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Re-Os isotopic data for molybdenum from Hejiangkou tungsten and tin polymetallic deposit in Chenzhou and its geological significance

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Abstract

Hejiangkou W-Sn-polymetallic deposit is a newly found deposit in Xitian ore field, one of the important and large scale W-Sn-polymetallic ore fields in the middle segment of Nanling metallogenic zone. Re-Os isotope dating was used on three molybdenite samples from Hejiangkou deposit to determine the ore forming period. The result is (224.9±2.6)Ma-(225±3.1)Ma and isochron age is (225.5±3.6)Ma. The field geological observations, geochronological data and optical petrography indicated that Hejiangkou deposit underwent multi-period of superimposed mineralization. It can be differentiated into three periods composed of six mineralization stages. The first period is the initial period for hydrothermal metasomatism and metal element enrichment during Indosinian Epoch. Further enrichment, strong brittle fracturing and hydrothermal metasomatism, remobilization and superimposition happened in the second period, during early Yanshanian. It is the major mineralization period of Hejiangkou deposit and can be subdivided into four mineralization stages, namely the skarn stage, oxide stage, high-temperature sulfide stage and low-temperature sulfide stage. And the third period is the mineralization period of a porphyry-skarn system related to the emplacement of the granite porphyry dyke. As minerogenic epoch of Hejiangkou deposit is similar with Hehuaping deposit, they show the possibility of Indosinian mineralization event in Nanling metallogenic zone. It can be an important perspective in any future mineral exploration in the same metallogenic zone.

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References

  1. LOVERING T S. Epigenetic, diplogenetic, syngenetic, and lithogene deposits [J]. Economic Geology, 1963, 58(3): 315–331.

    Article  Google Scholar 

  2. TU Guang-zhi. Superimplosition and reformation: Aneglected oreforming process [J]. Infomation of Geoscience and Technology of Hunan Province, 1975: 76–83. (in Chinese)

    Google Scholar 

  3. CHEN Guo-da. Polygenetic compound ore deposits and their origin in the context of crustal evlution regularitiea [J]. Newsletter of the Geological Society of Hunan, 1979(2): 1–22. (in Chinese)

    Google Scholar 

  4. XU Ke-qin, ZHU Jin-chu. Discussions on the genesis of sedimentary (or volcanic sedimentary)-hydrothermal superimposed Fe-Cu deposits in fault depressions in Southeastern China [J]. Fujian Geological Science and Technology Information, 1978(4): 1–68. (in Chinese)

    Google Scholar 

  5. ZHAI Yu-sheng. Ore-forming controlling factors and ore-forming regularities [M]// YUAN Jian-qi, ZHU Shang-qing, ZHAI Yu-sheng. Ore Deposit Geology. Beijing: Geological Publish House, 1979: 428–430. (in Chinese)

    Google Scholar 

  6. PERKINS W G. Mount Isa copper ore bodies [M]// Geology of the Mineral Deposits of Australia and Papua New Guinea. Parkville: Australian Institute of Mining and Metallurgy, 1990: 935–941.

    Google Scholar 

  7. KIRK J, RUIZ J, CHESLEY J, WALSHE J, GAVIN E. A major Archean, gold-and crust-forming event in the Kaapvaal craton, South Africa [J]. Science, 2002, 297(13): 1856–1858.

    Article  Google Scholar 

  8. ZHAI Yu-sheng, WANG Jian-ping, PENG Run-min. Research on superimposed metallogenic systems and polygenetic mineral deposits. earth [J]. Earth Science Frontiers, 2009, 16(6): 282–290.

    Google Scholar 

  9. LIU Guo-qing, WU Shi-chong, DU An-dao, FU Jian-ming, YANG Xiao-jun, TANG Zhi-hua, WEI Jun-qi. Metallogenic ages of the Xitian tugsten-tin deposit, eastern Hunan Province [J]. Geotectonicaet Metallogenia, 2008, 32(1): 63–71.

    Google Scholar 

  10. LUO Hong-wen, ZENG Qing-wang, ZENG Gui-hua. Geological characteristics and origin of the Xitian tin orefield in eastern Hunan Province [J]. Geology and Mineral Resources of South China, 2005(2): 61–68.

    Google Scholar 

  11. MA Li-yan, FU Jian-ming, WU Shi-chong, XU De-ming, YANG Xiao-jun. 40Ar/39Ar isotopic dating of the Longshang tin-polymetallic deposit, Xitian orefield, eastern Hunan [J]. Geology in China, 2008, 35(4): 706–715. (in Chinese)

    Google Scholar 

  12. MA Tie-qiu, WANG Xian-hui, BAI Dao-yuan. Geochemical characteristics and its tectonic setting of the Xitian tungstentin-bearing granite pluton [J]. Geology and Mineral Resources of South China, 2004(1): 11–17. (in Chinese)

    Google Scholar 

  13. MA Tie-qiu, BAI Dao-yuan, KUANG Jun, WANG Xian-hui. Zircon SHRIMP dating of the Xitian granite pluton, Chaling, southeastern Hunan, and its geological significance [J]. Geological Bulletin of China, 2005, 24(5): 415–421. (in Chinese)

    Google Scholar 

  14. WU Shi-chong, LUO Hong-wen, HUANG Tao. Metallogenetic geological characteristics and prospecting of tin-polymetallic deposits in central Xitian area, eastern Hunan [J]. Geology and Mineral Resources of South China, 2004(2): 21–27. (in Chinese)

    Google Scholar 

  15. WU Shi-chong, HONG Qing-hui, LONG Wei-ping, LUO Yun. Geological features and metallogenic model of Xitian W-Sn polymetallic deposit, Hunan province [J]. Geology and Mineral Resources of South China, 2009(2): 1–6. (in Chinese)

    Google Scholar 

  16. XU Hui-yang, WU Shi-chong, YU Yang-chun, XIE You-liang, LONG Wei-ping. Geological characteristics and ore-controlling factors of Xitian skarn-type W-Sn deposit in Hunan province [J]. Geology and Mineral Resources of South China, 2006(2): 37–42. (in Chinese)

    Google Scholar 

  17. YU Yang-chun, WU Shi-chong, LIANG Tie-gang. Metallogenetic geological characteristics and ore prospecting direction in Xitian area [J]. Resources Survey & Enviroment, 2006, 27(2): 122–136. (in Chinese)

    Google Scholar 

  18. YANG Xiao-jun, WU Shi-chong, FU Jian-ming. Fluid inclusion studies of Longshang tin-polymetallic deposit in Xitian ore field, eastern Hunan province [J]. Mineral Deposits, 2007, 26(5): 5011–5022.

    Google Scholar 

  19. WU Zi-cheng, LIU Ji-shun, SHU Guo-wen, WANG Wei, MA Hui-ying. The relationship between Yanshanian tectonic-magmatic thermal event and Tin, Tungsten mineralization at Xitian, Nanling area [J]. Contributions to Geology and Minera Resources Reserch, 2010, 25(3): 201–205. (in Chinese)

    Google Scholar 

  20. DENG Xiang-wei, DAI Xue-ling, LIU Guang-dong. Geological and geochemical characteristics of SP granites in Hejiangkou deposit of Xitian orefield and their contraction with pluton of Qinhang suture zone [J]. Journal of Mineralogy and Petrology, 2012, 32(2): 45–55.

    Google Scholar 

  21. ZHAI Yu-sheng, DENG Jun, WANG Jian-ping. Researches on deep ore prospecting [J]. Mineral Deposits, 2004(23): 142–149.

    Google Scholar 

  22. LIN Xin-duo, ZHANG De-hui, ZHANG Chuan-ling. A diacussion on the property of ore-forming fluid of the wolframite quarte-vein in the yaogangxian tungsten deposit, Yizhang county Hunan province [J]. Earth Science, 1986, 11(2): 153–160.

    Google Scholar 

  23. SHU Liang-shu. An analysis of principal features of tectonic evolution in South China Block [J]. Geological Bulletin of China, 2012, 31(7): 1035–1053. (in Chinese)

    Google Scholar 

  24. BAI Dao-yuan, JIA Bao-hua, LI Jin-dong, WANG Xian-hui, MA Tie-qiu, ZHANG Xiao-yang, CHEN Bi-he. Important significance of regional tectonic regime to metallogenic capacity of Indosinian and Early Yanshanian granites in southeastern Hunan: A case study of Qianlishan and Wangxianling plutons [J]. Mineral Deposit, 2007, 26(5): 487–500.

    Google Scholar 

  25. MAO Jing-wen, XIE Gui-qing, CHENG Yan-bo, CHEN Yu-chuan. Mineral deposit models of mesozoic ore deposits in South China [J]. Geological Review, 2009, 55(3): 347–353. (in Chinese)

    Google Scholar 

  26. FU Jian-ming, CHENG Shun-bo, LU You-yue, WU Shi-chong, MA Li-yan, CHEN Xi-qing. Geochronology of the greisen-quartzvein type tungsten tin deposit and its host granite in Xitian, Hunan province [J]. Geology and Exploration, 2012, 48(2): 313–320.

    Google Scholar 

  27. SHIREY S B, WALKER R J. Carius tube digestion for low-blank rhenium- osmium analysis [J]. Anal Chem, 1995, 67: 2136–2141.

    Article  Google Scholar 

  28. WIESER M E. Atomic weights of the elements (Iupic technical Report) [J]. Pure Appl Chem, 2005, 78(11): 2051–2066.

    Google Scholar 

  29. BOHLKEA J K, LAETER de J R, BIEVRE P D. Isotopic compositions of the elements [J]. J Phys Chem Ref Data, 2001, 34(1): 57–67.

    Article  Google Scholar 

  30. SMOLIAR M I, WALKER R J, MORGAN J W. Re-Os ages of group IIA, IIIA, IVA and VIB iron meteorites [J]. Science, 1996, 271: 1099–1102.

    Article  Google Scholar 

  31. LI Jian-kang, WANG Deng-hong, LIANG Ting. Progress of research on metallogenic regularity and deep exploration in nanling region and its indication for W-Sn exploration in tibet [J]. Acta Geoscientia Sinica, 2013, 34(1): 58–74. (in Chinese)

    MathSciNet  Google Scholar 

  32. CHEN Di, MA Ai-jun, LIU Wei, LIU Yao-rong, NI Yan-jun. Research on U-Pb chronology in Xitian pluton of Hunan province [J]. Geoscience, 2013, 27(4): 819–831.

    Google Scholar 

  33. FOSTER J G, LAMBERT D D, FRICK L R. Re-Os isotopic evidence for genesis of Archean nickel ores from uncontaminated komatiites [J]. Nature, 1996, 382: 703–706.

    Article  Google Scholar 

  34. LI Wen-chang, YU Hai-jun, YIN Guang-hou, CAO Xiao-min, HUANG Ding-zhu, DONG Tao. Re-Os dating of molybdenite from Tongchanggou Mo-polymetallic deposit in northwest Yunnan and its metallogenic environment [J]. Mineral deposit, 2012, 31(2): 282–292. (in Chinese)

    Google Scholar 

  35. YAO Yuan, CHEN Jun, LU Jian-jun, ZHANG Rong-qing. Geochronology, Hf isotopic compositions and geochemical characteristics of Xitian A-type granite and its geological signif icance [J]. Mineral deposits, 2013, 32(3): 467–488.

    Google Scholar 

  36. ZHOU Yun, LIANG Xin-quan, LIANG Xi-rong. Geochronology and geochemical characteristics of the xitian tungsten-tin-bearing A-type tranites, Hunan Province, China [J]. Geotectonica et Metallogenia, 2013, 37(6): 511–529.

    MathSciNet  Google Scholar 

  37. GUO Chun-li, LI Chao, WU Shi-chong. Molybdenite Re-Os isotopic dating of Xitian deposit in Hunan Province and its geological significance [J]. Rock and Mineral Analysis, 2014, 33(1): 145–152. (in Chinese)

    MathSciNet  Google Scholar 

  38. GUO Chun-li, ZHENG Jia-hao, LOU Fa-sheng. Petrography, genetic types and geological dynamical settings of the indosinian granitoids in South China [J]. Geotectonica et Metallogenia, 2012, 36(3): 457–475. (in Chinese)

    Google Scholar 

  39. YANG Ming-gui, MEI Yong-wen. Characteristics of geology and metatllization in the qinzhou-hangzhou paleoplate juncture [J]. Geology and Mineral Resources of South China, 1997(3): 52–59.

    Google Scholar 

  40. YU Da-gan, GUAN Tai-yang, WANG Gui-jin. The strata characteristics of early late proterozoic era in the border of Min, Zhe and Gan and its comparison with banxi group [J]. Journal of East China Geological Institute, 1993(4): 320–333. (in Chinese)

    Google Scholar 

  41. LI Guan-lai, HUA Ren-ming, HUANG Xiao-er. Re-Os isotopic age of molybdenite from Xiatongling tungsten deposit, central Jiangxi Province, and its geological implications [J]. Mineral Deposit, 2011, 30(6): 1075–1084.

    Google Scholar 

  42. XIE Xin, XU Xi-sheng, ZOU Hai-bo. The prologue to the late mesozoic magmatism: The middle Jurassic basalt, southeast China [J]. Science in China: Series D, 2005, 35(7): 587–605.

    Google Scholar 

  43. CHEN Jun, WANG Ru-cheng, ZHU Jin-chu, LU Jian-jun, MA Dong-sheng. Multiple-aged granitoids and related tungsten-tin mineralization in the Nanling Range, South China [J]. Science China: Earth Sciences, 2013, 44(1): 111–121.

    Google Scholar 

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Correspondence to Xiong-jun Wang  (王雄军).

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Foundation item: Project(41403035) supported by the National Natural Science Foundation of China; Project(13JJ4041) supported by Hunan Provincial National Natural Science Foundation, China

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Liu, Db., Yang, L., Deng, Xw. et al. Re-Os isotopic data for molybdenum from Hejiangkou tungsten and tin polymetallic deposit in Chenzhou and its geological significance. J. Cent. South Univ. 23, 1071–1084 (2016). https://doi.org/10.1007/s11771-016-0357-8

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  • DOI: https://doi.org/10.1007/s11771-016-0357-8

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