Abstract
An integrated process for the recovery of zinc that is generated from zinc hydrometallurgy in residues was developed. A mixture of residue and ferric sulfate was first roasted to transform the various forms of zinc in the residue, such as ferrite, oxide, sulfide, and silicate, into zinc sulfate. Next, water leaching was conducted to extract the zinc while the iron remained in the residue as ferric oxide. The effects of the roasting and leaching parameters on zinc recovery were investigated. A maximum zinc recovery rate of 90.9% was achieved for a mixture with a ferric sulfate/residue weight ratio of 0.05 when roasting at 640°C for 30 min before leaching with water at room temperature for 20 min using a liquid/solid ratio of 10. Only 0.13% of the iron was dissolved in the water. Thus, the leaching liquor could be directly returned for zinc smelting.
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Acknowledgements
The authors gratefully acknowledge the teachers and senior fellow apprentices who helped conduct the experiments. In addition, the authors would like to thank the National High Technology Research and Development Program of China (2011AA061001), the Key Project of Science and Technology of Hunan Province, China (2012FJ1010 and2014FJ1011), and the National Natural Science Foundation of China (51474247) for supporting this study.
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Hu, M., Peng, B., Chai, Ly. et al. High-Zinc Recovery from Residues by Sulfate Roasting and Water Leaching. JOM 67, 2005–2012 (2015). https://doi.org/10.1007/s11837-015-1483-8
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DOI: https://doi.org/10.1007/s11837-015-1483-8