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Partial sulfur doping induced variation in morphology of MnFe2O4 with enhanced electrochemical performance for energy storage devices

  • Materials (Organic, Inorganic, Electronic, Thin Films)
  • Published:
Korean Journal of Chemical Engineering Aims and scope Submit manuscript

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Abstract

Manganese ferrite offers several advantages when employed as an electrocatalytic material for supercapacitors, including outstanding cycle stability and energy capacity. When compared to identical-metal sulfides, specific capacitance (Csp) of MnFe2O4 remains inadequate. So, using the hydrothermal synthesis technique, partial sulfur doping of MnFe2O4 was achieved to investigate the synergetic effect of oxides and sulfides. Various spectroscopic and microscopic studies demonstrate that adding sulfur atoms into MnFe2O4 increases the lattice parameters, which improves electrochemical performance. At a current density around 2 A g−1, then calculating MnFe2O4 with partial sulfur doping has a Csp of 1,201.60 F g−1, that is greater than 784.0 F g−1 of pure MnFe2O4. Maximum energy density (Ed) of 93.62 Wh kg−1 was produced with a power density (Pd) of 749 W kg−1. The current study depicts that partial sulfur doping can enhance the electrochemical behavior of MnFe2O4. As a result, the present work shows more effective in field of energy storage by enhancing their poor electrochemical performance.

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Research Data Policy and Data Availability Statements

The corresponding author will provide the datasets created during and/or analyzed during the current investigation upon reasonable request.

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Acknowledgements

Princess Nourah bint Abdulrahman University, located in Riyadh, Saudi Arabia, is supporting researchers under Project Number (PNURSP2023R55). The authors extend their appreciation to the Research Center for Advanced Materials Science (RCAMS), King Khalid University, Saudi Arabia, for funding this work under grant number KKU/RCAMS/023/23.

Author information

Authors and Affiliations

  1. Department of Chemistry, Government College University, Lahore, Pakistan

    Muhammad Abdullah & Sumaira Manzoor

  2. Department of Physics, College of Science, Princess Nourah bint Abdulrahman University, P.O. Box 84428, Riyadh, 11671, Saudi Arabia

    Fatemah Farraj Alharbi & Huda A. Alburaih

  3. University of Education, Lahore, Dera Ghazi Khan Campus, D. G. Khan, 32200, Pakistan

    Rabia Yasmin Khosa

  4. Institute of Chemical Sciences, Bahauddin Zakariya University, Multan, Pakistan

    Abdul Ghafoor Abid & Muhammad Numair Ansari

  5. Research Center for Advanced Materials Science (RCAMS), King Khalid University, Abha, 61413, P.O. Box 9004, Saudi Arabia

    Haitham Elhosiny Ali

  6. Physics Department, Faculty of Science, Zagazig University, Zagazig, Egypt

    Haitham Elhosiny Ali

  7. Centre of Excellence in Solid State Physics, University of the Punjab, Lahore, 54590, Pakistan

    Muhammad Suleman Waheed

  8. Department of Physics, Government College Taunsa, Sharif, Taunsa, 32200, Pakistan

    Hafiz Muhammad Tahir Farid

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  1. Muhammad Abdullah
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  2. Fatemah Farraj Alharbi
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  3. Rabia Yasmin Khosa
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  4. Huda A. Alburaih
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Everyone has contributed equally.

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Correspondence to Hafiz Muhammad Tahir Farid.

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Compliance with Ethical Standards Yes, this paper complies with the journal’s ethical guidelines.

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Abdullah, M., Alharbi, F.F., Khosa, R.Y. et al. Partial sulfur doping induced variation in morphology of MnFe2O4 with enhanced electrochemical performance for energy storage devices. Korean J. Chem. Eng. 40, 1518–1528 (2023). https://doi.org/10.1007/s11814-023-1423-1

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  • DOI: https://doi.org/10.1007/s11814-023-1423-1

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