Skip to main content
Log in

Layered liquid-liquid flow in microchannels having selectively modified hydrophilic and hydrophobic walls

  • Separation Technology, Thermodynamics
  • Published:
Korean Journal of Chemical Engineering Aims and scope Submit manuscript

Abstract

When two immiscible liquids make contact in a microchannel, the flow pattern is affected by the affinity between channel walls and liquids. In this study, microchannels (200 µm in width and 200 µm in depth) having a T-shaped bifurcation point were fabricated on PMMA plates. The inner walls of the microchannels were modified in a zone-selective manner to be either hydrophilic or hydrophobic, based on verification accomplished via a laser interference fringe technique. The microchannel was placed horizontally, and water and octane were introduced into the upper-side channel (hydrophilic) and into the lower-side channel (hydrophobic), respectively. The experimental results showed that water and octane formed a stable layered flow, and the two liquids were virtually completely separated at the T-shaped section, even when static pressure was intentionally applied to the outlets. CFD simulation, using FLUENT 6.3 software, was performed to explain the role of zone-selective modification of microchannel walls.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. J. Choe, Y. Kwon, Y. Kim, H. S. Song and K. H. Song, Korean J. Chem. Eng., 20, 268 (2003).

    Article  CAS  Google Scholar 

  2. V. Hessel, S. Hardt and H. Löwe, Chemical micro process engineering, fundamentals, modelling and reactors, Wiley-VCH Wiley-VCH, Weinheim, Germany (2003).

    Google Scholar 

  3. V. Hessel, H. Löwe, A. Müller and C. Kolb, Chemical micro process engineering, processing and plants, Wiley-VCH, Weinheim, Germany (2004).

    Book  Google Scholar 

  4. K. I. Sotowa, R. Miyoshi, C. G. Lee, Y. Kang and K. Kusakabe, Korean J. Chem. Eng., 22, 552 (2005).

    Article  CAS  Google Scholar 

  5. N. Kitamura, K. Ueno and H.-B. Kim, Anal. Sic., 24, 701 (2008).

    Article  CAS  Google Scholar 

  6. J.-I. Yoshida, FLASH CHEMISTRY, Fast organic synthesis in microsystems, Wiley, Chichester, UK (2008).

    Google Scholar 

  7. V. Hessel, A. Renken, J. C. Shouten and J. Yoshida (edts.), Micro process engineering, a comprehensive handbook, Wiley-VCH, Weinheim, Germany (2009).

    Google Scholar 

  8. A.-L. Dessimos, L. Cavin, A. Renken and L. Kiwi-Minste, Chem. Eng. Sci., 63, 4035 (2008).

    Article  Google Scholar 

  9. Y. Yamaguchi, F. Takagi, K. Yamashita, H. Nakamura and H. Maeda, AIChE J., 50, 1530 (2004).

    Article  CAS  Google Scholar 

  10. Y. Yamaguchi, T. Honda, M. P. Briones, K. Yamashita, M. Miyazaki, H. Nakamura and H. Maeda, Chem. Eng. Technol., 30, 379 (2007).

    Article  CAS  Google Scholar 

  11. B. Zhao, N. O. L. Viernes, J. S. Moore and D. J. Beebe, J. Am. Chem. Soc., 124, 5284 (2002).

    Article  CAS  Google Scholar 

  12. H.-B. Kim, K. Ueno, M. Chiba, O. Kogi and N. Kitamura, Anal. Sci., 16, 871 (2000).

    Article  CAS  Google Scholar 

  13. A. Hibara, M. Tokeshi, K. Uchiyama, H. Hisamoto and T. Kitamori, Anal. Sci., 17, 89 (2001).

    Article  CAS  Google Scholar 

  14. A. Hibara, M. Nonaka, H. Hisamoto, K. Uchiyama, Y. Kikutani, M. Tokeshi and T. Kitamori, Anal. Chem., 74, 1724 (2002).

    Article  CAS  Google Scholar 

  15. A. Arata, A. Hibara and T. Kitamori, Anal. Chem., 79, 3919 (2007).

    Article  Google Scholar 

  16. A. Kariyasaki, Y. Yamasaki, M. Kagawa, T. Nagashima, A. Ousaka and S. Morooka, Heat Transfer Eng., 30, 28 (2009).

    Article  CAS  Google Scholar 

  17. Y. Yamasaki, M. Goto, A. Kariyasaki and S. Morooka, Kagaku Kogaku Ronbunshu, 34, 175 (2008).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Shigeharu Morooka.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Yamasaki, Y., Goto, M., Kariyasaki, A. et al. Layered liquid-liquid flow in microchannels having selectively modified hydrophilic and hydrophobic walls. Korean J. Chem. Eng. 26, 1759–1765 (2009). https://doi.org/10.1007/s11814-009-0265-9

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11814-009-0265-9

Key words

Navigation