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Enhancing biological treatment of dye wastewater with zero-valent iron

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Abstract

Pretreatment of authentic industrial dye wastewater with zero-valent iron (ZVI) was evaluated using a bench-scale integrated anaerobic-aerobic (ZVI-AO) biological treatment system. Average ADMI (American Dye Manufacturers’ Institute) value of dye wastewater was reduced from 245 to 107 units with ZVI column pretreatment. Subsequent treatment of ZVI column effluent by a continuous AO process further reduced the ADMI values to 18-39, resulting in overall decolorization efficiency of 78-89%. A control AO system without ZVI pretreatment, which was operated in parallel, achieved just 44-69% of ADMI removal efficiency. In addition, the ZVI integrated system yielded effluents with much lower COD and BOD concentrations than the control system. The aerobic batch respiration tests confirmed that ZVI treatment transformed the recalcitrant dye compounds to slowly biodegradable fractions, thus enhancing the overall biodegradability of dye wastewater.

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References

  1. A. Pandey, P. Singh and L. Iyengar, Int. Biodeterior. Biodegrad., 59, 73 (2007).

    Article  CAS  Google Scholar 

  2. F. P. Van der Zee and S. Villaverde, Water Res., 39, 1425 (2005).

    Article  Google Scholar 

  3. L. Ma and W. X. Zhang, Environ. Sci. Technol., 42, 5384 (2008).

    Article  CAS  Google Scholar 

  4. Y. T. Lin, C. H. Weng and F. Y. Chen, Sep. Purif. Technol., 64, 26 (2008).

    Article  CAS  Google Scholar 

  5. H. Y. Shu, M. C. Chang and C. C. Chang, J. Hazard. Mater., 167, 1178 (2009).

    Article  CAS  Google Scholar 

  6. S. K. Nam and P. G. Tratnyek, Water Res., 34(6), 1837 (2000).

    Article  CAS  Google Scholar 

  7. J. R. Perey, P. C. Chiu, C. P. Huang and D. K. Cha, Water Environ. Res., 74(3), 221 (2002).

    Article  CAS  Google Scholar 

  8. J. P. Saxe, B. L. Lubenow, P. C. Chiu, C. P. Huang and D. K. Cha, Water Environ. Res., 78(1), 19 (2006).

    Article  CAS  Google Scholar 

  9. V. M. Correia, T. Stephenson and S. J. Judd, Environ. Technol., 15, 929 (1994).

    Article  Google Scholar 

  10. C. O’Neill, F. R. Hawkes, D. L. Hawkes, N.D. Lourenço, H. M. Pinheiro and W. Delée, J. Chem. Technol. Biotechnol., 74, 1009 (1999).

    Article  Google Scholar 

  11. H. Y. Shu, M. C. Chang, H. H. Yu and W. H. Chen, J. Colloid Interface Sci., 314, 89 (2007).

    Article  CAS  Google Scholar 

  12. M. Henze, Water Sci. Technol., 25(6), 1 (1992).

    CAS  Google Scholar 

  13. P. A. Vanrolleghem, H. Spanjers, B. Petersen, P. Ginestet and I. Takacs, Water Sci. Technol., 39(1), 195 (1999).

    Article  Google Scholar 

  14. J. J. Yu, G. W. Gu, G. Esposito, M. Fabbricino, S. P. Wang and L. P. Sun, Environ. Technol., 31(11), 1191 (2010).

    Article  CAS  Google Scholar 

  15. K. Dircks, P. F. Pind, H. Mosbæk and M. Henze, Water SA, 25(1), 69 (1999).

    CAS  Google Scholar 

  16. W. Allen, W. B. Prescott, R. E. Derby, C. E. Garland, J. M. Peret and M. Saltzman, in Proceedings of 28th Ind. Waste Conference, Purdue Univ., Eng. Ext. Ser. No. 142, 661 (1973).

    Google Scholar 

  17. American Public Health Association, American Water Works Association, Water Environment Federation, Standard Methods for the Examination of Water and Wastewater, 22nd Ed., Washington, D.C. (2012).

    Google Scholar 

Download references

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Correspondence to Younggyun Choi.

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Choi, Y., Park, B. & Cha, D.K. Enhancing biological treatment of dye wastewater with zero-valent iron. Korean J. Chem. Eng. 32, 1812–1817 (2015). https://doi.org/10.1007/s11814-014-0388-5

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  • DOI: https://doi.org/10.1007/s11814-014-0388-5

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