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Synthesis, Physico-Chemical Properties and Enhanced Oil Recovery Flooding Evaluation of Novel Zwitterionic Gemini Surfactants

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Journal of Surfactants and Detergents

Abstract

In this work, a novel series of zwitterionic gemini surfactants with different hydrophobic tails were synthesized and characterized. The physico-chemical properties of these products (such as surface tension, oil/water interfacial tension, foaming ability, and the wetting ability of paraffin-coated sandstone) were fully studied. The CMC of the synthesized surfactants ranged from 2.17 × 10−4 mol L−1 to 5.36 × 10−4 mol L−1 and corresponding surface tension (γ CMC) ranged from 26.49 mN m−1 to 29.06 mN m−1, which showed excellent efficiency among the comparison surfactants. All the products can reduce the interfacial tension to a relatively low level of about 0.1–1.0 mN m−1. Additionally, results from applying different hydrocarbons suggested that the synergy will be clearer and oil/water interfacial tension will be lower if the oil components are similar to the surfactants. Contact angle and foaming measurements indicated that the surfactants exhibited good wetting and foaming abilities. The results of oil flooding experiments using an authentic sandstone microscopic model showed that C-12 and CA-12 could effectively improve the displacement efficiency by 21–29 %.

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Acknowledgments

We are thankful for financial support from the National Natural Science Foundation of China (No. 21171139), Visiting Scholar Foundation of Northwest University and the National Science and Technology Pillar Program of China (No.2007BAB17B02).

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Authors and Affiliations

  1. Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, College of Chemistry and Materials Science of Northwest University, Xi’an, 710069, China

    Zhen Dong & Jianshe Zhao

  2. Chemical Engineering Department, University of New Brunswick, FREDERICTON, New Brunswick, E3B5A3, Canada

    Ying Zheng

Authors
  1. Zhen Dong
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  2. Ying Zheng
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Correspondence to Jianshe Zhao.

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Dong, Z., Zheng, Y. & Zhao, J. Synthesis, Physico-Chemical Properties and Enhanced Oil Recovery Flooding Evaluation of Novel Zwitterionic Gemini Surfactants. J Surfact Deterg 17, 1213–1222 (2014). https://doi.org/10.1007/s11743-014-1616-z

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  • DOI: https://doi.org/10.1007/s11743-014-1616-z

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