Abstract
This article discusses the potential application of electrically conductive polymers as protective coatings for permanent lead anodes employed in aqueous electrowinning processes. Also presented are results from a preliminary study of the performance of two intrinsically conductive polymers (polyaniline and poly 3,4,5-trifluorophenylthiophene [TFPT]) under mild copper electrowinning conditions as conductive and protective coatings on anodic surfaces. The laboratory results indicated that using lead alloy anodes coated with TFPT merits continued research.
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J. Jenkins et al., “Electrolytic Copper-L. Solvent Extraction and Electrowinning World Operating Data,” Copper 99-Cobre 99, Vol. 4, ed. S.K. Young et al. (Warrendale, PA: TMS, 1999), pp. 493–566.
A.S. Gendron, R.R. Matthews, and W.C. Wilson, “Production of High-Quality Electrorefined and Electrowon Copper at Inco’s Copper Cliff Refinery,” CIM Bulletin, 70 (August 1977), pp. 166–172.
B. Hiskey, “Principle and Practical Considerations of Copper Electrorefining and Electrowinning,” Copper Leaching, Solvent Extraction and Electrowinning Theory, ed. Gerold V. Jergensen II (Littleton, CO: Society for Mining, Metallurgy adn Exploration, 1999), pp. 169–186.
K.L. Hardee and C.W. Brown, “Electrocatalytic Titanium Mesh Surfaces Combined with Standard Lead Substrates for Process Improvements and Power Savings in Copper Electrowinning,” Copper 99-Cobre 99, Vol. 3, ed. J.E. Dutrizac, J. Ji, and V. Ramachandran (Warrendale, PA: TMS, 1999), pp. 575–584.
M. Dattilo and L. J. Lutz, “Merrlin Composite Anodes for Copper Electrowinning,” Copper 99-Cobre 99, Vol. 3, ed. J.E. Dutrizac, J. Ji, and V. Ramachandran (Warrendale, PA: TMS, 1999), pp. 597–601.
M. Stelter, K. Hein, and I. Bauer, “New Energy Saving Lead Anodes for Metal Electrowinning,” Zinc and Lead Processing, ed. J.E. Dutrizac et al. (Montreal, Canada: The Metallurgical Society of CIM, 1998), pp. 389–406.
Peter Langlois (undergraduate thesis, Laurentian University, Sudbury, Canada 1996).
K. Purdy, Phelps Dodge, personal communications (1999).
M. Galvin, “Electrically Active Polymers and Their Applications,” JOM, 49 (3) (1997), pp. 52–55.
H. Sarker et al., “Synthesis and Characterization of Fluoro-Substituted Polythiophenes for Charge Storage Applications,” Synthetic Metals, 88 (1997), pp. 179–185.
Bernhard Wessling, Ormecon Chemie website, www.zipperling.de/Research/Synthmet.
Y. Gofer et al., “Fabrication of an All-Polymer Battery Based on Derivatized Polythiophenes,” Biomedical Instrumentation and Technology (January/February 1998), pp. 33–38.
Y. Gofer et al., “An All-Polymer Charge Storage Device,” Appl. Phys. Lett., 71 (11) (September 1997), pp. 1582–1584.
Y. Gofer et al., “The Electrochemistry of Fluorine-Substituted Polythiophenes for Charge Storage Applications,” J. Electroanalytical Chemistry, 443 (1998), pp. 103–115.
D. Valic (M.A.Sc. thesis, Lauretian University, Sudbury, Canada, 2002).
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For more information, contact A.M. Alfantazi, the University of British Columbia, Department of Metals and Materials Engineering, Vancouver, Canada, V6T 1Z4; (604) 822-8745; fax (604) 822-3619; e-mail alfantaz@interchange.ubc.ca.
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Alfantazi, A.M., Moskalyk, R.R. Conductive polymer coatings for anodes in aqueous electrowinning. JOM 55, 49–55 (2003). https://doi.org/10.1007/s11837-003-0126-7
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DOI: https://doi.org/10.1007/s11837-003-0126-7