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Reprocessing of spent nuclear waste using ionic liquids

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Abstract

Nuclear power has once again attracted from all over the world due to many factors including the rise in oil process and environmental concerns on greenhouse gas emission resulting in global warming. However, spent fuel from nuclear power reactors is an enormous problem both from radiation hazard and economical point of view. Therefore, this review presents an overview of application of ionic liquids (ILs) in spent fuel reprocessing, particularly in the extraction of high-level radioactive aqueous waste from the processing of nuclear fuel.

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References

  1. I. Hore-Lacy, Nuclear energy in the 21 st century, World Nuclear Univ. Press, London (2006).

    Google Scholar 

  2. G. J. Lumetta, K. L. Nash, S. B. Clark and J. I. Friese, Separations for the nuclear fuel cycle in the 21 st century, American Chemical Society, Washington (2006).

    Google Scholar 

  3. P.A. Baisden and G. R. Choppin, in Radiochemistry and nuclear chemistry, S. Nagy Ed., EOLSS (2007).

  4. P. K. Dey and N. K. Bansal, Nucl. Eng. Des., 236, 723 (2006).

    Article  CAS  Google Scholar 

  5. C. L. Riddle, J.D. Baker, J.D. Law, C.A. McGrath, D.H. Meikrantz, B. J. Mincher, D. R. Peterman and T.A. Todd, Solvent Extr. Ion Exch., 23, 449 (2004).

    Article  Google Scholar 

  6. E. P. Horwitz, M. L. Dietz and D. E. Fisher, Solvent Extr. Ion Exch., 9, 1 (1991).

    Article  CAS  Google Scholar 

  7. D. J. Wood, T. J. Tranter and T.A. Todd, Solvent Extr. Ion Exch., 13, 829 (1995).

    Article  CAS  Google Scholar 

  8. J. F. Dozol, N. Simon, V. Lamare, H. Rouquette, S. Eymard, B. Tournois, D. De Marc and R. M. Macias, Sep. Sci. Technol., 34, 877 (1999).

    CAS  Google Scholar 

  9. P.V. Bonnesen, L. H. Delmau, B. A. Moyer and R. A. Leonard, Solvent Extr. Ion Exch., 18, 1079 (2000).

    Article  CAS  Google Scholar 

  10. M.A. Norato, M. H. Beasley, S.G. Campbell, A. D. Coleman, M.W. Geeting, J.W. Guthrie, C.W. Kennell, R.A. Pierce, R.C. Ryberg, D. D. Walker, J. D. Law and T.A. Todd, Sep. Sci. Technol., 38, 2647 (2003).

    Article  CAS  Google Scholar 

  11. B. J. Mincher, G. Modolo and S. P. Mezyk, Solvent Extr. Ion Exch., 27, 579 (2009).

    Article  CAS  Google Scholar 

  12. E. R. Nazin, G.M. Zachinyaev and G. F. Egorov, Radiochemistry, 46, 54 (2004).

    Article  CAS  Google Scholar 

  13. R.A. Sheldon, R.M. Lau, M. J. Sorgedrager and F. van Rantwijk, Green Chem., 4, 147 (2002).

    Article  CAS  Google Scholar 

  14. M. Freemantle, Chem. Eng. News, 76, 32 (1998).

    Google Scholar 

  15. Y.H. Moon, S. M. Lee, S.H. Ha and Y.-M. Koo, Korean J. Chem. Eng., 23, 247 (2006).

    Article  CAS  Google Scholar 

  16. L. C. Branco, J.G. Crespo and C.A. M. Afonso, Chem. Eur. J., 8, 3865 (2002).

    Article  CAS  Google Scholar 

  17. A. Noda and M. Watanabe, Electrochim. Acta, 45, 1265 (2000).

    Article  CAS  Google Scholar 

  18. F. van Rantwijk and R.A. Sheldon, Chem. Rev., 107, 2757 (2007).

    Article  Google Scholar 

  19. P. Giridhar, K.A. Venkatesan, T.G. Srinivasan and P. R. Vasudeva Rao, J. Radioanal. Nucl. Chem., 265, 31 (2005).

    Article  CAS  Google Scholar 

  20. P. Giridhar, K.A. Venkatesan, T.G. Srinivasan and P. R. Vasudeva Rao, J. Nucl. Radiochem. Sci., 5, 21 (2004).

    CAS  Google Scholar 

  21. P. Giridhar, K.A. Venkatesan, S. Subramaniam, T.G. Srinivasan and P. R. Vasudeva Rao, J. Alloys Comp., 448, 104 (2008).

    Article  CAS  Google Scholar 

  22. P. Giridhar, K.A. Venkatesan, T.G. Srinivasan and P. R. Vasudeva Rao, Electrochim. Acta, 52, 3006 (2007).

    Article  CAS  Google Scholar 

  23. A. Ouadi, O. Klimchuk, C. Gaillarda and I. Billard, Green Chem., 9, 1160 (2007).

    Article  CAS  Google Scholar 

  24. M. L. Dietz and D.C. Stepinski, Talanta., 75, 598 (2008).

    Article  CAS  Google Scholar 

  25. P.Y. Chen and C. L. Hussey, Electrochim. Acta, 49, 5125 (2004).

    Article  CAS  Google Scholar 

  26. S. Dai, Y. H. Ju and C. E. Barnes, J. Chem. Soc., Dalton Trans., 8, 1201 (1999).

    Article  Google Scholar 

  27. A. E. Visser, R. P. Swatloski, W.M. Reichert, S. T. Griffin and R. D. Rogers, Ind. Eng. Chem. Res., 39, 3596 (2000).

    Article  CAS  Google Scholar 

  28. M. L. Dietz, J.A. Dzielawa, I. Laszak, B.A. Young and M. P. Jensen, Green Chem., 5, 682 (2003).

    Article  CAS  Google Scholar 

  29. H. Luo, S. Dai, P.V. Bonnesen, A. C. Buchanan III, J.D. Holbrey, N. J. Bridges and R. D. Rogers, Anal. Chem., 76, 3078 (2004).

    Article  CAS  Google Scholar 

  30. H. Luo, S. Dai and P.V. Bonnesen, Anal. Chem., 76, 2773 (2004).

    Article  CAS  Google Scholar 

  31. H. Luo, S. Dai, P.V. Bonnesen and A. C. Buchanan III, J. Alloys Compd., 418, 195 (2006).

    Article  CAS  Google Scholar 

  32. P. Y. Chen, Electrochim. Acta, 52, 5484 (2007).

    Article  CAS  Google Scholar 

  33. Z. Kolarik, U. Müllich and F. Gassner, Solvent Extr. Ion Exch., 17, 23 (1999).

    Google Scholar 

  34. G. Modolo and R. Odoj, Solvent Extr. Ion Exch., 17, 33 (1999).

    Article  CAS  Google Scholar 

  35. A. E. Visser and R. D. Rogers, J. Solid State Chem., 171, 109 (2003).

    Article  CAS  Google Scholar 

  36. Y. Zuo, Y. Liu, J. Chen and D. Q. Li, Ind. Eng. Chem. Res., 47, 2349 (2008).

    Article  CAS  Google Scholar 

  37. F. Kubota, Y. Koyanagi, K. Nakashima, K. Shimojo, N. Kamiya and M. Goto, Solvent Extr. Res. Dev. Jpn., 15, 81 (2008).

    CAS  Google Scholar 

  38. K. Shimojo, K. Kurahashi and H. Naganawa, Dalton Trans., 37, 5083 (2008).

    Article  Google Scholar 

  39. J. P. Schoebrechts, B. P. Gilbert and G. Duyckaerts, J. Electroanal Chem., 145, 127 (1983).

    Article  CAS  Google Scholar 

  40. J. P. Schoebrechts, B. P. Gilbert and G. Duyckaerts, J. Electroanal Chem., 145, 139 (1983).

    Article  CAS  Google Scholar 

  41. R.D. Waele, L. Heerman and W.D. Olieslager, J. Electroanal Chem., 142, 137 (1982).

    Article  Google Scholar 

  42. J. P. Schoebrechts and B. P. Gilbert, Inorg. Chem., 24, 2105 (1985).

    Article  CAS  Google Scholar 

  43. M. Yamagata, Y. Katayama and T. Miura, J. Electrochem. Soc., 153, E5 (2006).

    Article  CAS  Google Scholar 

  44. W.H. Smith and D.A. Costa, Radiat. Phys. Chem., 60, 157 (2001).

    Article  Google Scholar 

  45. D. Allen, G. Baston, A. E. Bradley, T. Gorman, A. Haile, I. Hamblett, J. E. Hatter, M. J. F. Healey, B. Hodgson, R. Lewin, K.V. L. B. Newton, W. R. Pitner, D.W. Rooney, D. Sanders, K. R. Seddon, H. E. Sims and R. C. Thied, Green Chem., 4, 152 (2002).

    Article  CAS  Google Scholar 

  46. L. Berthon, S. I. Nikitenko, I. Bisel, C. Berthon, M. Faucon, B. Saucerotte, N. Zorz and Ph. Moisy, Dalton Trans., 2526 (2006).

  47. E. Bosse, L. Berthon, N. Zorz, J. Monget, C. Berthon, I. Bisel, S. Legand and Ph. Moisy, Dalton Trans., 924 (2008).

  48. M.Y. Qi, G. Z. Wu, S.M. Chen and Y. D. Liu, Radiat. Res., 167, 508 (2007).

    Article  CAS  Google Scholar 

  49. M.Y. Qi, G. Z. Wu, Q.M. Li and Y. S. Luo, Radiat. Phys. Chem., 77, 877 (2008).

    Article  CAS  Google Scholar 

  50. L.Y. Yuan, J. Peng, L. Xu, M. L. Zhai, J.Q. Li and G. S. Wei, Dalton Trans., 6358 (2008).

  51. L.Y. Yuan, J. Peng, L. Xu, M. L. Zhai, J.Q. Li and G. S. Wei, Radiat. Phys. Chem., 78, 1133 (2009).

    Article  CAS  Google Scholar 

  52. P. Tarabek, S.Y. Liu, K. Haygarth and D. M. Bartels, Radiat. Phys. Chem., 78, 168 (2009).

    Article  CAS  Google Scholar 

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Correspondence to Yoon-Mo Koo.

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Yoon-Mo Koo is a Professor in the Department of Chemical and Biological Engineering at Inha University, Korea. He received B.S. degree (Seoul National University, Korea), M.S. degree (KAIST, Korea), and Ph.D. degree (Purdue University) all in Chemical Engineering. He served as the Dean of College of Engineering, Inha University, the President of the Korean Society of Biotechnology and Bioengineering, and is currently a Member of the National Academy of Engineering, Korea. His research interests include biological separation and purification, microbial mixed culture, and ionic liquids.

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Ha, S.H., Menchavez, R.N. & Koo, YM. Reprocessing of spent nuclear waste using ionic liquids. Korean J. Chem. Eng. 27, 1360–1365 (2010). https://doi.org/10.1007/s11814-010-0386-1

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  • DOI: https://doi.org/10.1007/s11814-010-0386-1

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