Abstract
In order to enhance the solubility of chitosan in water and its corrosion inhibition performance on Q235 steel in 1 M HCl solution, N-vanillyl-O-2′-hydroxypropyltrimethylammonium chloride chitosan (VHTC) was synthesized. The structure of VHTC was characterized by FT-IR and 1H-NMR spectroscopy. The corrosion inhibition performance of VHTC on Q235 steel in 1 M HCl solution was studied by weight loss, polarization, electrochemical impedance spectroscopy (EIS) and stereo microscope analysis. Experimental results indicate that VHTC shows better inhibition efficiency compared to chitosan. When the concentration of VHTC increases to 200 mg L−1, the inhibition efficiency reaches 90 %, which is almost equal to the conventional corrosion inhibitors (e.g., imidazoline). The polarization study demonstrates that VHTC is a mixed-type inhibitor caused by a geometrical blanketing effect. The charge transfer resistance is proportional to the inhibitor concentration as revealed by the EIS results, indicating that the protective film on the Q235 steel surface is formed by adsorption of the inhibitor molecules. The inhibition efficiency of VHTC achieves the maximum value within 24 h when the concentration of VHTC is 200 mg L−1. The morphology observation of the corroded steel surface indicates that the corrosion of Q235 steel in 1 M HCl solution is significantly inhibited after introducing VHTC into the acidic solution.
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References
Bouklah M, Hammouti B, Aouniti A, Benhadda T (2004) Thiophene derivatives as effective inhibitors for the corrosion of steel in 0.5 M H2SO4. Prog Org Coat 49:225–228
Zhang J, Song WW, Shi DL (2012) A dissymmetric bis-quaternary ammonium salt gemini surfactant as effective inhibitor for Q235 steel in hydrochloric acid. Prog Org Coat 75:284–291
Chauhan LR, Gunasekaran G (2007) Corrosion inhibition of mild steel by plant extract in dilute HCl medium. Corros Sci 49:1143–1161
Özcan M, Dehri İ (2004) Electrochemical and quantum chemical studies of some sulphur-containing organic compounds as inhibitors for the acid corrosion of mild steel. Prog Org Coat 51:181–187
Musa AY, Kadhum AAH, Mohamad AB (2010) Inhibition of aluminum corrosion by phthalazinone and synergistic effect of halide ion in 1.0 M HCl. Corros Sci 52:3331–3340
Azhar ME, Mernari B, Traisnel M (2001) Corrosion inhibition of mild steel by the new class of inhibitors [2,5-bis(n-pyridyl)-1,3,4-thiadiazoles] in acidic media. Corros Sci 43:2229–2238
Zhang J, Shi DL, Gong XL (2013) Inhibition performance of novel dissymmetric bisquaternary ammonium salt with an imidazoline ring and an ester group. J Surfact Deterg 16:515–522
Zhang F, Tang YM, Cao ZY (2012) Performance and theoretical study on corrosion inhibition of 2-(4-pyridyl)-benzimidazole for mild steel in hydrochloric acid. Corros Sci 61:1–9
Zhang J, Gong XL, Yu HH, Du M (2011) The inhibition mechanism of imidazoline phosphate inhibitor for Q235 steel in hydrochloric acid medium. Corros Sci 53:3324–3330
Wang B, Du M, Zhang J, Gao CJ (2011) Electrochemical and surface analysis studies on corrosion inhibition of Q235 steel by imidazoline derivative against CO2 corrosion. Corros Sci 53:353–361
Garai S, Garai S, Jaisankar P, Singh JK, Elango A (2012) A comprehensive study on crude methanolic extract of Artemisia pallens (Asteraceae) and its active component as effective corrosion inhibitors of mild steel in acid solution. Corros Sci 60:193–204
Nofrizal S, Rahim AA, Saad B, Raja PB, Shah AM, Yahya S (2011) Elucidation of the corrosion inhibition of mild steel in 1 M HCl by catechin monomers from commercial green tea extracts. Metall Mater Trans A 43A:1382–1393
Yan Y, Li W, Cai L, Hou B (2008) Electrochemical and quantum chemical study of purines as corrosion inhibitors for mild steel in 1 M HCl solution. Electrochim Acta 53:5953–5960
Balakrishnan B, Mohanty M, Umashankar PR, Jayakrishnan A (2005) Evaluation of an in situ forming hydrogel wound dressing based on oxidized alginate and gelatin. Biomaterials 26:6335–6342
Sinko J (2001) Challenges of chromate inhibitor pigments replacement in organic coatings. J Prog Org Coat 42:267–282
Hussein MHM, El-Hady MF, Shehata HAH, Hegazy MA, Hefni HHH (2013) Preparation of some eco-friendly corrosion inhibitors having antibacterial activity from sea food waste. J Surfact Deterg 16:233–242
Fekry AK, Mohamed RR (2010) Acetyl thiourea chitosan as an eco-friendly inhibitor for mild steel in sulphuric acid medium. Electrochim Acta 55:1933–1939
Achouri ME, Infante MR, Izquierdo F, Kertit S, Gouttaya HM, Nciri B (2001) Synthesis of some cationic gemini surfactants and their inhibitive effect on iron corrosion in hydrochloric acid medium. Corros Sci 43:19–35
Gece G (2011) Drugs: a review of promising novel corrosion inhibitors. Corros Sci 53:3873–3898
Hegazy MA, Abdallah M, Awad MK, Rezk M (2014) Three novel di-quaternary ammonium salts as corrosion inhibitors for API X65 steel pipeline in acidic solution. Part I: experimental results. Corros Sci 81:54–64
Sperpil S, Berrin D, Aysel Y, Gulsen T (2012) Schiff bases as corrosion inhibitor for aluminium in HCl solution. Corros Sci 54:251–259
Jia ZS, Shen DF, Xu WL (2001) Synthesis and antibacterial activities of quaternary ammonium salt of chitosan. Carbohyd Res 333:1–6
Guo ZY, Xing RG, Liu S (2008) Synthesis and hydroxyl radicals scavenging activity of quaternized carboxymethyl chitosan. Carbohyd Polym 73:173–177
Peng HL, Xiong H, Li JH, Xie MY, Liu YZ, Bai CQ, Chen LX (2010) Vanillin cross-linked chitosan microspheres for controlled release of resveratrol. Food Chem 121:23–28
He GH, Chen X, Yin YH, Zheng H, Xiong X, Du YM (2011) Synthesis, characterization and antibacterial activity of salicyloyl chitosan. Carbohyd Polym 83:1274–1278
Guo ZY, Chen R, Xing RG, Liu S, Yu HH, Wang PB, Li CP, Li PC (2006) Novel derivatives of chitosan and their antifungal activities in vitro. Carbohyd Res 341:351–354
Yi HZ, Ding F, Xin F, Liao H (2003) Advance in Synthesis of 3-Chloro-2-hydroxypropyltrimethylammonium Chloride. Fine Chem 20:742–745
Jiang B, Zhang J, Du M, Sun ZD (2009) Synthesis and inhibition performance of dissymmetric bis-quaternary ammonium with imidazoline ring. Fine Chem 26:761–764
Hamman JH, Kotzé AF (2001) Effect of the type of base and number of reaction steps on the degree of quaternization and molecular weight of N-Trimethyl chitosan chloride. Drug Dev Ind Pharm 27:373–380
ASTM G 01-03 (2003) ASTM Book of Standards, vol 3.02. West Conshohocken
ASTM G 31-72 (2004) ASTM Book of Standards, vol 3.02. West Conshohocken
Kim YH, Choi HM, Yoon JH (1998) Synthesis of a quaternary ammonium derivative of chitosan and its application to a cotton antimicrobial finish. Text Res J 68:428–434
Mi FL, Shyu SS, Chen CT, Lai JY (2002) Adsorption of indomethacin onto chemically modified chitosan beads. Polym 43:757–765
Vachoud L, Chen T, Payne GF (2001) Peroxidase catalyzed grafting of gallate esters onto the polysaccharide chitosan. Enzyme Microb Tech 29:380–385
Kim JY, Lee JK, Lee TS, Park WH (2003) Synthesis of chitooligosaccharide derivative with quaternary ammonium group and its antimicrobial activity against Streptococcus mutans. Int J Biol Macromol 32:23–27
Jiang FH, Zhang P (1996) A study on the corrosion inhibition behavior of mild steel in HCl Solution by N-Dodecylglycines. Surface Tech 2:7–10
Zhao JG, Peng YL (2008) Effect of surface activity of organic corrosion inhibitors on adsorption and corrosion behavior of metallic materials. Corros Sci Protect Tech 5:353–357
Yang QR, Zhang XF, Yang HG, Ma DG, Chen JG (2002) Corrosion inhibition of oleic diethanolamide borate ester for steel. Mater Prot 2:21–22
Olivares-Xometl O, Likhanova NV, Dominggues-Aguilar MA, Arce E, Dorantes H, Arellanes-Lozada P (2008) Synthesis and corrosion inhibition of α-amino acids alkylamides for mild steel in acidic environment. Mater Chem Phys 110:344–351
Hegazy MA (2009) A novel Schiff base-based cationic gemini surfactants: synthesis and effect on corrosion inhibition of carbon steel in hydrochloric acid solution. Corros Sci 51:2610–2618
Abdallah M (2002) Rhodanine azosulpha drugs as corrosion inhibitors for corrosion of 304 stainless steel in hydrochloric acid solution. Corros Sci 44:717–728
Abdallah M (2003) Ethoxylated fatty alcohols as corrosion inhibitors for dissolution of zinc in hydrochloric acid. Corros Sci 45:2705–2716
Fawcett WR, Kovacova Z, Motheo AJ, Foss CA (1992) Application of the ac admittance technique to double-layer studies on polycrystalline gold electrodes. J Electrochem Soc 326:91–103
Okafor PC, Liu X, Zheng YG (2009) Corrosion inhibition of mild steel by ethylamino imidazoline derivative in CO2-saturated solution. Corros Sci 51:761–768
Popova A, Sokolova E, Raicheva S, Christov M (2003) AC and DC study of the temperature effect on mild steel corrosion in acid media in the presence of benzimidazole derivatives. Corros Sci 45:33–58
Muralidharan S, Phani KLN, Pitchumani S, Ravichandran S, Iyer SVK (1995) Polyamino-benzoquinone polymers: a new class of corrosion inhibitors for mild steel. J Electrochem Soc 142:1478–1483
Acknowledgments
The authors gratefully acknowledge the financial support of the National Natural Science Foundation of China (Project No. 40806030) and the Natural Science Foundation of Shandong Province of China (Project No. ZR2013EMQ015).
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Wang, Q., Zhang, J., Shi, D. et al. Synthesis, Characterization and Inhibition Performance of Vanillin-Modified Chitosan Quaternary Ammonium Salts for Q235 Steel Corrosion in HCl Solution. J Surfact Deterg 18, 825–835 (2015). https://doi.org/10.1007/s11743-015-1717-3
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DOI: https://doi.org/10.1007/s11743-015-1717-3