Abstract
Compressive strength and mineralogical and microstructural characterization of the pastes prepared from alkali-activation of low calcium fly ash were investigated. XRD and FTIR were used to observe the mineralogical characterization; SEM, MIP, and NMR were used to observe the microstructural characterization of the pastes. The higher strength of paste was attributed to a more compact and continuous gelatinous matrix due to restructuring of reaction product. The lower values of both porosity (31.0%) and mean pore diameter (9.7 nm) of fly ash-pastes alkali-activated at 85 °C for 24 hr indicate higher reactivity of these pastes compared with other pastes, and result in the higher compressive strength.
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D. Li, Z. Xu, Z. Luo, Z. Pan and L. Cheng, Cement & Concrete Composites, 32, 1145 (2002).
A. Guerrero, S. Goñi, A. Macías and M. P. Luxán, J. Mater. Res., 14, 2680 (1999).
A. Fernández-Jiménez and A. Palomo, Cement & Concrete Research, 35, 1984 (2005).
X. Zhaohui and X. Yunping, Cement & Concrete Research, 31, 1245 (2001).
R. Hossein and B. William, Environ. Sci. Technol., 37, 3454 (2003).
A. Samdi, PhD dissertation of Drexel University, Treatment of fly ash to increase its cementitious characteristics, Philadelphia, PA (1996).
P. Arjunan, M. R. Silsbee and D. M. Roy, Chemical activation of low calcium fly ash: Part: Identification of the most appropriate activators and their dosage, Proceedings of the Intl. Ash Utilization Symposium, Kentucky (2001).
Van J.G. S. Jaarsveld and Van J. S. J. Deventer, Miner. Eng., 10, 659 (1997).
J. Davidovits, J. Mater. Eng., 16, 91 (1994).
A. Palomo, M.W. Grutzeck and M. T. Blanco, Cement & Concrete Research, 29, 1323 (1999).
S. S. Park and H.Y. Kang, Korean J. Chem. Eng., 23, 367 (2005).
V. F. F. Barbosa, K. J. D. MacKenzie and C. Thaumaturgo, Int. J. Inorg. Mater., 2, 309 (2000).
I.G. Richardson, A. R. Brough, G.W. Groves and C. M. Dobson, Cement & Concrete Research, 24, 813 (1994).
F. Puertas and A. Fernández-Jiménez, Cement & Concrete Composites, 25, 287 (2003).
G. Engelhardt and D. Michel, High resolution solid state NMR of silicates and zeolites, Wiley (1987).
J. Skibsted, E. Henderson and H. J. Jakobsen, Inorg. Chem., 32, 1013 (1993).
M. D. Andersen, H. J. Jakobsen and J. Skibsted, Inorg. Chem., 42, 2280 (2003).
A. Palomo and J. I. López de la Fuente, Cement & Concrete Research, 33, 281 (2003).
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Park, SS., Kang, HY. Characterization of fly ash-pastes synthesized at different activator conditions. Korean J. Chem. Eng. 25, 78–83 (2008). https://doi.org/10.1007/s11814-008-0013-6
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DOI: https://doi.org/10.1007/s11814-008-0013-6