Skip to main content
Log in

Stability to oxidation of virgin olive oils as related to olive conditions: Study of polar compounds by chemometric methods

  • Published:
Journal of the American Oil Chemists' Society

Abstract

Polar compounds of virgin olive oils were analyzed. They influence oil flavor and aroma and improve the shelf-life of the oil. The orthodiphenolic fraction is particularly significant for oil stability because of its antioxidative activity. A relationship between the composition of the whole fraction of polar compounds and the state of health of the olives was established. For this purpose, oil samples were obtained from olives that had reached different degrees of ripeness and that had been affected by Dacus oleae infestation differently. The polar compounds were then analyzed by high-performance liquid chromatography. The data set was studied by means of chemometric methods. Partial least squares regression was used to obtain models that show a significant correlation between composition of the oil’s polar compounds and conditions of the olives sampled. In particular, compounds with antioxidative activity were directly linked with the state of health of the olives. The models obtained allow tracing of the state of health of the olives sampled through analysis of the polar fraction of virgin olive oil with a high degree of accuracy, and thus prediction of the oil’s expected shelf life.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Vasquez Roncero, A., Les Polyphénoles de l’Huile d’Olive et Leurs Influence sur les Caractéristiques de l’Huile, Rev. Franç. Corps Gras 25:21–26 (1978).

    Google Scholar 

  2. Solinas, M., A. Di Giovacchino, and A. Mascolo, The Polyphenols of Olives and Olive Oil. Note III. Influence of Temperature and Kneading Time on the Oil Polyphenols Content, Riv. Ital. Sost. Grasse 55:19–23 (1978).

    CAS  Google Scholar 

  3. Graciani Constante, E., and A. Vasquez Roncero, Study on Polar Components of Olive Oil by High-Performance Liquid Chromatography (HPLC). Application to Various Types of Virgin Oils, Grasas Aceites 32:365–371 (1981).

    CAS  Google Scholar 

  4. Perrin, J.L., Les Composés Mineurs et les Antooxygènes Naturels de l’Olive et de Son Huile, Rev. Franç. Corps Gras 39:25–32 (1992).

    CAS  MathSciNet  Google Scholar 

  5. Gutierrez Gonzales-Quijan, R., C. Janer del Valle, M.L. Janer del Valle, F. Gutierrez Rosales, and A. Vasquez Roncero, Relationship Between Polyphenols Content and the Quality and Stability of Virgin Olive Oil, Grasas Aceites 28:101–106 (1977).

    Google Scholar 

  6. Cortesi, N., A. Ponziani, and E. Fedeli, Characterization of Virgin and Refined Olive Oils by HPLC of Polar Component, Riv. Ital. Sost. Grasse 58:108–114 (1981).

    CAS  Google Scholar 

  7. Di Giovacchino, L., M. Solinas, and M. Miccoli, Effect of Extraction Systems on the Quality of Virgin Olive Oil, J. Am. Oil Chem. Soc. 71:1189–1193 (1994).

    Article  Google Scholar 

  8. Maestro-Durán, R., R. León Cabello, and V. Ruiz Gutíerrez, Phenolic Compounds from Olive (Olea europaea), Grasas Aceites 45:265–269 (1994).

    Google Scholar 

  9. Cortesi, N., and E. Fedeli, Polar Components of Virgin Olive Oil. Note 1, Riv. Ital. Sost. Grasse 60:341–351 (1983).

    CAS  Google Scholar 

  10. Amiot, M.T., A. Fleuriet, and J.T. Macheix, Importance and Evolution of Phenolics Compounds During Growth and Maturation, J. Agric. Food Chem. 34:823–826 (1986).

    Article  CAS  Google Scholar 

  11. Maestro Durán, R., and R. Borja Padilla, Relationship Between the Quality of the Oil and the Composition and Ripening of the Olive, Grasas Aceites 41:171–178 (1990).

    Google Scholar 

  12. Evangelisti, F., P. Zunin, E. Tiscornia, and R. Petacchi, Effect of Different Environmental and Cropping Conditions on the Antioxidant Compounds of Virgin Olive Oil, in Proceedings of the Second National Conference on Food Chemistry, Grafica Ed., Messina, 1995, pp. 519–523.

  13. Evangelisti, F., P. Zunin, C. Calcagno, E. Tiscornia, and R. Petacchi, Dacus oleae Infestation and Its Consequences on the Phenolic Compounds of Virgin Olive Oil, Riv. Ital. Sost. Grasse 71:507–511 (1994).

    CAS  Google Scholar 

  14. Zunin, P., F. Evangelisti, M.A. Pagano, E. Tiscornia, and R. Petacchi, Phenolic Compounds in Oil Obtained from Olea europaea and Anti-Dacus Treatments, Ibid.:55–59 (1995).

    CAS  Google Scholar 

  15. Solinas, M., A. Di Giovacchino, and A. Mascolo, The Polyphenols of Olives and Olive Oil. Note IV. Their Evolution Depending by Early Oxidative Reactions Which Happened During the Storage of the Oil, Ann. Ist. Sper. Elaiotecn. 8:3–19 (1978).

    Google Scholar 

  16. Chimi, H., A. Sadik, B. Le Tutour, and M. Rahmani, Contribution à l’Étude Comparative des Pouvoirs Antioxydants dans l’Huile d’Olive du Tyrosol, de l’Hydroxytyrosol, de l’Acide Cafeique, de l’Oleuropéine et du BHT, Rev. Franç. Corps Gras 35:339–344 (1988).

    CAS  Google Scholar 

  17. Chimi, H., M. Rahmani, J. Cillard, and P. Cillard, Autooxydation des Huiles d’Olive: Rôle des Composés Phenoliques, Ibid.:363–367 (1990).

    CAS  Google Scholar 

  18. Papadopoulos, G., and D. Boskou, Antioxidant Effect of Natural Phenols on Olive Oil, J. Am. Oil Chem. Soc. 68:669–671 (1991).

    CAS  Google Scholar 

  19. Armanino, C., R. Leardi, and S. Lanteri, Chemometric Analysis of Tuscan Olive Oils, Chemom. Intell. Lab. Syst. 5:343–354 (1989).

    Article  CAS  Google Scholar 

  20. Aparicio, R., L. Ferreiro, R. Leardi, and M. Forina, Building Decision Rules by Chemometric Analysis: Application to Olive Oil, Ibid.:349–358 (1991).

    Article  CAS  Google Scholar 

  21. Alessandri, S., A. Cimato, A. Mattei, and G. Modi, Characterization of Olive Oils from Tuscany According to Harvesting Time, by Means of Their Phenols Content, Boll. Chim. Igien. 43:143–161 (1992).

    Google Scholar 

  22. Montedoro, G.F., M. Servili, M. Baldioli, C. Magnarini, L. Cossignani, and P. Damiani, Potential Models Defining Virgin Olive Oil Characteristics, Ind. Alim. 32:618–631 (1993).

    Google Scholar 

  23. Drava, G., M. Forina, S. Lanteri, and M. Lupoli, Development of the Chemical Model of a Typical Food Product: Olive Oil from an Italian Region (Basilicata), J. Sci. Food Agric. 65:21–30 (1994).

    Article  CAS  Google Scholar 

  24. Baraldi, P.G., D. Simoni, S. Manfredini, and E. Menziani, Preparation of 3,4-Dihydroxy-1-Benzenethanol: A Reinvestigation, Liebigs Ann. Chem.: 684–686 (1983).

  25. Forina, M., R. Leardi, C. Armanino, and S. Lanteri, QPARVUS: An Extendable Package of Programs for Data Exploration, Classification and Correlation, Istituto di Analisi e Tecnologie Farmaceutiche e Alimentari, Università di Genova, 1995.

  26. Meloun, M., J. Militky, and M. Forina, Exploratory and Factor Analysis of Multivariate Data, in Chemometrics for Analytical Chemistry, Vol. 1, Ellis Horwood, New York, 1992, pp. 212–300.

    Google Scholar 

  27. Brown, P.J., Measurement, Regression, and Calibration, Oxford University Press Inc., New York, 1993, pp. 51–117.

    MATH  Google Scholar 

  28. Montedoro, G.F., M. Servili, M. Baldioli, R. Selvaggini, E. Miniati, and A. Macchioni, Simple and Hydrolyzable Compounds in Virgin Olive Oil. 3. Spectroscopic Characterization of the Secoiridoid Derivatives, J. Agric. Food Chem. 41:2228–2234 (1993).

    Article  CAS  Google Scholar 

  29. Saxberg, B.E.H., D.L. Duewer, J.L. Booker, and B.R. Kowalski, Pattern Recognition and Blind Assay Techniques Applied to Forensic Separation of Whiskies, Anal. Chim. Acta 103:201–212 (1978).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to F. Evangelisti.

About this article

Cite this article

Evangelisti, F., Zunin, P., Tiscornia, E. et al. Stability to oxidation of virgin olive oils as related to olive conditions: Study of polar compounds by chemometric methods. J Amer Oil Chem Soc 74, 1017–1023 (1997). https://doi.org/10.1007/s11746-997-0019-y

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11746-997-0019-y

Key words

Navigation