Abstract
Niobium films were deposited on silicon carbide by chemical vapor deposition using niobium chloride and hydrogen at a temperature range of 900–1300°C. The solid-state reactions between the deposited niobium and silicon carbide matrix were studied by examining the obtained films using X-ray diffraction and energy dispersion spectroscopy. The results indicated that niobium silicides could be formed at the beginning, which blocked further reactions between carbon and niobium to form niobium carbides. When the deposition temperature was increased, silicon would diffuse outward, which allowed the formation of niobium carbides. The reaction process and mechanism are discussed based on the thermodynamics and kinetics.
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References
Jack HK (1976) Sialons and Related Nitrogen Ceramics. J. Mater. Sci., 11 1135–1158. doi:10.1007/BF02396649
Takeda Y (1988) “Development of High-Thermal-Conductive SiC Ceramics.” Am. Ceram. Soc. Bull., 67 1961–1965
Lin GB, Huang JH, Zhang H (2007) “Joints of Carbon Fiber-Reinforced SiC Composites to Ti-Alloy Brazed by Ag–Cu–Ti Short Carbon Fibers.” J. Mater. Proc. Tech. 189 256–261. doi:10.1016/j.jmatprotec.2007.01.031
Chamberlain MB (1980) “Solid State Reaction of Titanium and (0001) α-SiC.” Thin Solid Films, 72 305–311. doi:10.1016/0040-6090(80)90012-7
Naslain R, Pailler R, Martineau P 1984 Fiber-Matrix Interfacial Phenomena in Metal Matrix Composite Materials: Their Effect on Material Processing and Properties, in: Lacombe P, Collongues R, Hanus J, Joud JC, Maurion G, Oudar J, Troyanowsky C (Eds.), Physical Chemistry of the Solid State: Applications to Metals and their Compounds. Elsevier, New York, pp. 481–499
Chou TC (1990) Anomalous Solid State Reaction Between SiC and Pt. J. Mater. Res. 5 601–608. doi:10.1557/JMR.1990.0601
Chou TC, Joshi A, Wadsworth J (1991) Solid state reactions of SiC with Co, Ni, and Pt. J. Mater. Res., 6 796–809. doi:10.1557/JMR.1991.0796
Chou TC, Joshi A (1991) “Selectivity of Silicon Carbide/Stainless Solid-State Reactions and Discontinuous Decomposition of Silicon Carbide.” J. Am. Ceram. Soc., 74(6) 1364–1372. doi:10.1111/j.1151-2916.1991.tb04113.x
Nikitina IP, Vassilevski KV, Wright NG, Horsfall AB, O’Neill AG, Johnson CM (2005) “Formation and Role of Graphite and Nickel Silicide in Nickel Based Ohmic Contacts to n-Type Silicon Carbide. J. Appl. Phys. 97 083709. doi:10.1063/1.1872200
Schiepers RCJ, Van Loo FJI, De With G (1988) “Reactions Between α-Silicon Carbide Ceramic and Nickel or Iron.” J. Am. Ceram. Soc. 71[6] C284–C287. doi:10.1111/j.1151-2916.1988.tb05903.x
Bochnicek Z, Vavra I (2000) “Interdiffusion in Amorphous Nb/Si Multilayers.” Mater. Lett., 45 120–124. doi:10.1016/S0167-577X(00)00089-6
Barzilai S, Raveh A, Frage N (2006) “Inter-Diffusion of Carbon into Niobium Coatings Deposited on Graphite.” Thin Solid Films, 496 450–456. doi:10.1016/j.tsf.2005.09.106
Loehman RE, Ewsuk K, Tomsia AP (1996) “Synthesis of Al2O3–Al Composites by Reactive Metal Penetration.” J. Am. Ceram. Soc., 79(1) 27–32. doi:10.1111/j.1151-2916.1996.tb07876.x
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Wang, Y., Liu, Q., Zhang, L. et al. Solid-state reactions of silicon carbide and chemical vapor deposited niobium. J Coat Technol Res 6, 413–417 (2009). https://doi.org/10.1007/s11998-008-9129-1
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DOI: https://doi.org/10.1007/s11998-008-9129-1