Abstract
The effect of dolomite with different particle size fractions on hematite flotation was studied using sodium oleate as collector at pH of about 9. The effect mechanism of dolomite on hematite flotation was investigated by means of solution chemistry, ultraviolet spectrophotometry (UV), inductively coupled plasma atomic emission spectrometry (ICP-AES) and X-ray photoelectron spectroscopy (XPS). It is observed that dolomite with different size fractions has depressing effect on hematite flotation using sodium oleate as collector, and dolomite could be the “mineral depressant” of hematite using sodium oleate as collector. The reasons for that are concerned with sodium oleate consumption and the adsorption onto hematite of dissolved species of dolomite.
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ARAUJO A C, VIANA P R M, PERES A E C. Reagents in iron ores flotation [J]. Minerals Engineering, 2005, 18(2): 219–224.
MOWLA D, KARIMI G, OSTADNEZHAD K. Removal of hematite from silica sand ore by reverse flotation technique [J]. Separation and Purification Technology, 2008, 58(3): 419–423.
LIMA N P, VALADÃO G E S, PERES A E C. Effect of amine and starch dosage on the reverse cationic flotation of an iron ore [J]. Minerals Engineering, 2013, 45: 180–184.
FILIPPOV L O, SEVEROV V V, FILIPPOVA I V. An overview of the beneficiation of iron ores via reverse cationic flotation [J]. International Journal of Mineral Processing, 2014, 127: 62–69.
MA M. Froth flotation of iron ores [J]. Int J Min Eng Miner Process, 2012, 1(2): 56–61.
MA X, MARQUES M, GONTIJO C. Comparative studies of reverse cationic/anionic flotation of Vale iron ore [J]. International Journal of Mineral Processing, 2011, 100(1/2): 179–183.
MONTES-SOTOMAYOR S, HOVOT R, KONGOLO M. Technical notes. Flotation of silicate gangue iron ores: mechanism and effect of starch [J]. Minerals Engineering, 1998, 11: 71–76.
QUAST K. Flotation of hematite using C6-C18 saturated fatty acid [J]. Minerals Engineering, 2006, 19(6/7/8): 582–597.
ZHANG Zhao-yuan, LV Zheng-fu, YIN Wan-zhong, HAN Yue-xin. Influence of the siderite in donganshan iron ore on reverse flotation [J]. Metal Mine, 2008(10): 52–55. (in Chinese)
YANG Bin. Study on separation technology and mechanism of siderite and hematite [D]. Changsha: Central South University, 2010. (in Chinese)
LUO Xi-mei, YIN Wan-zhong, YAO Jin, SUN Chuan-yao, CAO Yang, MA Ying-qiang, HOU Ying. Flotation separation of magnetic separation concentrate of refractory hematite containing carbonate with enhanced dispersion [J]. The Chinese Journal of Nonferrous Metals, 2013, 23(1): 238–245. (in Chinese)
CAPPELLEN P, CHARLET L, STUMM W, WERSIN P. A surface complexation model of the carbonate mineral-aqueous solution interface [J]. Geochim Cosmochim Acta, 1993, 57(15): 3505–3518.
CHEN Gong-lun, TAO D. Effect of solution chemistry on flotability of magnesite and dolomite [J]. International Journal of Mineral Processing, 2004, 74(1/2/3/4): 343–357.
NUNES A P L, PERES A E C, ARAUJO A C, VALADÃO G E S. Electrokinetic properties of wavellite and its floatability with cationic and anionic collector [J]. Journal of Colloid and Interface Science, 2011, 361(2): 632–638.
VUCINIC D R, RADULOVIC D S, DEUŠIC S D. Electrokinetic properties of hydroxyapatite under flotation conditions [J]. Journal of Colloid and Interface Science, 2010, 343(1): 239–245.
HU Yue-hua. Research on solution chemistry and floatability of salt-type minerals [D]. Changsha: Central South University, 1989. (in Chinese)
HU Y, CHI R, XU Z. Solution chemistry study of salt-type mineral flotation systems: Role of inorganic dispersants [J]. Industrial and Engineering Chemistry Research, 2003, 42(8): 1641–1647.
POKROVSKY O S, GOLUBEV S V, SCHOTT J, CASTILLO A. Calcite, dolomite and magnesite dissolution kinetics in aqueous solutions at acid to circumnetral pH, 25 to 150? and 55 atm pCO2: New constrains on CO2 sequestration in sedimentary basins [J]. Chemical Geology, 2009, 260(3/4): 317–329.
NERMIN G, NURGUL O. pH dependence of electrokinetic behavior of dolomite and magnesite in aqueous electrolyte solutions [J]. Applied Surface Science, 2005, 252(23): 8057–8061.
POKROVSKY O S, GOLUBEV S V, SCHOTT J, CASTILLO A. Calcite, dolomite and magnesite dissolution kinetics in aqueous solutions at acid to circumnetral pH, 25 to 150 °C and 1 to 55 atm pCO2: New constrains on CO2 sequestration in sedimentary basins [J]. Chemical Geology, 2009, 265(1/2): 20–32.
JIANG Hao, LIU Guo-rong, HU Yue-hua, XU Long-hua, YU Ya-wen, XIE Zhen, CHEN Hao-chuan. Flotation and adsorption of quaternary ammonium salts collectors on kaolinite of different particle size [J]. International Journal of Mining Science and Technology, 2013, 23(2): 249–253.
VIEIRA A M, PERES A E C. The effect of amine type, pH and size range in the flotation of quartz [J]. Minerals Engineering, 2007, 20(10): 1008–1013.
NERMIN G, NURGUL O. pH dependence of electrokinetic behavior of dolomite and magnesite in aqueous electrolyte solutions [J]. Applied Surface Science, 2006, 252(23): 8057–8061.
GAUTELIER M, SCHOTT J, OELKERS E H. An experimental study of dolomite dissolution rates at 80 °C as a function of chemical affinity and solution composition [J]. Chemical Geology, 2007, 242(3/4): 509–517.
LIU A, NI W, WU W. Mechanism of separating pyrite and dolomite by flotation [J]. Journal of University of Science and Technology Beijing: Mineral, Metallurgy, Material, 2007, 14(4): 291–296.
FENG Yin. Study on direct flotation separation between apatite and dolomite [D]. Changsha: Central South University, 2011. (in Chinese)
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Foundation item: Project(51374079) supported by the National Natural Science Foundation of China; Project(KKSY201521031) supported by Talent Cultivation Foundation of Kunming University of Science and Technology, China; Project(2015Y067) supported by Foundation of Yunnan Educational Committee, China
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Luo, Xm., Yin, Wz., Wang, Yf. et al. Effect and mechanism of dolomite with different size fractions on hematite flotation using sodium oleate as collector. J. Cent. South Univ. 23, 529–534 (2016). https://doi.org/10.1007/s11771-016-3099-8
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DOI: https://doi.org/10.1007/s11771-016-3099-8