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Organic nitrogen in PM2.5 in Beijing

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Abstract

Nitrogenous species, as important chemical components in PM2.5, include organic nitrogen (ON) and inorganic nitrogen (IN), both of which have potential effects on human health, climate change and visibility degradation. In this study, we analyzed total nitrogen (TN) by CHN Elemental analyzer and inorganic nitrogen by ion chromatography (IC) respectively to obtain ON by calculating the difference between TN and IN. The results show that the mean ON concentrations in winter and summer are both 2.86 μg·m−3, ten times higher than other places reported on average. ON contributes about 20%–30% to TN on average in both seasons, presenting higher contribution in summer. N:C ratios are much higher in summer than winter. ON sources or formation were strengthened by heavy PM2.5 pollution loads, especially sensitive to sulfate. ON concentrations are higher at night in the both seasons, however with distinguished day and night difference patterns influenced by relative humidity (RH) conditions. In winter, ON concentrations increase with RH on average through low RH values to high RH values. The variations are far larger than the ones caused by day and night difference. However in summer, day and night difference dominates the variations of ON concentrations at low RH values, and RH conditions promote ON concentrations increase significantly only at high RH values. Dust related source and anthropogenic emission related secondary source are identified as important sources for ON. At heavy pollution loads, ON sources are more of secondary formation, possibly strengthened by combination influence of RH and acidity increase.

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Authors and Affiliations

  1. State Key Joint Laboratory of Environment Simulation and Pollution Control, School of Environment; State Environmental Protection Key Laboratory of Sources and Control of Air Pollution Complex, Tsinghua University, Beijing, 100084, China

    Qian Zhang, Fengkui Duan, Kebin He, Yongliang Ma & Haiyan Li

  2. Kimoto Electric Co. Ltd., Funahashi-Cho, Tennouji-Ku, Osaka, 543-0024, Japan

    Takashi Kimoto

  3. Analysis and Testing Center of Beijing Normal University, Beijing, 100875, China

    Aihua Zheng

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  1. Qian Zhang
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  2. Fengkui Duan
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  3. Kebin He
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  4. Yongliang Ma
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  5. Haiyan Li
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  6. Takashi Kimoto
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  7. Aihua Zheng
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Correspondence to Fengkui Duan or Kebin He.

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Zhang, Q., Duan, F., He, K. et al. Organic nitrogen in PM2.5 in Beijing. Front. Environ. Sci. Eng. 9, 1004–1014 (2015). https://doi.org/10.1007/s11783-015-0799-5

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  • DOI: https://doi.org/10.1007/s11783-015-0799-5

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