yong, J, Chen, F, Yang, Q, Zhang, D, Du, G, Si, J, Hou, X, “Femtosecond Laser Weaving Superhydrophobic Patterned PDMS Surfaces with Tunable Adhesion.” J. Phys. Chem. C, 117 24907–24912 (2013)
Cheng, Z, Du, M, Lai, H, Zhang, N, Sun, K, “From Petal Effect to Lotus Effect: A Facile Solution Immersion Process for the Fabrication of Super-Hydrophobic Surfaces with Controlled Adhesion.” Nanoscale, 5 2776–2783 (2013)
Peng, S, Deng, W, “A Facile Approach for Preparing Biomimetic Polymer Macroporous Structures with Petal or Lotus Effects.” New. J. Chem., 38 1011–1018 (2014)
Li, L, Breedveld, V, Hess, DW, “Hysteresis Controlled Water Droplet Splitting on Superhydrophobic Paper.” Colloid Polym. Sci., 291 417–426 (2013)
Yilgor, I, Bilgin, S, Isik, M, Yilgor, E, “Facile Preparation of Superhydrophobic Polymer Surfaces.” Polymer, 53 1180–1188 (2012)
Lee, Y, Ju, KY, Lee, JK, “Stable Biomimetic Superhydrophobic Surfaces Fabricated by Polymer Replication Method from Hierarchically Structured Surfaces of Al Templates.” Langmuir, 26 14103–14110 (2010)
Victor, JJ, Facchini, D, Erb, U, “A Low-Cost Method to Produce Superhydrophobic Polymer Surfaces.” J. Mater. Sci., 47 3690–3697 (2012)
Liu, Y, Lin, Z, Lin, W, Moon, KS, Wong, CP, “Reversible Superhydrophobic-Superhydrophilic Transition of ZnO Nanorod/Epoxy Composite Films.” ACS Appl. Mater. Inter., 4 3959–3964 (2012)
Choudhury, IA, Chuan, PC, “Experimental Evaluation of Laser Cut Quality of Glass Fibre Reinforced Plastic Composite.” Opt. Laser. Eng., 51 1125–1132 (2013)
Bagheri, R, Marouf, BT, Pearson, RA, “Rubber-Toughened Epoxies: A Critical Review.” J. Macromol. Sci. Polym. Rev., 49 201–225 (2009)
Park, SJ, Kim, HC, Kim, HY, “Roles of Work of Adhesion Between Carbon Blacks and Thermoplastic Polymers on Electrical Properties of Composites.” J. Colloid Interface Sci., 255 145–149 (2002)
Adam, NK, Livingston, HK, “Contact Angles and Work of Adhesion.” Nature, 182 128 (1958)
Brandon, S, Haimovich, N, Yeger, E, Marmur, A, “Partial Wetting of Chemically Patterned Surfaces: the Effect of Drop Size.” J. Colloid Interface Sci., 263 237–243 (2003)
Marmur, A, “Soft Contact: Measurement and Interpretation of Contact Angles.” Soft Matter., 2 12–17 (2006)
Wang, C, Xiao, J, Zeng, J, Jiang, D, Yuan, Z, “A Novel Method to Prepare a Microflower-Like Superhydrophobic Epoxy Resin Surface.” Mater. Chem. Phys., 135 10–15 (2012)
Huang, XJ, Kim, DH, Im, M, Lee, JH, Yoon, JB, Choi, YK, “Lock-and-Key Geometry Effect of Patterned Surfaces: Wettability and Switching of Adhesive Force.” Small, 5 90–94 (2009)
Cassie, ABD, Baxter, S, “Wettability of Porous Surfaces.” Trans. Faraday Soc., 40 546–551 (1944)
Larmour, IA, Bell, SE, Saunders, GC, “Remarkably Simple Fabrication of Superhydrophobic Surfaces Using Electroless Galvanic Deposition.” Angew. Chem. Int. Ed., 119 1740–1742 (2007)
Marmur, A, “Underwater Superhydrophobicity: Theoretical Feasibility.” Langmuir, 22 1400–1402 (2006)
Li, M, Xu, J, Lu, Q, “Creating Superhydrophobic Surfaces with Flowery Structures on Nickel Substrates Through a Wet-Chemical-Process.” J. Mater. Chem., 17 72–4776 (2007)
Basu, BBJ, Paranthaman, AK, “A Simple Method for the Preparation of Superhydrophobic PVDF–HMFS Hybrid Composite Coatings.” Appl. Surf. Sci., 255 4479–4483 (2009)
Zhang, Q, Wan, Y, Li, Y, Yang, S, Yao, W, “Friction Reducing Behavior of Stearic Acid Film on a Textured Aluminum Substrate.” Appl. Surf. Sci., 280 545–549 (2013)
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Sun, J., Wang, J. Fabrication of superhydrophobic surfaces on FRP composites: from rose petal effect to lotus effect. J Coat Technol Res 12, 1023–1030 (2015). https://doi.org/10.1007/s11998-015-9692-1
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DOI: https://doi.org/10.1007/s11998-015-9692-1