Abstract
The interfacial reaction and intermetallic formation at the interface between tin solders containing a small amount of copper with platinum were investigated in this study. Sn-0.7Cu and Sn-1.7Cu solders were reacted with platinum by dipping Pt/Ti/Si specimens into the molten solder at 260°C. Sn-3.8Ag-0.7Cu solder was reacted with platinum by reflowing solder paste on a Pt/Ti/Si substrate at 250°C. PtSn4 intermetallic formed in all specimens while Cu6Sn5 interfacial intermetallic was not observed at the solder/platinum interfaces in any specimens. A parabolic relationship existed between the thickness of the Pt-Sn intermetallic and reaction time, which indicates the intermetallic formation in the solder/platinum interface is diffusion controlled.
Similar content being viewed by others
References
M. Abtew and G. Selavaduray, Mater. Sci. Eng., 27 (2000), p. 95.
A. Zribi et al., J. Electron. Mater., 30 (2001), p. 1157.
S.K. Kang and A. Sarkhel, J. Electron. Mater., 23 (1994), p. 701.
S.T. Yang, Y. Chung, and Y.-H. Kim, J. Microelectronics and Packaging Society, 9 (2002), p. 6.
W.T. Chen, C.E. Ho, and C.R. Kao, J. Mater. Res., 17 (2002), p. 263.
K. Zeng, V. Vuorinen, and J.K. Kivilahti, Proc. 51st Electronic Components and Technology Conf., 693 (2001).
S.C. Hsu, S.J. Wang, and C.Y. Liu, J. Electron. Mater., 32 (2003), p. 1214.
B. Meagher, D. Schwarcz, and M. Chring, J. Mater. Sci., 31 (1996), p. 5479.
M. Klein et al., Electronic Components and Technology Conf., 40 (2000).
J.F. Kuhman et al., Mater. Sci. Eng., 22 (1998), p. 242.
W.G. Kim and K.N. Tu, Materials Chemistry and Physics, 53 (1998), p. 165.
J.H. Kim et al., J. Electron. Mater., 33 (2004), 28.
A.E. Guttensohn, J.D. Hanan, and D. Holderfield, Hybrid Circuit Technology, 4 (1987), p. 21.
D.K. Joo, J. Yu, and S.W. Shin, J. Electron. Mater., 32 (2003), p. 541.
D.W. Kang and J.Y. Huh, J. Kor. Inst. Met. & Mater., 38 (2000), p. 180.
X. Su et al., J. Alloys Comp., 325 (2001), p. 109.
T.B. Massalski, Binary Alloys Phase Diagrams, vol. 2 (Matals Park, OH: ASM, 1986), pp. 1908–1909.
K.S. Shin, W.G. Cho, and Y.-H. Kim, J. Electron. Mater., 32 (2003), p. 483.
S. Choi et al., J. Electron. Mater., 28 (1999), p. 1209.
G. Sharma, C.M. Eichfeld, and S.E. Mohney, J. Electron. Mater., 32 (2003), p. 1209.
T.B. Massalski, Binary Alloys Phase Diagrams, vol. 1 (Metals Park, OH: ASM, 1986), p. 950.
Y.G. Shen et al., Surf. Sci. Rep., 357 (1996), p. 921.
S.T. Yang et al., 2nd Japan-Korea Berkeley Symposium on Advanced Materials, 3 (2003).
S. Chada et al., J. Electron. Mater., 28 (1999), p. 1194.
D.R. Frear, W.B. Jones, and K.R. Kinsman, Solder Mechanics (Warrendale, PA: TMS, 1991), p. 55.
Author information
Authors and Affiliations
Additional information
For more information, contact Young-Ho Kim, Hanyang University, Department of Materials Engineering, Seoul, 133-791, Korea; e-mail kimyh@hanyang.ac.kr.
Rights and permissions
About this article
Cite this article
Kim, T.H., Kim, YH. Sn-Ag-Cu and Sn-Cu solders: Interfacial reactions with platinum. JOM 56, 45–49 (2004). https://doi.org/10.1007/s11837-004-0111-9
Issue Date:
DOI: https://doi.org/10.1007/s11837-004-0111-9