Skip to main content
SpringerLink
Log in

Cassava starch graft copolymer as an eco-friendly corrosion inhibitor for steel in H2SO4 solution

  • Polymer, Industrial Chemistry
  • Published:
Korean Journal of Chemical Engineering Aims and scope Submit manuscript

Abstract

Cassava starch graft copolymer (CSGC) was prepared by grafting acryl amide (AA) onto cassava starch (CS). The inhibition effect of CSGC on the corrosion of cold rolled steel (CRS) in 1.0M H2SO4 solution was first studied by weight loss, potentiodynamic polarization curves, electrochemical impedance spectroscopy (EIS) and scanning electron microscope (SEM) methods. The results show that CSGC is a good inhibitor, and inhibition efficiency of CSGC is higher than that of CS or AA. The adsorption of CSGC on steel surface obeys Langmuir adsorption isotherm. CSGC is a mixed-type inhibitor at 20 °C, while mainly a cathodic inhibitor at 50 °C.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. G. Trabanelli, Corrosion, 47, 410 (1991).

    Article  CAS  Google Scholar 

  2. X. M. Li, Y.N. Liu, J. S. Liu and C.Y. Fu, Total Corros. Control., 23(2), 23 (2012).

    Google Scholar 

  3. Y. Jianguo, W. Lin, V. Otieno-Alego and D. P. Schweinsberg, Corros. Sci., 37, 975 (1995).

    Article  CAS  Google Scholar 

  4. H. Ashassi-Sorkhabi, N. Ghalebsaz-Jeddi, F. Hashemzadeh and H. Jakani, Electrochim. Acta, 51, 3848 (2006).

    Article  CAS  Google Scholar 

  5. X. H. Li, S.D. Deng, H. Fu and G. N. Mu, J. Appl. Electrochem., 39, 1125 (2009).

    Article  CAS  Google Scholar 

  6. X. Zhang, B. J. Gao and Y. L. Shen, Chin. J. Appl. Chem., 25, 212 (2008).

    Google Scholar 

  7. S. A. Ali and M. T. Saeed, Polymer, 42, 2785 (2001).

    Article  CAS  Google Scholar 

  8. S.K. Shukla and M.A. Quraishi, Appl. Poly. Sci., 124, 5130 (2012).

    Article  CAS  Google Scholar 

  9. P. Manivel and S. Sathiyanarayanara, Appl. Poly. Sci., 110, 2807 (2008).

    Article  CAS  Google Scholar 

  10. H.Q. He, Y. J. Hou, L. He, J. Guo, C. H. Yang, W. Li, Y. X. Cai, J. J. Chen and Y. L. Hao, Industry Water Treat., 32, 69 (2012).

    CAS  Google Scholar 

  11. J. G. Zhao, Mater. Prot., 41(5), 23 (2008).

    CAS  Google Scholar 

  12. Y. Guo and S.Z. Song, J. Chem. Industry Eng. (China), 51, 788 (2000).

    CAS  Google Scholar 

  13. A. M. Atta, O. E. El-Azabawy, H. S. Ismail and M. A. Hegazy, Corros. Sci., 53, 1680 (2011).

    Article  CAS  Google Scholar 

  14. Y. H. Zhou, Y. N. Wang, H. Xie and Z.Q. Song, Corros. Sci. Prot. Tech., 15, 324 (2003).

    CAS  Google Scholar 

  15. X.P. Qiu, J.Z. Chen, Q. Wang and Y.A. Liu, Yunnan Chem. Tech., 33(5), 24 (2006).

    Google Scholar 

  16. S. Cheng, Y.S. Yin, S.G. Chen, X.T. Chang, L.N. Yan and T. Liu, J. Chem. Indus. Engin., 58, 704 (2007).

    CAS  Google Scholar 

  17. L. Zhu, Y.F. Wang and B.X. Xu, Corros. Prot., 22, 426 (2001) (in Chinese).

    CAS  Google Scholar 

  18. C. H. Yi, X.Q. Qiu, D. J. Yang and H. M. Lou, J. Chem. Industry Eng. (China), 60, 959 (2009).

    CAS  Google Scholar 

  19. X. J. Wang, X. F. Wang and S.W. Huang, Mater. Prot., 36(12), 45 (2003).

    CAS  Google Scholar 

  20. H. Fu, X. H. Li, Y. X. Li and J. X. Liu, J. Chin. Soc. Corros. Prot., 31, 265 (2011).

    Google Scholar 

  21. X. H. Li, H. Fu, Y. X. Li and N. Zhao, Chin. J. Spectro. Labor., 28, 124 (2011).

    CAS  Google Scholar 

  22. X. H. Li, S.D. Deng and H. Fu, Corros. Sci., 62, 163 (2012).

    Article  CAS  Google Scholar 

  23. X. H. Li, S.D. Deng and H. Fu, Corros. Sci., 55, 280 (2012).

    Article  CAS  Google Scholar 

  24. R. Fuchs-Godec and V. Dolecek, Colloids Surf., A, 244, 73 (2004).

    Article  CAS  Google Scholar 

  25. X. H. Li and S.D. Deng, Corros. Sci., 65, 299 (2012).

    Article  CAS  Google Scholar 

  26. F. Bentiss, M. Lebrini and M. Lagrenée, Corros. Sci., 47, 2915 (2005).

    Article  CAS  Google Scholar 

  27. E. Cano, J. L. Polo, A. La Iglesia and J. M. Bastidas, Adsorption, 10, 219 (2004).

    Article  CAS  Google Scholar 

  28. V. Branzoi, F. Branzoi and M. Baibarac, Mater. Chem. Phys., 65, 288 (2000).

    Article  CAS  Google Scholar 

  29. B. Ateya, B. El-Anadauli and F. El, Corros. Sci., 24, 509 (1984).

    Article  CAS  Google Scholar 

  30. G. Moretti, E. Guidi and F. Fabris, Corros. Sci., 76, 206 (2013).

    Article  CAS  Google Scholar 

  31. C. Cao, Corros. Sci., 38, 2073 (1996).

    Article  CAS  Google Scholar 

  32. C. N. Cao, Corrosion Electrochemistry Mechanism, Chemical Industrial Engineering Press, Beijing, 235 (2004), (in Chinese).

    Google Scholar 

  33. N. Labjar, M. Lebrini, F. Bentiss, N. E. Chihib, S. El Hajjaji and C. Jama, Mater. Chem. Phys., 119, 330 (2010).

    Article  CAS  Google Scholar 

  34. M. Lagrenée, B. Mernari, M. Bouanis, M. Traisnel and F. Bentiss, Corros. Sci., 44, 573 (2002).

    Article  Google Scholar 

  35. A. K. Singh and M. A. Quraishi, Corros. Sci., 52, 152 (2010).

    Article  CAS  Google Scholar 

  36. M. Lebrini, M. Lagrenée, H. Vezin, M. Traisnel and F. Bentiss, Corros. Sci., 49, 2254 (2007).

    Article  CAS  Google Scholar 

  37. Q. Qu, S.A. Jiang, W. Bai and L. Li, Electrochim. Acta, 52, 6811 (2007).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Faculty of Science, Southwest Forestry University, Kunming, 650224, P. R. China

    Xianghong Li

  2. Yunnan Key Laboratory of Wood Adhesives and Glue Products, Southwest Forestry University, Kunming, 650224, P. R. China

    Shuduan Deng

Authors
  1. Xianghong Li
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Shuduan Deng
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Xianghong Li.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Li, X., Deng, S. Cassava starch graft copolymer as an eco-friendly corrosion inhibitor for steel in H2SO4 solution. Korean J. Chem. Eng. 32, 2347–2354 (2015). https://doi.org/10.1007/s11814-015-0044-8

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11814-015-0044-8

Keywords

Search

Navigation