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Performance of activated carbon coated graphite bipolar electrodes on capacitive deionization method for salinity reduction

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Abstract

This research investigates a capacitive deionization method for salinity reduction in a batch reactor as a new approach for desalination. Reductions of cost and energy compared with conventional desalination methods are the significant advantages of this approach. In this research, experiments were performed with a pair of graphite bipolar electrodes that were coated with a one-gram activated carbon solution. After completing preliminary tests, the impacts of four parameters on electrical conductivity reduction, including (1) the initial concentration of feed solution, (2) the duration of the tests, (3) the applied voltage, and (4) the pH of the solution, were examined. The results show that the maximum efficiency of electrical conductivity reduction in this laboratory-scale reactor is about 55%. Furthermore, the effects of the initial concentration of feed solution are more significant than the other parameters. Thus, using the capacitive deionization method for water desalination with low and moderate salt concentrations (i.e., brackish water) is proposed as an affordable method. Compared with conventional desalination methods, capacitive deionization is not only more efficient but also potentially more environmentally friendly.

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References

  • Ahirrao D J, Tambat S, Pandit A B, Jha N (2019). Sweet-lime-peels-derived activated-carbon-based electrode for highly efficient super-capacitor and flow-through water desalination. ChemistrySelect, 4(9): 2610–2625

    Article  CAS  Google Scholar 

  • Ahmed M A, Tewari S (2018). Capacitive deionization: Processes, materials and state of the technology. Journal of Electroanalytical Chemistry, 813: 178–192

    Article  CAS  Google Scholar 

  • AlMarzooqi F A, Al Ghaferi A A, Saadat I, Hilal N (2014). Application of capacitive deionisation in water desalination: A review. Desalination, 342: 3–15

    Article  CAS  Google Scholar 

  • Ban A, Schafer A, Wendt H (1998). Fundamentals of electrosorption on activated carbon for wastewater treatment of industrial effluents. Journal of Applied Electrochemistry, 28(3): 227–236

    Article  CAS  Google Scholar 

  • Bao W, Tang X, Guo X, Choi S, Wang C, Gogotsi Y, Wang G (2018). Porous cryo-dried MXene for efficient capacitive deionization. Joule, 2(4): 778–787

    Article  CAS  Google Scholar 

  • Blair J W, Murphy G W (1960) Electrochemical demineralization of water with porous electrodes of large surface area. In: Saline Water Conversion. Washington, DC: American Chemical Society, 206–223

    Chapter  Google Scholar 

  • Design Expert Software (2015) Design Expert Software, Version 9, User’s Guide

  • Dutta S, Huang S Y, Chen C, Chen J E, Alothman Z A, Yamauchi Y, Hou C H, Wu K C W (2016). Cellulose framework directed construction of hierarchically porous carbons offering high-performance capacitive deionization of brackish water. ACS Sustainable Chemistry & Engineering, 4(4): 1885–1893

    Article  CAS  Google Scholar 

  • Gustafsson J, Mikkola P, Jokinen M, Rosenholm J B (2000). The influence of pH and NaCl on the zeta potential and rheology of anatase dispersions. Colloids and Surfaces. A, Physicochemical and Engineering Aspects, 175(3): 349–359

    Article  CAS  Google Scholar 

  • Han L, Karthikeyan K G, Anderson M A, Wouters J J, Gregory K B (2013). Mechanistic insights into the use of oxide nanoparticles coated asymmetric electrodes for capacitive deionization. Electrochimica Acta, 90: 573–581

    Article  CAS  Google Scholar 

  • Khajouei G, Mortazavian S, Saber A, Zamani Meymian N, Hasheminejad H (2019). Treatment of composting leachate using electro-Fenton process with scrap iron plates as electrodes. International Journal of Environmental Science and Technology, 16(8): 4133–4142

    Article  CAS  Google Scholar 

  • Laxman K, Myint M T Z, Al Abri M, Sathe P, Dobretsov S, Dutta J (2015). Desalination and disinfection of inland brackish ground water in a capacitive deionization cell using nanoporous activated carbon cloth electrodes. Desalination, 362: 126–132

    Article  CAS  Google Scholar 

  • Li L, Zou L, Song H, Morris G (2009). Ordered mesoporous carbons synthesized by a modified sol-gel process for electrosorptive removal of sodium chloride. Carbon, 47(3): 775–781

    Article  CAS  Google Scholar 

  • Liu D, Huang K, Xie L, Tang H L (2015). Relation between operating parameters and desalination performance of capacitive deionization with activated carbon electrodes. Environmental Science. Water Research & Technology, 1(4): 516–522

    Article  CAS  Google Scholar 

  • Liu P, Yan T, Shi L, Park H S, Chen X, Zhao Z, Zhang D (2017a). Graphene-based materials for capacitive deionization. Journal of Materials Chemistry. A, Materials for Energy and Sustainability, 5(27): 13907–13943

    Article  CAS  Google Scholar 

  • Liu P, Yan T, Zhang J, Shi L, Zhang D (2017b). Separation and recovery of heavy metal ions and salt ions from wastewater by 3D graphene-based asymmetric electrodes via capacitive deionization. Journal of Materials Chemistry. A, Materials for Energy and Sustainability, 5(28): 14748–14757

    Article  CAS  Google Scholar 

  • Montgomery D C (2012) Design and Analysis of Experiments, 8th ed. Hoboken: John Wiley & Sons

    Google Scholar 

  • Montgomery D C (2017) Design and Analysis of Experiments, 13th ed. Hoboken: John Wiley & Sons

    Google Scholar 

  • Ohshima H, Furusawa K (1998) Electrical phenomena at interfaces: Fundamentals: Measurements, and applications, 2nd ed. Boca Raton: CRC Press

    Google Scholar 

  • Oren Y, Soffer A (1983). Water desalting by means of electrochemical parametric pumping. Journal of Applied Electrochemistry, 13(4): 473–487

    Article  CAS  Google Scholar 

  • Pekala R W, Farmer J C, Alviso C T, Tran T D, Mayer S T, Miller J M, Dunn B (1998). Carbon aerogels for electrochemical applications. Journal of Non-Crystalline Solids, 225: 74–80

    Article  CAS  Google Scholar 

  • Porada S, Weinstein L, Dash R, van der Wal A, Bryjak M, Gogotsi Y, Biesheuvel P M (2012). Water desalination using capacitive deionization with microporous carbon electrodes. ACS Applied Materials & Interfaces, 4(3): 1194–1199

    Article  CAS  Google Scholar 

  • Raymundō Piñero E, Leroux F, Béguin F (2006). A high-performance carbon for supercapacitors obtained by carbonization of a seaweed biopolymer. Advanced Materials, 18(14): 1877–1882

    Article  Google Scholar 

  • Ryoo M W, Seo G (2003). Improvement in capacitive deionization function of activated carbon cloth by titania modification. Water Research, 37(7): 1527–1534

    Article  CAS  Google Scholar 

  • Saber A, Mortazavian S, James D E, Hasheminejad H (2017). Optimization of collaborative photo-fenton oxidation and coagulation for the treatment of petroleum refinery wastewater with scrap iron. Water, Air, and Soil Pollution, 228(8): 312

    Article  Google Scholar 

  • Saboorian-Jooybari H, Chen Z (2019). Calculation of re-defined electrical double layer thickness in symmetrical electrolyte solutions. Results in Physics, 15: 102501

    Article  Google Scholar 

  • Shi W, Zhou X, Li J, Meshot E R, Taylor A D, Hu S, Kim J H, Elimelech M, Plata D L (2018). High-performance capacitive deionization via manganese oxide-coated, vertically aligned carbon nanotubes. Environmental Science & Technology Letters, 5(11): 692–700

    Article  CAS  Google Scholar 

  • Singh K, Porada S, de Gier H D, Biesheuvel P M, de Smet L C P M (2019). Timeline on the application of intercalation materials in Capacitive Deionization. Desalination, 455: 115–134

    Article  CAS  Google Scholar 

  • Tsouris C, Mayes R, Kiggans J, Sharma K, Yiacoumi S, DePaoli D, Dai S (2011). Mesoporous carbon for capacitive deionization of saline water. Environmental Science & Technology, 45(23): 10243–10249

    Article  CAS  Google Scholar 

  • Wang M, Xu X, Tang J, Hou S A, Hossain M S, Pan L, Yamauchi Y (2017a). High performance capacitive deionization electrodes based on ultrathin nitrogen-doped carbon/graphene nano-sandwiches. Chemical Communications, 53(78): 10784–10787

    Article  CAS  Google Scholar 

  • Wang S, Li X, Zhao H, Quan X, Chen S, Yu H (2018). Enhanced adsorption of ionizable antibiotics on activated carbon fiber under electrochemical assistance in continuous-flow modes. Water Research, 134: 162–169

    Article  CAS  Google Scholar 

  • Wang Z, Dou B, Zheng L, Zhang G, Liu Z, Hao Z (2012). Effective desalination by capacitive deionization with functional graphene nanocomposite as novel electrode material. Desalination, 299: 96–102

    Article  CAS  Google Scholar 

  • Wang Z, Xu X, Kim J, Malgras V, Mo R, Li C, Lin Y, Tan H, Tang J, Pan L, Bando Y, Yang T, Yamauchi Y (2019). Nanoarchitectured metal-organic framework/polypyrrole hybrids for brackish water desalination using capacitive deionization. Materials Horizons, 6(7): 1433–1437

    Article  CAS  Google Scholar 

  • Wang Z, Yan T, Chen G, Shi L, Zhang D (2017b). High salt removal capacity of metal-organic gel derived porous carbon for capacitive deionization. ACS Sustainable Chemistry & Engineering, 5(12): 11637–11644

    Article  CAS  Google Scholar 

  • Xing F, Li T, Li J, Zhu H, Wang N, Cao X (2017). Chemically exfoliated MoS2 for capacitive deionization of saline water. Nano Energy, 31: 590–595

    Article  CAS  Google Scholar 

  • Xu P, Drewes J E, Heil D, Wang G (2008). Treatment of brackish produced water using carbon aerogel-based capacitive deionization technology. Water Research, 42(10–11): 2605–2617

    Article  CAS  Google Scholar 

  • Xu X, Allah A E, Wang C, Tan H, Farghali A A, Khedr M H, Malgras V, Yang T, Yamauchi Y (2019). Capacitive deionization using nitrogen-doped mesostructured carbons for highly efficient brackish water desalination. Chemical Engineering Journal, 362: 887–896

    Article  CAS  Google Scholar 

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Correspondence to Hasti Hasheminejad.

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Highlights

• Graphite bipolar electrodes act as an appropriate bed for the CDI process.

• Activated carbon Coating improves the application of the electrodes.

• CDI is an environmentally friendly method to apply for brackish water.

• Initial concentration is the most important parameter in the CDI method.

• CDI process in a batch-mode setup needs more development.

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Atoufi, H.D., Hasheminejad, H. & Lampert, D.J. Performance of activated carbon coated graphite bipolar electrodes on capacitive deionization method for salinity reduction. Front. Environ. Sci. Eng. 14, 99 (2020). https://doi.org/10.1007/s11783-020-1278-1

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  • DOI: https://doi.org/10.1007/s11783-020-1278-1

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