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The oxidation behavior of high-temperature aluminides

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Abstract

The kinetics and mechanisms of oxidelayer formation on Ti-Al-X alloys, specifically Ti-25Al-18Ta, Ti-30Al-2.7Nb, and Ti-43Al-11Nb have been studied. The activation energies for the oxide formation of each of the alloys used in this work were determined, and the values obtained were compared with those obtained by other researchers for identical alloys.

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References

  1. J.H. Westbrook, ed., Mechanical Properties of Intermetallic Compounds (New York: John Wiley & Sons, 1960).

    Google Scholar 

  2. C.T. Liu, J.O. Stiegler, and F.H. Froes, Metals Handbook, Vol. 2—Properties and Selection: Nonferrous Alloys and Special-Purpose Materials, 10th ed. (Materials Park, OH: ASM, 1990), pp. 913–942.

    Google Scholar 

  3. J.H. Westbrook and R.L. Fleischer, ed., Intermetallic Compounds: Principles and Practice (New York: John Wiley & Sons, 1994).

    Google Scholar 

  4. G. Sauthoff, Intermetallics (New York: VCH, 1995), pp. 1–14.

    Google Scholar 

  5. V.K. Sikka, Oxidation and Corrosion of Intertmetallic Alloys, ed. G. Welsch and P.D. Desai (West Lafayette, IN: Purdue Research Foundation, 1996), pp. 1–119.

    Google Scholar 

  6. J.A. Nesbitt and C.E. Lowell, High-Temperature Ordered Intermetallic Alloys V, Vol. 288, ed. I. Baker (Pittsburgh, PA: MRS, 1993), pp. 107–118.

    Google Scholar 

  7. F.C. Grensing. Oxidation of High-Temperature Intermetallics, ed. T. Grobstein and J. Doychak (Warrendale, PA: TMS, 1989), pp. 279–293.

    Google Scholar 

  8. G.H. Meier and F.S. Pettit, Mater. Sci. Eng. A, 153(1992), pp. 548–560.

    Article  Google Scholar 

  9. M.P. Brady et al., JOM, 48 (11) (1996), pp. 46–50.

    CAS  Google Scholar 

  10. J.C. Williams, Structural Intermetallics, ed. M.V. Nathal, R. Darolia, and C.T. Liu (Warrendale, PA: TMS, 1997), pp. 3–8.

    Google Scholar 

  11. K.E. Wiedemann, R.N. Shenoy, and J. Unnam, Met. Trans. A, 18A (1987), pp. 1503–1510.

    Article  CAS  Google Scholar 

  12. P. Kofstad, High Temperature Corresion (London: Elsevier Applied Science Publishing, 1988).

    Google Scholar 

  13. J.E. Benci and J.C. Ma, Structural Intermetallics, ed. M.V. Nathal, R. Darolia, and C.T. Liu (Warrendale, PA: TMS, 1997), pp. 859–868.

    Google Scholar 

  14. G.H. Meier, in Ref. 7,, pp. 1–16.

    Google Scholar 

  15. M. Yamaguchi, Y. Umakoshi, and T. Yamane, Phil. Mag. A, 55 (3) (1987), pp. 301–315.

    CAS  Google Scholar 

  16. Y. Umakoshi et al., J. Mater Sci., 24 (1989), pp. 1599–1603.

    Article  CAS  Google Scholar 

  17. J.L. Smialek and D.L. Humphrey. Scripta Metall. Mater., 26 (1992), pp. 1763–1768.

    Article  CAS  Google Scholar 

  18. G. Welsch, S.L. Friedman, and A.I. Kahveci, Microscopy of Oxidation, ed. M.J. Bennett and G.W. Lorimer (London: Institute of Metals, 1991), pp. 193–205.

    Google Scholar 

  19. R.C. Robinson, Department of Material Science Engineering, Case Westem Reserve University, Cleveland, OH, Final Report (May 1992).

  20. J.S. Fish and D.J. Duquette, Proc. 3rd Intl. Symp. on High Temperature Corrosion and Protection of Materials (Les Embiex, France: 1992) and J. Physique (in press).

  21. R.G. Reddy, X. Wen, and Y. Li, Titanium Extraction and Processing, ed. B. Mishra and G.J. Kipouros (Warrendale, PA: TMS, 1997), pp. 153–161.

    Google Scholar 

  22. S.G. Kumar and R.G. Reddy, Metallurgical and Materials Trans. A, 27A (1996), pp. 1121–1126.

    CAS  Google Scholar 

  23. S.G. Kumar, R.G. Reddy, and L. Brewer, J. of Phase Equilibria, 15 (3) (1994), pp. 279–284.

    CAS  Google Scholar 

  24. G. Welsch and A.I. Kahveci, in Ref. 7,, pp. 207–218.

    Google Scholar 

  25. K.E. Wiedermann et al., in Ref. 7,, pp. 195–206.

    Google Scholar 

  26. R.A. Perkins and G.H. Meier, Proc. Industry-University Advanced Materials Conf., ed. F.W. Smith (Denver, CO: Advanced Materials Institute, 1989), pp. 92–99.

    Google Scholar 

  27. X. Wen and R.G. Reddy, Processing and Fabrication of Advanced Materials V, ed. T.S. Srivatsan and J.J. Moore (Warrendale, PA: TMS, 1996), pp. 379–389.

    Google Scholar 

  28. X. Wen and R.G. Reddy, EPD Congress ’98, ed. B. Mishra (Warrendale, PA: TMS, 1998), pp. 903–924.

    Google Scholar 

  29. J. Doychak, Intermetallic Compounds Principles and Practice, Vol. 1, ed. J.H. Westbrook and R.L. Fleischer (New York: John Wiley & Sons, 1995), pp. 997–1016.

    Google Scholar 

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Author’s Note: All compositions are given in atomic percent unless otherwise indicated.

For more information, contact R.G. Reddy, University of Alabama, Department of Metallurgical and Materials Engineering, A129 Bevill Buiding, P.O. Box 870202, Tuscaloosa, Alabama 35487-0202; (205) 348-1740; fax (205) 348-2164.

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Okafor, I.C.I., Reddy, R.G. The oxidation behavior of high-temperature aluminides. JOM 51, 35–40 (1999). https://doi.org/10.1007/s11837-999-0092-9

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  • DOI: https://doi.org/10.1007/s11837-999-0092-9

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