Abstract
A facilitated transport polyamide (PA) membrane was developed for gas separation by interfacial polymerization reaction of piperazine (PIP) and isophthaloyl chloride (IPC) supported on polysulfone (PSF) membrane previously prepared by dry/wet phase inversion method. The properties of the prepared membranes were characterized by SEM, FT-IR, TGA, and XRD. SEM images showed that a defect-free PSF, and rough PA membranes were fabricated, while the FT-IR spectra confirmed the formation of PA layer on top of the PSF support. The separation performance of the thin film PA and PSF membranes was evaluated using four gasses (CO2, CH4, N2, and O2). Compared to the PSF membrane, the PA membrane demonstrated an increased selectivity of CO2/CH4 and CO2/N2 by 178%, 169%, respectively. This improvement was attributed to the presence of amine functional groups, which acted as a fixed carrier to facilitate the transport of CO2 gas across the membrane. However, building the PA layer on top of PSF support reduced the membrane permeance of CO2 from 2.41 to 2.12 GPU as a result of the increased mass transfer resistance. Furthermore, the effect of operating temperature and pressure on the separation performance of the membranes was investigated.
Similar content being viewed by others
References
J. Adewole, A. Ahmad, S. Ismail and C. Leo, Int. J. Greenh. Gas Control., 17, 46 (2013).
P. Shao, M. Dal-Cin, M. Guiver and A. Kumar, J. Membr. Sci., 427, 451 (2013).
J. Leggett, R. Lattanzio, C. Ek and L. Parker, An Overview of Greenhouse Gas (GHG) Control Policies in Various Countries, Congressional Research Service (2009).
K. Wong, P. Goh and A. Ismail, J. Mater. Chem. A Mater. Energy Sustain., 4, 15726 (2016).
K. Schoots, R. Rivera-tinoco, G. Verbong and B. Van Der Zwaan, Int. J. Greenh. Gas Control., 5, 1614 (2011).
T. Rufford, S. Smart, G. Watson, B. Graham, J. Boxall, J.C. Diniz and E. F. May, J. Pet. Sci. Eng., 94, 123 (2012).
M. Wang, W. Zhi, S. Li, C. Zhang, J. Wang and S. Wang, Energy Environ. Sci., 6, 539 (2013).
B. Shimekit and H. Mukhtar, Natural Gas Purification Technologies Major Advances for CO2 Separation and Future Directions, Advances in Natural Gas Technology, H. Al-Megren, Eds., InTech, Croatia, 235 (2012).
M. Rezakazemi and A. Ebadi, Prog. Polym. Sci., 39, 817 (2014).
Y. Zhang, J. Sunarso, S. Liu and R. Wang, Int. J. Greenh. Gas Control., 12, 84 (2013).
L. Peters, A. Hussain, M. Follmann, T. Melin and M. Hägg, Chem. Eng. J., 172, 952 (2011).
R. Baker and K. Lokhandwala, Ind. Eng. Chem. Res., 47, 2109 (2008).
M.A. Aroon and A. F. Ismail, Sep. Purif. Technol., 75, 229 (2010).
J. Zhao, Z. Wang, J. Wang and S. Wang, J. Membr. Sci., 283, 346 (2006).
X. Yu, Z. Wang, Z. Wei, S. Yuan and J. Zhao, J. Membr. Sci., 362, 265 (2010).
M. Yoshikawa, K. Fujimoto, H. Kinugawa, T. Kitao and N. Ogata, Chem. Lett., 23, 243 (1994).
S. Du, X. Feng and A. Chakma, J. Membr. Sci., 279, 76 (2006).
J. Zou and W. Ho, J. Membr. Sci., 286, 310 (2006).
H. Matsuyama, K. Hirai and M. Teramoto, J. Membr. Sci., 92, 257 (1994).
S. Saedi, S. Madaeni, F. Seidi, A. Shamsabadi and S. Laki, Chem. Eng. J., 236, 263 (2014).
S. Saedi, S. Madaeni, F. Seidi, A. Shamsabadi and S. Laki, Int. J. Greenh. Gas Control., 19, 126 (2013).
S. Saedi, B. Nikravesh, F. Seidi, L. Moradi, A. Shamsabadi, M. Salarabadi and H. Salimi, RSC Adv., 5, 67299 (2015).
J. Albo, J. Wang and T. Tsuru, J. Membr. Sci., 453, 384 (2014).
Y. Zhang, C. Xiao, E. Liu, Q. Du and X. Wang, Desalination, 191, 291 (2006).
L. Lianchao, W. Baoguo, T. Huimin, C. Tianlu and X. Jiping, J. Membr. Sci., 269, 84 (2006).
Y. Shepl, Y. Kotp, M. El-deab, H. Shawky and B. El-anadouli, J. Membr. Sci., 391, 215 (2012).
J. Kim, K. Lee and S. Youl, J. Membr. Sci., 169, 81 (2000).
Y. Zhang, N. E. Benes and R. G. H. Lammertink, Lab. Chip., 15, 575 (2015).
S. Sridhar, B. Smitha, S. Mayor, B. Prathab and T. Aminabhavi, J. Mater. Sci., 42, 9392 (2007).
Z. Zhang, F. Chen, M. Rezakazemi, W. Zhang, C. Lu, H. Chang and X. Quan, Chem. Eng. Res. Des., 131, 375 (2018).
Y. Mo, A. Tiraferri, N.Y. Yip, A. Adout, X. Huang and M. Elimelech, Environ. Sci. Technol., 46, 13253 (2012).
H. Rabiee, S. Meshkat and M. Soltanieh, J. Ind. Eng. Chem., 27, 223 (2015).
P. Jan, F. Detlev, K. Thomas and P. Klaus-viktor, J. Membr. Sci., 389, 343 (2012).
W. Lin, R. H. Vora and T. Chung, J. Polym. Sci. Part B Polym. Phys., 38, 2703 (2016).
F. Dorosti, M. Omidkhah and R. Abedini, J. Nat. Gas Sci. Eng., 25, 88 (2015).
S.C. Pesek and W. J. Koros, J. Membr. Sci., 81, 71 (1993).
M.A. Aroon, A. F. Ismail, M.M. Montazer-rahmati and T. Matsuura, Sep. Purif. Technol., 72, 194 (2010).
B. Chakrabarty, A.K. Ghoshal and M.K. Purkait, J. Membr. Sci., 315, 36 (2008).
R.M. Boom, I. M. Wlenk, T. Van and C. A. Smolders, J. Membr. Sci., 73, 277 (1992).
A.K. Ghosh, B. Jeong, X. Huang and E.M.V. Hoek, J. Membr. Sci., 311, 34 (2008).
F. Yuan, Z. Wang, S. Li, J. Wang and S. Wang, J. Membr. Sci., 421, 327 (2012).
S.D. Bruck, Polymer, 7, 231 (1966).
Y.A. Shepl, Y. H. Kotp, M. S. El-deab, H. A. Shawky and B. E. Elanadouli, J. Membr. Sci., 51, 215 (2012).
K. C. Wong, P. S. Goh, B. C. Ng and A. F. Ismail, RSC Adv., 5, 31683 (2015).
W. Mcdanel, M. G. Cowan, N.O. Chisholm, D. L. Gin and R.D. Noble, J. Membr. Sci., 492, 303 (2015).
S.K. Sen and S. Banerjee, J. Membr. Sci., 350, 53 (2010).
D. Bera, P. Bandyopadhyay, S. Ghosh and S. Banerjee, J. Membr. Sci., 453, 175 (2014).
S. Banerjee, G. Maier, C. Dannenberg and J. Spinger, J. Membr. Sci., 229, 63 (2004).
X. Li, I. Kresse and Z. Xu, Polymer, 42, 6801 (2001).
Q. Xin, H. Wu, Z. Jiang, Y. Li and S. Wang, J. Membr. Sci., 467, 23 (2014).
L. Ansaloni, Y. Zhao, B.T. Jung, K. Ramasubramanian, M. Giacinti and W. S. W. Ho, J. Membr. Sci., 490, 18 (2015).
A. Ebadi, M. Omidkhah and A. Kargari, J. Membr. Sci., 490, 364 (2015).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Awad, A., Aljundi, I.H. Interfacial polymerization of facilitated transport polyamide membrane prepared from PIP and IPC for gas separation applications. Korean J. Chem. Eng. 35, 1700–1709 (2018). https://doi.org/10.1007/s11814-018-0079-8
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11814-018-0079-8