Abstract
A series of Co-Ni nano catalysts were prepared by co-precipitation method. We investigated the effect of Co/Ni molar ratios precipitate and calcination conditions on the catalytic performance of cobalt nickel catalysts for Fisher-Tropsch synthesis (FTS). The catalyst containing 90%Co/10%Ni was found to be optimal for the conversion of synthesis gas to light olefins. The activity and selectivity of the optimal catalyst were studied in different operational conditions. The results show that the best operational conditions are the H2/CO=2/1 molar feed ratio at 310 °C and GHSV=1,200 h−1 under 5 bar of pressure. The prepared catalysts were characterized by powder X-ray diffraction (XRD), N2 adsorption-desorption measurements such as BET and BJH methods, transmission electron microscopy (TEM) and thermal gravimetric analysis (TGA).
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H. Weyda and E. Kohler, Catal. Today, 81, 51 (2003).
N. Tsubaki, Y. Yoneyama, K. Michiki and K. Fujimoto, Catal. Commun., 4, 108 (2003).
T. Matsuda, H. Sakagamif and N. Takahashi, Catal. Today, 81, 31 (2003).
M. E. Vannice, Catal. Rev. Sci. Eng., 14, 153 (1976).
E. Iglesia, S. L. Soled, R. A. Fiato and G. H. Via, J. Catal., 143, 345 (1993).
M. Feyzi and A. A. Mirzaei, Iran J. Chem. Chem. Eng., 30, 1 (2011).
E. Iglesia, Appl. Catal. A: Gen., 161, 59 (1997).
A. R. Belambe, R. Oukaci and J. G. Goodwin, J. Catal., 166, 8 (1997).
A. Lapidus, A. Krylova, V. Kazanskii, V. Borovkov, J. Rathousky, A. Zukal and M. Jancalkova, Appl. Catal. A: Gen., 73, 65 (1991).
J. Rathousky, A. Zukal, A. Lapidus and A. Krylova, Appl. Catal. A: Gen., 79, 167 (1991).
A. Lapidus, A. Krylova, J. Rathousky, A. Zukal and M. Jancalkova, Appl. Catal. A: Gen., 80, 1 (1992).
R. Sethuraman, N. N. Bakhshi, S. P. Katikaneni and R. O. Idem, Fuel Process. Technol., 73, 197 (2001).
J. R. Anderson, Catalysis: Science and Technology, New York, Springer-Verlag Press, 1, 159 (1981).
G. Parkinson, Chem. Eng., 4, 39 (1997).
C. Wang, L. Xu and Q. Wang, J. Nat. Gas Chem., 12, 10 (2003).
M. Feyzi and F. Jafari, J. Fuel Chem. Technol., 40, 5 (2012).
F. Stoop and K. V. Wiele, Appl. Catal. A: Gen., 23, 35 (1986).
H. Arakawa, Y. Kiyozumi and K. Suzuki, Chem. Lett., 176, 1341 (1986).
J. P. Hindermann, G. J. Hutchings and A. Kiennemann, Catal. Rev. Sci. Eng., 35, 1 (1993).
D. O. Uner, Ind. Eng. Chem. Res., 37, 2239 (1998).
I.R. Leth and M.G. Howden, Appl. Catal. A: Gen., 37, 75 (1988).
W. J. Shen, S.R. Yan, J. L. Zhou and B. J. Zhang, J. Nat. Gas Conv., 4, 311 (1995).
E. Iglesia, Appl. Catal., 161, 59 (1997).
S. Li, S. Krishnamoorthy, G.D. Meitzner and E. Iglesia, Catal. Lett., 47, 197 (2002).
A. Trovarelli, Catalysis by ceria and related materials, London, Imperial College Press, 123–145 (2002).
J. Gaube, K. Herzog, L. Knig and B. Schliebs, Chem. Ing. Technol., 58, 682 (1986).
R. L. Varma, Liu Dan-Chu, J. F. Mathews and N. N. Bakhshi, Can. J. Chem. Eng., 63, 72 (1985).
A. A. Mirzaei, M. Faizi and R. Habibpour, Appl. Catal. A: Gen., 306, 98 (2006).
H. B. Zhang and G. L. Schrader, J. Catal., 95, 325 (1985).
M. D. Shroff, D. S. Kalakkad, S. Kohler, N. B. Jackson, A.G. Sault and A. K. Datye, J. Catal., 156, 185 (1995).
K. Kuramori, K. Suehiro and Y. Oishi, Stud. Surf. Sci. Catal., 136, 417 (2001).
G. L. Bezemer, J. H. Bitter, H. P. C. E. Kuipers, H. Oosterbeek, J. E. Holewijn, X. Xu, F. Apteijn, A. J. Van Dillen and K. P. De Jong, J. Am. Chem. Soc., 128, 3956 (2006).
J. S. Girardon, E. Quinet, A. Griboval-Constant, P.A. Chernavskii, L. Gengembre and A. Y. Khodakov, J. Catal., 248, 143 (2007).
A. S. Lermontov, J. S. Girardon, A. Griboval-Constant, S. Pietrzyk and A. Y. Khodakov. Catal. Lett., 101, 117 (2005).
K. R. Krishna and A. T. Bell, J. Catal., 139, 104 (1993).
R. B. Anderson, B. Seligman, J. F. Shultz, R. Kelly and M. A. Elliott, Ind. Eng. Chem., 44, 391 (1952).
D. K. Matsumoto and C. N. Satterfield, Energy Fuels, 3, 249 (1989).
J. Barrault, C. Forquy and V. Perrichon, Appl. Catal. A: Gen., 5, 119 (1983).
D. B. Bukur, X. Lang, A. Akgerman and Z. Feng, Ind. Eng. Chem. Res., 36, 2580 (1997).
H. Schulz and M. Claeys, Appl. Catal. A: Gen., 186, 71 (1999).
H. Schulz, E. Van Steen and M. Claeys, Stud. Surf. Sci. Catal., 81, 455 (1994).
A. Griboval-Constant, A. Y. Khodakov, R. Bechara and V. L. Zholobenko, Stud. Surf. Sci. Catal., 144, 609 (2002).
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Feyzi, M., Babakhanian, A. & Gholivand, M.B. Catalytic performance and characterization of cobalt-nickel nano catalysts for CO hydrogenation. Korean J. Chem. Eng. 31, 37–44 (2014). https://doi.org/10.1007/s11814-013-0186-5
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DOI: https://doi.org/10.1007/s11814-013-0186-5