Abstract
The effect of emulsion structure on the susceptibility to oxidation of emulsified olive oils was tested. Olive oil samples were emulsified by adding a certain quantity of water in different ways. The resulting water-in-oil emulsions were then oxidized with UV light. The results revealed that the emulsion structure played a significant role in the oxidation process of emulsified olive oils. A kinetic mechanism is discussed based on the PV determined experimentally. The susceptibility of water-emulsified extra virgin olive oils to oxidation was quantified by means of a dimensionless parameter that displayed a characteristic dependence on the specific surface area of the water dispersed phase.
Similar content being viewed by others
References
Tuck, K.L., and P.J. Hayball, Major Phenolic Compounds in Olive Oil: Metabolism and Health Effects, J. Nutr. Biochem. 13:636–644 (2002).
Papadopulos, G., and D. Boskou, Antioxidant Effect of Natural Phenols on Olive Oil, J. Am. Oil Chem. Soc. 68:669–671 (1991).
Hoffmann, G., The Chemistry and Technology of Edible Oils and Fats and Their High Fat Products, Academic Press, San Diego, 1989, pp. 29–119.
Lerker, G., N. Frega, F. Bocci, and G. Servidio, “Veiled” Extra-Virgin Olive Oil: Dispersion Response Related to Oil Quality, J. Am. Oil Chem. Soc. 71:657–658 (1994).
Kiritsakis, A.K., Olive Oil (2nd edn., augmented and revd.), Food and Nutrition Press, Trumbull, CT, 1998.
Ambrosone, L., R. Angelico, G. Cinelli, V. Di Lorenzo, and A. Ceglie, The Role of Water in the Oxidation Process of Extra Virgin Olive Oils, J. Am. Oil Chem. Soc. 79:577–581 (2002).
Fritsch, C.W., Lipid Oxidation—The Other Dimension, INFORM 5:423–436 (1994).
McClements, D.J., and E.A. Decker, Lipid Oxidation in Oil-in-Water Emulsions: Impact of Molecular Environment on Chemical Reactions in Heterogeneous Systems, J. Food Sci. 65:1270–1281 (2000).
European Community, Regulation 2568/91, Off. J. Eur. Commun. L.248 (1991).
Kalbanov, A., T. Tarara, R. Arlauskas, and J. Weers, Phospholipids as Emulsion Stabilizers. 2. Phase Behavior vs. Emulsion Stability, J. Colloid Interface Sci. 184:227–235 (1996).
Sæther, Ø., Flocculation and Coalescence in Oil/Water and Water/Oil Emulsions as Studied by Video Enhanced Microscopy, Ph.D. Thesis, University of Bergen, Bergen, Norway, 1999.
Frankel, E.N., Lipid Oxidation, The Oily Press, Dundee, Scotland, 1998.
Evans, D.F., and H. Wennerström, The Colloidal Domain: Where Physics, Chemistry, and Technology Meet, VCH, New York, 1994.
Georgalaki, M.D., T.G. Sotiroudis, and A. Xenakis, The Presence of Oxidizing Enzyme Activities in Virgin Olive Oil, J. Am. Oil Chem. Soc. 75:155–159 (1998).
Kiritsakis, A.K., and L.R. Dugan, Study in Photooxidation of Olive Oil, Ibid. 62:892–896 (1985).
Orr, C., Emulsion Droplet Size Data, in Encyclopedia of Emulsion Technology, edited by P. Becher, Marcel Dekker, New York, 1983, Vol. 1, pp. 369–404.
Author information
Authors and Affiliations
Corresponding author
About this article
Cite this article
Ambrosone, L., Cinelli, G., Mosca, M. et al. Susceptibility of water-emulsified extra virgin olive oils to oxidation. J Amer Oil Chem Soc 83, 165–170 (2006). https://doi.org/10.1007/s11746-006-1190-2
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/s11746-006-1190-2